File name: Pandora143s1_LibertyTX_20240825_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20241119T223800.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240825_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240825T125024.4Z 9003.535005 205 1 47.40 2 78.47 84.49 23.28 254.20 0.00 1 0.00 1 0 25 2.367e-01 6.584e-03 1.647e-01 2.752e-03 5.981469e-01 1.420465e-03 6.367227e-03 -6.000000e+00 1.310034e-01 229.26 -2.00 3.25 -2.00 320.80 0.00e+00 7.771587e-04 6.290318e-04 7.942180e-04 -6.000000e+00 6.141150e-03 294.27 -2.00 20.00 -2.00 320.05 0.00e+00 4.836 0.001 302.00 328.00 3 1.6653e+00 4.7563e-03 5.6233e-02 -6.0000e+00 3.2559e-01 -2.3568e-02 6.4062e-03 2.9463e-02 -6.0000e+00 3.5286e-01 -2.6615e-02 6.0397e-03 1.4932e-02 -6.0000e+00 2.1118e-01 8.6867e-03 2.9688e-03 4.3792e-03 -6.0000e+00 9.1644e-02 4.4544e-04 9.1613e-05 7.1222e-05 4.3937e-05 -6.0000e+00 5.7405e-03 1.7005e-02 0.0000e+00 11 8 0 10 0 0 16.45 21.66 0.25 0.01701 0.01769 82 21 5 8 0 577.960 20.00 21.66 30.74 25.79 26.00 21.1 1022.31 -7714 991 -78689 -65531 900000 -56808 -69811 -127255 -150155 -63719 -31356 -56137 -41222 33832 -7739 -22503 -41232 -20759 31759 -31946 12090 3676 -9986 -26198 2062 -16960 -4923 -16284 -13765 -12122 -5524 -6349 6563 5586 12001 -7949 -6680 -6930 2949 -1017 -1253 -1785 661 -3734 -3229 -2019 -2901 315 3894 -3616 3361 -636 3406 1049 -970 2819 594 -833 2793 -782 762 871 1356 4573 1951 1711 1495 -908 -193 1660 882 2051 125 -216 573 -1327 910 -1293 -733 232 633 -1606 -677 -2212 -865 -411 861 -43 668 1543 216 1276 -358 699 -231 -531 532 -144 -117 -784 -165 -471 -1250 -585 -213 -1454 -616 -1000 -542 394 536 -87 619 327 47 279 532 468 21 -455 -456 -93 374 45 150 450 269 791 766 386 319 -253 -104 -687 -131 -94 -150 428 151 135 100 -320 -443 -21 3 -557 -400 900000 -277 -426 -1645 -2857 -560 -207 -520 -412 206 -91 -368 -915 -415 411 -834 212 70 -227 -780 52 -554 -145 -520 -416 -376 -189 -266 285 267 512 -399 -362 -458 223 -97 -137 -212 81 -447 -389 -269 -397 43 533 -518 499 -112 633 217 -218 642 144 -206 646 -183 179 226 401 1487 694 589 493 -311 -73 728 434 1049 65 -107 259 -544 335 -482 -301 113 362 -992 -456 -1599 -659 -334 737 -38 592 1312 174 942 -252 494 -184 -493 523 -163 -147 -1002 -195 -494 -1295 -611 -226 -1661 -730 -1261 -740 559 844 -146 1033 525 71 396 755 700 33 -777 -779 -152 583 69 220 633 384 1148 1177 679 577 -483 -207 -1459 -281 -214 -347 1003 358 311 216 -687 -915 SS 20240825T125737.5Z 9003.540018 208 1 47.67 2 76.92 85.36 24.74 256.01 0.00 1 0.00 1 0 17 1.509e-01 5.633e-03 8.170e-02 1.753e-03 5.366119e-01 8.853989e-04 5.748777e-03 -6.000000e+00 8.343751e-02 229.26 -2.00 3.25 -2.00 320.29 0.00e+00 1.222911e-03 3.315986e-04 4.594796e-04 -6.000000e+00 3.845397e-03 294.27 -2.00 20.00 -2.00 319.48 0.00e+00 4.302 0.001 302.00 328.00 3 1.4494e+00 2.7473e-03 5.0111e-02 -6.0000e+00 2.0750e-01 -2.4777e-02 3.5009e-03 2.6151e-02 -6.0000e+00 2.2486e-01 -5.9772e-03 3.1394e-03 1.3134e-02 -6.0000e+00 1.3464e-01 -1.9893e-03 1.6076e-03 4.0275e-03 -6.0000e+00 5.8399e-02 9.6763e-04 -2.5146e-05 4.5200e-05 3.6223e-05 -6.0000e+00 3.6111e-03 1.6518e-02 0.0000e+00 11 1 0 11 8 0 -52.02 21.67 0.19 0.01652 0.01633 131 34 5 8 0 363.860 20.01 21.67 31.15 25.79 26.00 21.2 1026.27 -20746 6348 -26358 -35640 89092 -73509 -40460 -79711 -31654 -44462 4346 -48839 9182 -22450 7440 -13685 -10898 -3494 -3014 -7202 1236 10945 -13351 2551 -8009 4379 -3634 444 -4869 -2111 2771 -5155 5154 -2909 5408 -11296 50 -4990 2048 -3470 900 -1096 -1037 -3055 -3325 75 -3072 1870 -1953 354 -577 1698 1137 1733 -912 205 762 -845 1602 -1238 1675 1370 2012 2712 2314 273 1201 -861 671 1775 -121 1177 -423 586 -261 134 -174 -567 -656 46 -741 -923 -1411 -2204 -849 -739 461 -412 1034 910 931 1004 361 583 0 362 10 724 -302 -166 -279 -683 -1166 -44 -678 -1147 -496 -786 -268 -137 421 -59 702 202 362 62 676 219 166 -270 -563 -164 122 160 37 433 -134 1092 579 392 -23 -252 -224 -295 -82 -155 -52 233 149 -118 246 -258 -298 -129 39 -221 -321 228 -834 -358 -1239 -354 -615 42 -782 111 -433 133 -359 -310 -101 -94 -250 41 328 -527 95 -367 190 -173 20 -219 -95 137 -331 348 -231 374 -886 4 -484 232 -461 129 -173 -172 -530 -584 13 -557 329 -367 68 -123 400 295 484 -277 64 247 -279 502 -390 525 473 784 1182 1071 123 509 -373 316 898 -70 701 -255 334 -138 68 -81 -260 -330 25 -478 -679 -1144 -1763 -715 -668 438 -410 1012 864 825 820 298 480 0 354 11 860 -400 -222 -347 -758 -1269 -49 -766 -1386 -623 -1045 -383 -204 688 -96 1128 331 549 89 966 331 268 -437 -921 -274 195 249 56 619 -193 1585 890 683 -41 -473 -436 -575 -170 -343 -111 506 327 -253 522 -514 -574 SS 20240825T130325.9Z 9003.544049 211 1 47.52 2 75.67 86.07 25.93 257.35 0.00 1 0.00 1 0 17 7.461e-02 5.072e-03 3.244e-02 1.300e-03 4.968791e-01 6.505341e-04 5.333582e-03 -6.000000e+00 4.124635e-02 229.26 -2.00 3.25 -2.00 319.94 0.00e+00 9.527575e-04 2.153920e-04 3.210400e-04 -6.000000e+00 1.900947e-03 294.27 -2.00 20.00 -2.00 319.09 0.00e+00 3.951 0.001 302.00 328.00 3 1.3100e+00 1.9420e-03 4.6115e-02 -6.0000e+00 1.0258e-01 -2.8293e-02 2.3979e-03 2.4140e-02 -6.0000e+00 1.1116e-01 4.3279e-04 2.0338e-03 1.1973e-02 -6.0000e+00 6.6557e-02 -3.4705e-03 1.0617e-03 3.5863e-03 -6.0000e+00 2.8869e-02 1.6194e-03 3.6382e-05 3.3806e-05 3.2532e-05 -6.0000e+00 1.7851e-03 1.6585e-02 0.0000e+00 10 0 0 10 0 0 11.82 21.67 0.20 0.01658 0.01686 177 46 5 8 0 268.440 19.99 21.67 31.58 25.79 26.00 21.3 1029.99 -25600 12948 -23295 7838 -5642 -29842 -30820 -35435 -24964 -31337 -139 -27847 1160 -17004 3327 -6791 -967 -1699 8385 -3693 222 3598 -3080 1836 -5226 1138 -3925 628 -2952 40 -676 -33 2573 -747 280 -6186 -46 -3570 782 -2010 222 -843 -904 -2533 -1068 -83 -1697 -66 -1352 -9 278 762 484 831 143 1655 263 -585 480 -446 822 839 1901 2078 1668 -134 503 -841 413 1104 512 1170 -87 615 97 45 67 -589 -532 278 -563 -959 -1750 -1873 -1093 -557 313 -335 589 652 725 989 590 744 468 -97 96 615 58 -259 -201 -476 -992 61 -572 -1077 -672 -889 -248 256 399 195 368 104 254 160 500 146 128 -311 -407 -279 310 -14 159 291 44 933 504 332 151 -306 -353 -314 -84 -95 -173 346 288 -40 134 -332 -298 -286 115 -319 76 -56 -363 -410 -584 -430 -624 -2 -582 22 -487 96 -232 -34 -66 319 -168 10 158 -148 92 -313 68 -251 37 -172 2 -45 -3 225 -73 26 -577 -4 -426 112 -355 43 -178 -200 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