File name: Pandora143s1_LibertyTX_20240508_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20250113T235554.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240508_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T153521.3Z 8894.649552 137 1 24.01 2 38.59 100.02 42.54 89.29 0.00 1 0.00 1 0 17 1.541e-02 8.895e-03 7.948e-03 4.266e-03 1.836159e-01 2.124058e-03 2.064347e-03 -6.000000e+00 8.581486e-03 230.72 -2.00 3.25 -2.00 315.86 0.00e+00 1.485948e-04 2.205754e-04 6.952462e-05 -6.000000e+00 3.850544e-04 289.56 -2.00 20.00 -2.00 315.09 0.00e+00 1.278 0.000 302.00 328.00 3 7.0994e+00 5.5362e-03 1.5614e-02 -6.0000e+00 2.1455e-02 2.7993e-02 6.1706e-03 8.8520e-03 -6.0000e+00 2.3220e-02 9.7420e-03 3.5485e-03 4.3077e-03 -6.0000e+00 1.3846e-02 -5.3873e-03 1.6537e-03 1.1924e-03 -6.0000e+00 5.9790e-03 9.8983e-05 -2.2312e-04 1.1018e-04 1.2695e-05 -6.0000e+00 3.6848e-04 -2.5332e-03 0.0000e+00 11 8 0 10 0 0 99.97 24.57 0.61 -0.00253 -0.00421 6 6 2 8 0 4000.000 20.01 24.57 33.78 25.90 26.11 14.2 1100.00 1702 1409 2258 -778 5609 -4266 -1107 -1490 5250 1082 389 -2119 319 -6422 2464 1453 -1183 -957 4364 -766 1443 24 -2088 71 -558 1707 877 613 -3041 1398 -898 -895 2449 1579 -2452 -3978 -1886 -3120 -818 700 337 -1634 -958 469 -1159 -78 -767 -306 -4197 -2121 916 1061 1105 2241 322 977 1104 -308 521 516 1253 825 1907 1942 754 445 69 -534 55 -146 385 935 240 1293 -300 216 -287 -1871 -641 -114 -273 -1316 -775 -2389 -751 -651 248 -369 1048 438 290 480 126 -729 -106 -254 -161 932 -208 -311 999 -224 -1982 -493 114 -590 -319 -1473 -293 552 398 250 861 -320 233 -767 124 -277 107 -77 -255 355 474 115 33 572 -565 1021 967 101 669 174 -405 -537 825 -147 -504 522 315 167 -115 -455 -1028 375 342 555 -188 1122 -855 -220 -335 1257 284 100 -540 86 -2047 814 524 -449 -367 1644 -311 591 10 -864 30 -250 781 404 268 -1277 537 -357 -379 1077 728 -1100 -1697 -823 -1570 -475 459 240 -1219 -725 353 -882 -59 -574 -222 -3036 -1481 640 783 852 1774 264 807 928 -262 434 424 1037 720 1759 1885 746 416 59 -435 46 -136 386 969 252 1319 -298 198 -241 -1481 -503 -98 -256 -1336 -823 -2636 -854 -783 310 -478 1347 557 353 543 131 -725 -107 -276 -188 1156 -275 -413 1257 -265 -2262 -567 139 -761 -422 -2016 -407 795 594 379 1270 -452 306 -958 152 -349 142 -108 -368 510 667 158 44 732 -695 1216 1197 133 907 239 -559 -757 1198 -224 -785 820 500 264 -178 -687 -1522 SS 20240508T155047.0Z 8894.660266 140 1 24.01 2 35.32 102.83 39.27 91.10 0.00 1 0.00 1 0 17 5.855e-02 2.351e-02 2.678e-02 1.212e-02 1.676897e-01 5.993214e-03 1.879386e-03 -6.000000e+00 3.257487e-02 230.72 -2.00 3.25 -2.00 316.42 0.00e+00 -9.284386e-04 7.033954e-04 2.751267e-04 -6.000000e+00 1.462002e-03 289.56 -2.00 20.00 -2.00 315.59 0.00e+00 1.225 0.000 302.00 328.00 3 7.3894e+00 1.5764e-02 1.4714e-02 -6.0000e+00 8.1441e-02 -1.2343e-02 1.7636e-02 8.3031e-03 -6.0000e+00 8.8175e-02 3.0061e-02 1.0215e-02 3.8929e-03 -6.0000e+00 5.2581e-02 -8.8681e-03 4.8465e-03 1.4975e-03 -6.0000e+00 2.2672e-02 8.1632e-05 4.4683e-05 3.1893e-04 1.3897e-05 -6.0000e+00 1.4004e-03 5.6483e-03 0.0000e+00 12 8 8 10 0 0 99.93 24.13 2.01 0.00565 0.00598 6 6 5 8 0 4000.000 19.98 24.13 34.00 25.90 26.11 14.3 1100.00 -1337 8323 -11508 17917 37310 -1768 -2925 -9734 9910 3592 11859 -4195 7628 -17269 1032 3134 -3319 -3495 23129 -8468 10830 2978 -5779 877 -3087 9500 -694 6093 -7777 5522 -11321 2351 752 8069 1936 -8166 -2265 -10703 3887 -740 -2001 -5050 2602 -1085 1643 84 -947 3698 -9728 -3484 658 2649 2809 5743 -764 5510 -81 -3686 2582 200 5904 -2648 1417 1312 -656 -894 4395 -4111 897 -1830 4100 1509 119 2075 -3356 403 1362 -4122 1752 4192 -69 225 -2430 -1676 -3046 171 1733 -538 2032 1506 512 1395 -156 -2281 619 19 1266 266 -784 -1120 0 614 -6461 238 73 -14 -868 -2939 -2503 887 257 -1000 887 -1067 2230 -1583 2336 1594 1635 -716 878 -236 1264 2903 291 -615 -23 685 2714 546 62 661 -1933 -2667 1069 1133 -1584 237 854 -272 153 -538 -775 -257 1597 -2709 3010 4548 -288 -499 -2029 1952 793 2351 -940 1645 -5274 298 958 -1102 -1176 6235 -3175 3497 1021 -2146 321 -1253 3582 -287 2217 -2960 1755 -4271 833 290 3018 711 -3103 -861 -5126 1959 -452 -1344 -3621 1778 -770 1131 59 -654 2356 -6747 -2238 420 1769 1970 4082 -590 4091 -65 -3039 1977 154 4404 -2265 1258 1234 -632 -796 3356 -3192 696 -1652 3844 1513 121 2035 -3292 349 1045 -3073 1247 3236 -61 219 -2552 -1804 -3503 205 2167 -710 2637 1924 622 1540 -157 -2210 605 21 1450 334 -1061 -1519 1 714 -7543 270 90 -18 -1183 -4206 -3676 1329 405 -1609 1359 -1555 2898 -1988 2797 1992 2174 -1040 1306 -353 1825 3999 393 -802 -28 815 3331 730 86 927 -2768 -3950 1611 1793 -2629 394 1433 -457 250 -851 -1196 SS 20240508T155700.8Z 8894.664593 144 1 8.00 2 34.01 104.07 37.95 91.86 0.00 1 0.00 1 0 17 2.062e-02 1.244e-02 1.709e-02 9.854e-03 1.688343e-01 4.914173e-03 1.904523e-03 -6.000000e+00 1.148130e-02 230.72 -2.00 3.25 -2.00 315.63 0.00e+00 1.259728e-04 4.844442e-04 3.509928e-05 -6.000000e+00 5.151762e-04 289.56 -2.00 20.00 -2.00 314.87 0.00e+00 1.206 0.000 302.00 328.00 3 5.9694e+00 1.2771e-02 1.4607e-02 -6.0000e+00 2.8705e-02 1.1946e-02 1.4212e-02 8.1562e-03 -6.0000e+00 3.1067e-02 1.0345e-02 8.1568e-03 3.9685e-03 -6.0000e+00 1.8525e-02 -2.1127e-03 3.7575e-03 1.0983e-03 -6.0000e+00 7.9991e-03 3.4122e-04 -1.9451e-04 2.5410e-04 1.1927e-05 -6.0000e+00 4.9303e-04 -2.2220e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.68 1.04 -0.00222 -0.00368 1 7 5 8 0 4000.000 20.01 23.68 34.10 25.90 26.11 14.3 1100.00 4665 2917 2389 -6311 7369 -7497 3377 -8789 420 -2162 -4205 -3902 1126 3605 -482 2826 -544 -3286 2607 1114 211 2155 -1516 44 -235 4540 477 353 527 -825 917 1791 1747 -1816 1975 -2653 27 351 597 -818 -336 -512 -2257 159 -3142 -738 -534 1070 -4691 -1448 2643 -875 3100 -313 -438 1287 2311 -1397 734 1362 2251 1680 -511 1859 1005 -1157 822 -551 981 -154 -547 955 627 720 743 658 348 -233 1642 -1831 1181 -2081 -2124 -1401 -1781 -1243 -559 114 -280 2146 -1347 771 -1790 6 400 3136 -397 1196 196 -140 998 -1591 -1800 -661 1321 -1805 -679 -1480 -521 1101 952 -667 -15 -134 500 153 1550 344 -1495 -4 -317 662 31 240 1112 2046 1528 -756 647 -1109 600 -746 648 -554 1089 -167 422 -372 -292 -872 130 -467 -128 1122 781 654 -1777 1618 -1723 717 -2340 116 -644 -1241 -1112 328 1145 -177 1088 -221 -1378 1066 474 93 924 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