File name: Pandora143s1_LibertyTX_20240521_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20240524T152701.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240521_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240521T125103.3Z 8907.535454 180 1 25.92 2 72.61 76.14 127.21 272.16 0.00 1 0.00 1 0 17 3.241e-01 1.205e-02 1.210e-01 5.714e-03 4.274972e-01 2.870613e-03 4.637809e-03 -6.000000e+00 1.808781e-01 231.06 -2.00 3.25 -2.00 319.42 0.00e+00 -4.856420e-04 7.816575e-04 4.636627e-04 -6.000000e+00 8.277250e-03 290.57 -2.00 20.00 -2.00 318.59 0.00e+00 3.297 0.000 302.00 328.00 3 3.7319e+00 8.1974e-03 3.9091e-02 -6.0000e+00 4.5226e-01 2.2134e-02 9.7182e-03 2.1119e-02 -6.0000e+00 4.8920e-01 1.1498e-03 7.5103e-03 1.0213e-02 -6.0000e+00 2.9177e-01 -5.5658e-03 3.9749e-03 2.8500e-03 -6.0000e+00 1.2618e-01 2.7886e-04 7.0594e-04 1.5086e-04 2.5664e-05 -6.0000e+00 7.8786e-03 1.3653e-02 0.0000e+00 12 9 8 11 12 0 98.94 32.07 0.67 0.01365 0.01896 8 8 5 8 0 3238.970 20.01 32.07 31.86 25.68 25.90 15.0 1092.77 353661 37343 58296 -37721 900000 -32682 6325 -53400 20175 -28544 39328 -24684 8315 -15481 4872 20690 -14803 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681 -48 -755 937 -256 2053 -868 -888 -3593 -1402 -1278 808 -457 1315 1900 -347 1081 -2043 1181 -745 815 -762 -522 -1350 749 -339 28 -2817 -508 210 -2212 -1121 -2290 398 -456 1116 658 1002 -234 1318 562 1400 1744 -1158 -109 -1342 723 -178 -218 311 810 1026 1807 2911 1517 492 -1417 -196 -2726 1331 -146 -229 410 -934 1094 -457 -565 -1196 SS 20240521T134122.8Z 8907.570403 206 1 6.01 2 61.93 81.57 137.68 279.00 0.00 1 0.00 1 0 25 4.647e-02 1.272e-02 7.365e-02 1.326e-02 2.642701e-01 6.550024e-03 2.860054e-03 -6.000000e+00 2.593113e-02 231.06 -2.00 3.25 -2.00 318.73 0.00e+00 8.406928e-04 1.371327e-03 3.054554e-04 -6.000000e+00 1.166900e-03 290.58 -2.00 20.00 -2.00 317.83 0.00e+00 2.114 0.000 302.00 328.00 3 2.4474e+00 1.8089e-02 2.4709e-02 -6.0000e+00 6.4864e-02 -1.4132e-01 2.0763e-02 1.2768e-02 -6.0000e+00 7.0148e-02 6.6256e-02 1.3594e-02 6.2539e-03 -6.0000e+00 4.1845e-02 -3.7026e-03 7.0944e-03 1.8600e-03 -6.0000e+00 1.8087e-02 4.1776e-03 1.2415e-03 3.6158e-04 1.6845e-05 -6.0000e+00 1.1107e-03 1.0590e-02 0.0000e+00 12 9 9 12 4 4 12.56 36.58 0.37 0.01059 0.01992 2485 7453 5 8 0 2.400 20.01 36.58 32.57 25.68 25.90 15.0 1098.57 -6386 14065 9890 8495 2250 -27040 15377 -3205 10511 -8565 -9642 1464 12931 5035 10371 19823 -7208 5603 -7100 -1391 -1706 2044 304 1531 -2277 1902 -4430 2461 -2616 6671 8066 -365 5500 1543 -4 -3407 2253 4111 -2629 2179 18 -1778 408 -542 -2095 -383 -2058 -2123 -2553 2287 -2401 2991 -606 3750 1514 -98 -1159 610 262 251 2200 1208 1982 778 -428 -2920 600 -1387 -1194 51 -1291 -11 208 176 1344 -990 401 -4518 -1835 -2029 286 -2215 -1175 -679 -2512 -403 546 1377 176 1197 1057 469 -377 -485 -268 -692 631 1388 2649 464 371 -1616 -821 -2595 -1011 -1041 645 652 635 2068 1828 2039 -27 915 -300 -632 -1736 -1084 -571 -1091 557 201 417 -394 -734 -1282 -402 -1175 -821 -190 -968 -615 -1744 -1425 -234 895 -44 2146 1291 820 68 -1034 -152 -392 809 614 517 130 -1876 763 -212 700 -715 -805 110 976 469 1059 2071 -1002 720 -1068 -208 -265 305 46 243 -400 339 -841 422 -441 1006 1255 -67 1053 323 -1 -668 444 925 -756 704 7 -689 160 -218 -858 -156 -849 -858 -1021 871 -999 1282 -286 1790 764 -51 -632 329 139 132 1160 689 1228 528 -301 -1971 357 -803 -727 35 -998 -9 169 139 999 -683 245 -2718 -1102 -1378 215 -1886 -1062 -636 -2542 -430 615 1605 209 1382 1151 470 -346 -424 -245 -701 700 1695 3467 625 472 -1904 -896 -2951 -1238 -1364 865 911 924 3182 3002 3431 -45 1424 -433 -854 -2336 -1509 -847 -1751 912 327 660 -606 -1085 -1828 -534 -1547 -1148 -288 -1558 -1010 -2914 -2460 -423 1698 -87 4225 2596 1639 133 -1937 -273 SS 20240521T134129.0Z 8907.570475 206 2 6.02 2 61.91 81.58 137.71 279.02 0.00 1 0.00 1 0 17 1.457e-01 2.120e-02 1.819e-01 2.767e-02 2.703424e-01 1.367290e-02 2.945662e-03 -6.000000e+00 8.130017e-02 231.06 -2.00 3.25 -2.00 318.75 0.00e+00 2.908553e-04 2.838559e-03 4.030853e-04 -6.000000e+00 3.658170e-03 290.58 -2.00 20.00 -2.00 317.83 0.00e+00 2.113 0.000 302.00 328.00 3 3.2554e+00 3.7757e-02 2.4894e-02 -6.0000e+00 2.0336e-01 -1.3567e-01 4.3307e-02 1.3194e-02 -6.0000e+00 2.1991e-01 3.2004e-02 2.8349e-02 6.3728e-03 -6.0000e+00 1.3119e-01 4.5973e-03 1.4809e-02 1.7625e-03 -6.0000e+00 5.6717e-02 1.8716e-03 7.0607e-04 7.5821e-04 1.6617e-05 -6.0000e+00 3.4813e-03 9.1026e-03 0.0000e+00 12 9 9 12 4 4 52.05 36.58 0.39 0.00910 0.01441 2485 7453 5 8 0 2.400 20.01 36.58 32.57 25.68 25.90 15.0 1098.57 32284 101153 13319 79604 43631 -6001 8764 7922 16224 -7921 -4829 -23055 69600 -2372 27060 10089 756 -3593 -9058 -1782 -2241 1570 -11981 2495 13596 16436 -9827 -3387 12508 -6292 -141 -16509 -663 -5909 11318 1409 6043 -12375 3 5364 -926 320 1700 6425 8711 695 -1689 5669 -2284 2422 -6218 3751 -2009 2110 1717 3483 -4094 -7764 -86 -5206 -3501 -1061 526 2397 2336 -6528 2131 -2045 -3335 369 1401 1214 968 -1292 1505 4409 -3615 -5884 -3339 4015 -1651 -4665 -3290 4072 -1022 3349 474 1428 1954 2668 1050 650 1704 -753 3424 -1090 -2709 -648 1994 749 1323 -538 -4327 -1679 -572 353 -1952 -1184 -1103 3822 3336 2507 -363 168 -1125 -1683 -1752 -679 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