File name: Pandora143s1_LibertyTX_20240528_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20250114T000243.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240528_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240528T134614.3Z 8914.573777 237 1 24.00 2 60.55 80.72 68.67 224.83 0.00 1 0.00 1 0 17 6.805e-02 1.390e-02 3.180e-02 6.994e-03 2.806815e-01 3.454467e-03 3.107132e-03 -6.000000e+00 3.791550e-02 231.07 -2.00 3.25 -2.00 317.86 0.00e+00 4.006464e-04 5.868180e-04 2.541222e-04 -6.000000e+00 1.711014e-03 291.16 -2.00 20.00 -2.00 316.97 0.00e+00 2.024 0.000 302.00 328.00 3 5.7589e+00 9.3045e-03 2.4473e-02 -6.0000e+00 9.4821e-02 3.0942e-02 1.0552e-02 1.3658e-02 -6.0000e+00 1.0260e-01 1.0674e-02 6.5882e-03 6.6224e-03 -6.0000e+00 6.1223e-02 -8.5440e-03 3.3926e-03 1.8237e-03 -6.0000e+00 2.6428e-02 1.5253e-04 -1.2282e-04 1.8467e-04 1.6972e-05 -6.0000e+00 1.6276e-03 3.9994e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.62 0.48 0.00400 0.00308 6 6 5 8 0 4000.000 20.00 22.62 33.18 25.58 25.90 15.5 1096.08 25920 12641 10035 -13172 56880 835 -10197 -8286 -8218 9836 -2565 -17144 5945 -2200 983 9883 -9269 -1011 16114 -11019 6844 654 -7883 1255 -722 -914 609 8812 5466 3682 4234 -1774 5460 844 -741 -7611 681 -7756 4872 156 -1465 -961 -2971 2058 -17 559 -310 2547 -8405 1 3034 1539 3959 -1327 -3400 1172 1348 543 3076 -3359 -643 1031 -1483 3000 -2079 1900 1833 834 -1000 2794 96 2098 -2853 1656 1990 -1321 841 990 1405 -399 802 -510 -941 -3175 -1393 -1379 239 -503 434 1756 -566 1261 -1153 845 -299 1801 457 537 -263 -795 1592 -467 -3038 -291 366 -1175 -659 -1633 -378 347 149 517 855 -1047 173 -164 1273 1152 515 -396 -801 533 1656 484 439 -1051 97 180 993 740 602 -702 -1530 -1544 144 337 -637 1468 -294 339 343 -348 -582 1538 957 808 -1271 2489 58 -814 -746 -845 908 -262 -2006 623 -290 146 1500 -1773 -185 2629 -2414 1313 132 -1722 266 -168 -223 147 1872 1120 741 889 -436 1374 234 -196 -2019 177 -2543 1717 67 -701 -479 -1551 1039 -9 288 -159 1249 -4464 1 1517 839 2240 -825 -2218 751 885 359 1954 -2220 -422 709 -1130 2363 -1744 1449 1282 564 -723 2213 85 1905 -2711 1477 1681 -1048 594 658 953 -307 683 -480 -941 -3343 -1519 -1599 288 -628 541 2120 -661 1341 -1149 795 -297 1911 535 684 -359 -1097 2050 -563 -3521 -336 452 -1551 -894 -2302 -546 527 238 840 1359 -1603 245 -219 1669 1562 741 -606 -1261 824 2478 711 623 -1455 127 232 1340 1072 914 -1096 -2417 -2508 242 591 -1148 2645 -540 614 604 -595 -970 SS 20240528T135139.0Z 8914.577535 240 1 5.46 2 59.39 81.29 69.46 225.81 0.00 1 0.00 1 0 17 9.329e-02 1.459e-02 8.145e-02 1.411e-02 2.636259e-01 6.981074e-03 2.862538e-03 -6.000000e+00 5.200530e-02 231.07 -2.00 3.25 -2.00 318.62 0.00e+00 9.816355e-04 1.415622e-03 2.073231e-04 -6.000000e+00 2.346541e-03 291.16 -2.00 20.00 -2.00 317.71 0.00e+00 1.956 0.000 302.00 328.00 3 3.0170e+00 1.9211e-02 2.3376e-02 -6.0000e+00 1.3006e-01 -1.1991e-01 2.2001e-02 1.2726e-02 -6.0000e+00 1.4069e-01 6.1963e-02 1.4255e-02 6.2273e-03 -6.0000e+00 8.3955e-02 -8.7799e-03 7.4334e-03 1.8525e-03 -6.0000e+00 3.6271e-02 2.7265e-03 -1.3527e-04 3.8501e-04 1.6701e-05 -6.0000e+00 2.2311e-03 -5.8440e-04 0.0000e+00 12 8 8 10 0 0 65.16 23.21 0.05 -0.00058 -0.00160 2260 2034 5 8 0 2.400 20.01 23.21 33.32 25.68 25.90 15.6 1098.27 12986 15599 23367 2692 4563 -29444 80174 -11447 3622 6532 3011 9845 5682 3219 8361 12416 -14732 13345 -14510 13255 -7335 21087 -8683 22868 -3522 2391 -2065 -8091 6546 -16150 11932 -6180 7661 -3679 4161 -8814 4700 1087 -2283 5149 -710 2324 -4217 6665 -2075 2936 -2426 -786 -5623 2104 -1605 2561 1195 -1046 3719 -4120 2873 -2382 1139 -1646 2071 29 2096 2344 -176 -1689 -1291 -53 -2811 2078 -1076 954 -1397 1186 -1942 1292 -807 -3471 1482 -3448 338 -1625 376 -399 -1244 -150 -305 1100 1387 2093 -77 975 -1601 -534 -1507 1019 -1203 829 573 86 1823 -289 -2153 -1328 967 -1570 797 -251 638 655 1804 1527 1909 80 -1350 -1789 -1470 -641 -759 457 -577 378 601 -165 -239 -527 -991 -1538 -1296 -1220 234 -933 456 -970 -358 -292 1290 1575 576 763 -646 -214 -366 726 951 1387 185 277 -2231 2468 -868 273 509 240 736 486 324 923 1468 -2323 1698 -2465 1839 -1264 2817 -1510 3164 -659 447 -404 -1599 1070 -3124 1883 -1257 1510 -847 845 -1898 945 262 -682 1686 -270 903 -1796 2612 -883 1210 -1042 -326 -2395 831 -686 1138 573 -538 1897 -2309 1556 -1359 618 -906 1124 17 1329 1603 -127 -1154 -800 -31 -1771 1436 -847 776 -1171 948 -1514 890 -509 -2099 876 -2399 257 -1393 339 -377 -1255 -162 -350 1298 1643 2416 -86 981 -1496 -469 -1399 1021 -1361 1020 765 117 2296 -339 -2390 -1495 1160 -2065 1065 -352 928 1020 2955 2577 3133 125 -1963 -2436 -1963 -883 -1120 719 -949 614 944 -252 -351 -741 -1318 -2014 -1804 -1848 371 -1525 742 -1654 -643 -556 2488 3095 1157 1512 -1251 -395 -656 SS 20240528T135144.6Z 8914.577600 240 2 5.46 2 59.37 81.30 69.48 225.83 0.00 1 0.00 1 0 17 3.263e-01 5.522e-02 1.703e-01 2.918e-02 2.464749e-01 1.455915e-02 2.704742e-03 -6.000000e+00 1.841938e-01 231.07 -2.00 3.25 -2.00 318.66 0.00e+00 4.157607e-03 2.914546e-03 5.609351e-04 -6.000000e+00 8.592105e-03 291.16 -2.00 20.00 -2.00 317.73 0.00e+00 1.955 0.000 302.00 328.00 3 3.8785e+00 4.0062e-02 2.2824e-02 -6.0000e+00 4.6135e-01 -1.3257e-01 4.5876e-02 1.1841e-02 -6.0000e+00 4.9964e-01 -4.7431e-02 2.9360e-02 6.3699e-03 -6.0000e+00 2.9582e-01 5.1901e-02 1.5220e-02 3.4626e-03 -6.0000e+00 1.2769e-01 1.2091e-03 -1.8403e-05 8.1375e-04 2.7528e-05 -6.0000e+00 8.0418e-03 -1.6947e-03 0.0000e+00 12 8 8 10 0 0 13.34 23.21 0.79 -0.00169 -0.00183 2260 2034 5 8 0 2.400 20.01 23.21 33.32 25.68 25.90 15.6 1098.27 165015 26505 900000 14460 900000 -33135 900000 -47789 900000 -26085 93194 -13335 6103 90358 3406 137470 2897 103550 -29964 107513 -25100 60002 4763 54763 16688 7270 12951 -14791 119776 -30353 104066 -28862 56087 -22133 36893 3321 38338 24096 9635 23495 -12514 16727 -10257 21351 -10896 28903 -18081 12714 621 10842 7208 5687 15085 -7605 23985 -9091 10723 -14083 13839 -13212 4265 -522 -2172 1699 -2704 5915 -9164 10485 -11705 15980 -9784 9110 -4404 6097 -1459 2741 4220 -3599 6926 -6736 8722 -10700 7237 -6730 6134 -6174 4123 448 1567 3323 -3683 5809 -5292 5034 -8417 6815 -5502 6485 -1008 -951 -835 -2116 -1108 -5573 6213 -6925 6700 -5948 9057 -1333 5575 -1458 1656 368 -182 1074 -4096 2977 -3886 3841 -2369 5060 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