File name: Pandora143s1_LibertyTX_20240601_L2Fit_fwvt1c9d20230920p1-8.txt File generation date: 20250114T000723.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240601_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240601 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1663 1812 Nominal wavelengths inside fitting window [nm]: 492.0785 492.1995 492.3206 492.4416 492.5626 492.6836 492.8046 492.9256 493.0465 493.1674 493.2883 493.4092 493.5301 493.6510 493.7718 493.8926 494.0135 494.1342 494.2550 494.3758 494.4965 494.6173 494.7380 494.8587 494.9793 495.1000 495.2206 495.3413 495.4619 495.5825 495.7030 495.8236 495.9441 496.0646 496.1852 496.3056 496.4261 496.5466 496.6670 496.7874 496.9078 497.0282 497.1486 497.2690 497.3893 497.5096 497.6299 497.7502 497.8705 497.9907 498.1110 498.2312 498.3514 498.4716 498.5917 498.7119 498.8320 498.9521 499.0722 499.1923 499.3124 499.4324 499.5525 499.6725 499.7925 499.9124 500.0324 500.1524 500.2723 500.3922 500.5121 500.6320 500.7518 500.8717 500.9915 501.1113 501.2311 501.3509 501.4706 501.5904 501.7101 501.8298 501.9495 502.0691 502.1888 502.3084 502.4281 502.5477 502.6672 502.7868 502.9064 503.0259 503.1454 503.2649 503.3844 503.5038 503.6233 503.7427 503.8621 503.9815 504.1009 504.2203 504.3396 504.4589 504.5782 504.6975 504.8168 504.9360 505.0553 505.1745 505.2937 505.4129 505.5320 505.6512 505.7703 505.8894 506.0085 506.1276 506.2467 506.3657 506.4847 506.6038 506.7227 506.8417 506.9607 507.0796 507.1985 507.3174 507.4363 507.5552 507.6740 507.7929 507.9117 508.0305 508.1493 508.2680 508.3868 508.5055 508.6242 508.7429 508.8616 508.9802 509.0989 509.2175 509.3361 509.4547 509.5732 509.6918 509.8103 509.9288 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240601T121938.2Z 8918.513637 151 1 24.00 2 78.56 70.88 37.58 136.44 0.00 1 0.00 1 0 15 3.683e-02 2.812e-02 3.060e-03 3.047e-03 1.282451e+04 2.267136e+02 8.444728e+02 -6.000000e+00 2.153680e+03 291.49 -2.00 20.00 -2.00 505.30 0.00e+00 1.020570e-03 8.649742e-05 6.685928e-05 -6.000000e+00 1.063358e-03 291.49 -2.00 20.00 -2.00 500.42 0.00e+00 3.070847e-01 6.119855e-02 7.365969e-02 -6.000000e+00 7.357983e-01 231.07 -2.00 3.25 -2.00 502.02 0.00e+00 4.873 0.001 489.00 513.00 1 8.9207e+00 4.7031e-03 9.5368e-03 -6.0000e+00 5.6634e-02 -2.4475e-03 1.1901e-03 1.8582e-03 -6.0000e+00 1.4599e-02 1.2296e-04 -2.6655e-03 2.9606e-04 7.1503e-05 -6.0000e+00 3.9279e-03 7.5237e-03 -2.1259e-05 12 8 8 10 0 0 -69.88 22.28 1.24 0.00752 -0.01097 6 6 2 2 0 4000.000 19.99 22.28 29.39 25.79 26.11 15.8 1067.88 -1580 -623 -1312 -677 -639 947 -879 299 344 -109 -256 -347 -1477 -106 -1080 -1054 43407 -3665 -311 -570 -400 -496 285 -253 40 -397 -1157 -484 -435 97 38 -837 -1184 205 -1644 -344 -1198 -18 -622 -32 244 -521 93 -1053 212 -66 608 -79 381 1182 -908 168 -674 -498 -376 -217 -186 -428 -396 426 759 92 -268 84 -125 -124 -464 265 1081 -693 57 163 204 -168 449 -603 373 -111 918 139 -467 -134 -718 -1251 -334 386 -154 -378 61 194 678 -924 234 -73 582 1003 766 -826 565 -253 -710 -648 -1431 -853 -688 -565 -471 -272 21 460 621 -539 845 418 420 418 93 427 44 487 579 -5 583 -710 1145 128 960 -948 -887 766 -222 817 355 -312 -335 -372 447 -63 -109 -561 -358 222 126 -388 140 1262 -79 -478 -68 295 -1533 -606 -1307 -686 -659 980 -932 316 363 -114 -266 -357 -1519 -107 -1094 -1071 32674 -3884 -327 -604 -425 -528 301 -269 42 -423 -1235 -509 -451 98 38 -843 -1215 213 -1753 -365 -1275 -19 -650 -33 252 -543 97 -1117 224 -70 639 -83 392 1190 -909 165 -659 -489 -375 -221 -192 -443 -411 440 781 95 -279 88 -129 -127 -470 264 1063 -684 55 159 201 -166 446 -600 364 -108 875 132 -449 -129 -697 -1227 -328 379 -152 -372 60 189 664 -919 231 -73 563 946 707 -757 505 -225 -636 -589 -1345 -822 -677 -559 -465 -267 20 448 609 -536 836 416 419 419 94 432 45 486 570 -5 564 -693 1107 125 931 -930 -868 739 -214 775 335 -294 -318 -356 431 -62 -108 -561 -360 223 127 -393 141 1253 -79 -469 -65 285 SQ 20240601T131404.5Z 8918.551441 173 1 22.14 2 67.26 76.71 30.96 157.21 0.00 1 0.00 1 0 15 2.227e-03 2.217e-03 3.843e-04 3.839e-04 6.756600e+03 2.610557e+01 4.547621e+02 -6.000000e+00 1.302217e+02 291.49 -2.00 20.00 -2.00 505.30 0.00e+00 6.636991e-04 1.089684e-05 4.875393e-05 -6.000000e+00 6.429523e-05 291.49 -2.00 20.00 -2.00 500.56 0.00e+00 9.303414e-02 7.623585e-03 4.259458e-02 -6.000000e+00 4.448886e-02 231.07 -2.00 3.25 -2.00 502.14 0.00e+00 2.566 0.000 489.00 513.00 1 5.3891e+00 5.8604e-04 5.2839e-03 -6.0000e+00 3.4243e-03 -2.8499e-02 1.4920e-04 1.0423e-03 -6.0000e+00 8.8269e-04 6.0391e-03 2.5327e-04 3.8922e-05 4.5264e-05 -6.0000e+00 2.3750e-04 1.7315e-03 1.4794e-05 12 1 1 12 1 1 99.95 23.10 1.21 0.00173 0.00349 68 84 2 2 0 320.850 20.01 23.10 32.61 25.90 26.11 15.9 1091.62 -189 -149 -24 69 181 375 465 471 400 273 180 102 -19 -49 -121 -122 350 -38 28 -69 11 173 132 232 317 46 140 80 -194 -269 -143 -210 -160 97 -93 -203 -69 16 -126 -143 -53 -8 32 192 155 193 124 4 -62 -233 -347 -430 -467 -409 -231 -198 -129 -104 73 174 280 229 173 160 136 3 -22 -46 -103 -312 -281 -261 -198 -117 -88 -335 -297 -217 -150 -239 -266 -292 -222 -111 -37 -247 -68 -75 -50 -14 71 174 286 121 134 94 -31 -89 -175 -484 -458 -459 -375 -187 -318 -348 -308 -160 -78 84 28 23 135 283 401 455 562 441 207 251 193 88 218 295 149 142 247 66 112 271 54 -55 -16 -26 -41 112 115 -109 47 203 133 179 257 120 125 1 -148 -319 -249 -266 -183 -143 -24 69 181 383 482 480 416 281 183 102 -19 -49 -121 -123 349 -39 29 -72 12 180 137 242 332 48 146 82 -195 -269 -141 -209 -159 100 -95 -210 -70 16 -129 -146 -54 -9 33 197 161 200 127 4 -63 -232 -345 -419 -452 -401 -227 -201 -130 -106 74 176 284 233 177 163 138 3 -22 -46 -101 -305 -273 -255 -195 -116 -88 -333 -291 -210 -143 -228 -255 -282 -217 -110 -37 -243 -67 -74 -50 -14 70 175 289 122 133 91 -30 -84 -166 -455 -432 -433 -367 -185 -316 -347 -305 -160 -78 83 28 23 137 289 403 459 570 449 210 250 194 88 216 292 149 141 246 66 112 268 53 -53 -15 -25 -40 109 114 -107 48 205 136 180 259 122 126 1 -149 -315 -243 -259 SQ 20240601T131924.6Z 8918.555145 176 1 12.34 2 66.14 77.27 30.52 159.63 0.00 1 0.00 1 0 22 2.376e-03 2.367e-03 1.263e-04 1.262e-04 6.459845e+03 8.510638e+00 4.331939e+02 -6.000000e+00 1.389339e+02 291.49 -2.00 20.00 -2.00 505.30 0.00e+00 6.715135e-04 3.580453e-06 4.894416e-05 -6.000000e+00 6.859625e-05 291.49 -2.00 20.00 -2.00 500.61 0.00e+00 4.274243e-02 2.495971e-03 4.163349e-02 -6.000000e+00 4.746260e-02 231.07 -2.00 3.25 -2.00 502.18 0.00e+00 2.453 0.000 489.00 513.00 1 2.6214e+00 1.9192e-04 5.1107e-03 -6.0000e+00 3.6532e-03 -3.6281e-02 4.8826e-05 1.0108e-03 -6.0000e+00 9.4164e-04 9.8138e-02 3.6667e-04 1.2821e-05 4.3859e-05 -6.0000e+00 2.5338e-04 1.5290e-03 2.0093e-05 10 0 0 10 0 0 98.99 23.08 1.20 0.00153 0.00407 452 181 1 2 0 27.100 20.00 23.08 32.90 25.90 26.11 15.9 1094.48 -182 -225 -40 86 184 475 493 471 460 321 232 105 -5 -58 -133 -119 -103 51 68 -52 33 189 160 269 324 173 117 129 -152 -343 -183 -224 -148 85 -60 -198 -65 -23 -111 -104 -32 -12 47 171 200 202 139 14 -101 -276 -418 -468 -544 -428 -237 -218 -141 -70 94 185 283 305 214 187 121 71 -55 -80 -149 -282 -278 -225 -203 -100 -126 -326 -377 -225 -178 -285 -271 -284 -283 -139 -91 -187 -151 -108 -77 -34 60 186 279 110 129 132 -57 -128 -226 -521 -508 -445 -288 -158 -365 -408 -247 -169 -76 67 50 87 200 308 408 489 553 447 286 213 198 124 242 325 85 113 280 152 174 283 98 -54 13 -81 -89 109 50 -45 97 172 162 189 234 193 76 7 -169 -303 -352 -266 -175 -217 -39 84 185 478 504 485 473 326 233 106 -5 -58 -131 -118 -102 51 69 -54 34 195 165 280 337 180 121 131 -155 -340 -182 -221 -150 87 -62 -204 -66 -23 -114 -105 -33 -12 48 176 207 209 143 14 -103 -275 -413 -453 -524 -418 -232 -220 -142 -71 96 188 288 312 219 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