File name: Pandora143s1_LibertyTX_20240831_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20240901T062646.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240831_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240831T135403.7Z 9009.579210 134 1 24.01 2 65.37 94.69 37.73 93.25 0.00 1 0.00 1 0 17 1.185e-01 1.494e-02 4.745e-02 7.549e-03 3.073344e-01 3.695349e-03 3.339565e-03 -6.000000e+00 6.548580e-02 229.06 -2.00 3.25 -2.00 318.00 0.00e+00 -5.583112e-04 6.774963e-04 4.186217e-04 -6.000000e+00 3.015548e-03 294.05 -2.00 20.00 -2.00 317.06 0.00e+00 2.383 0.000 302.00 328.00 3 6.1892e+00 9.9805e-03 2.7970e-02 -6.0000e+00 1.6280e-01 9.5315e-02 1.1418e-02 1.4873e-02 -6.0000e+00 1.7639e-01 1.7208e-02 7.2697e-03 7.1134e-03 -6.0000e+00 1.0563e-01 -1.3254e-02 3.7962e-03 2.0331e-03 -6.0000e+00 4.5868e-02 6.5859e-05 1.7131e-03 1.9839e-04 1.7585e-05 -6.0000e+00 2.8330e-03 2.9356e-02 0.0000e+00 12 8 8 10 0 0 99.88 21.60 0.58 0.02936 0.04223 6 6 2 8 0 4000.000 19.99 21.60 31.88 25.79 26.00 21.5 1028.47 25190 22305 -8422 27838 114248 -24088 -5568 -18490 3532 -8737 35637 -10323 11493 -620 -5486 6814 -8119 -8475 20428 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-2232 -810 786 711 -3259 -1944 -3539 -2258 117 1125 1019 3440 1164 -992 1462 -1714 -297 74 -1440 578 1500 -790 -563 611 308 -4352 -824 -198 -1807 -1073 -2762 -504 1272 1567 559 1030 -1378 -516 -392 781 634 1212 659 -203 1870 1577 925 -164 -888 343 647 1603 1602 -132 -1198 -840 -1809 236 793 -2217 1489 3282 -688 394 -731 -2897 SS 20240831T150435.3Z 9009.628186 180 1 24.01 2 50.36 105.27 23.06 106.68 0.00 1 0.00 1 0 17 5.031e-02 1.733e-02 1.926e-02 7.791e-03 2.073597e-01 3.822784e-03 2.345369e-03 -6.000000e+00 2.780150e-02 229.06 -2.00 3.25 -2.00 316.59 0.00e+00 1.335659e-04 4.843925e-04 3.971472e-04 -6.000000e+00 1.280399e-03 294.05 -2.00 20.00 -2.00 315.70 0.00e+00 1.564 0.000 302.00 328.00 3 7.1566e+00 1.0033e-02 1.8482e-02 -6.0000e+00 6.9114e-02 6.7634e-02 1.1290e-02 9.9359e-03 -6.0000e+00 7.4897e-02 2.4599e-02 6.5841e-03 4.7651e-03 -6.0000e+00 4.4849e-02 -1.2119e-02 3.1921e-03 1.3788e-03 -6.0000e+00 1.9465e-02 6.6530e-05 1.3558e-03 2.0301e-04 1.4012e-05 -6.0000e+00 1.2034e-03 3.2051e-02 0.0000e+00 12 9 8 11 8 0 99.39 21.61 0.33 0.03205 0.04224 6 6 2 8 0 4000.000 20.00 21.61 33.68 25.79 26.11 21.7 1042.59 16769 2816 -4409 7294 46305 -3403 -5440 -10679 5462 -1080 1518 1265 -3717 -591 -2333 4410 -5235 -376 3115 -7190 3520 84 -3085 -3219 2573 -1129 3838 853 -2442 545 3727 -1809 6299 6354 5109 -2750 -7833 -5187 3247 1218 76 -431 -655 1151 -1288 -2634 -4220 257 -2326 -2330 1743 -2142 4743 296 -3369 1938 1012 -536 2741 -1700 -110 -359 956 3181 903 1432 1018 -1123 -2364 2950 -102 3140 -1003 884 682 -557 -70 -6192 -2179 727 2107 -2644 -676 -2062 691 811 1487 919 3118 3085 -1867 1860 -2517 -301 -2804 -1457 1485 1570 -820 -381 103 -2452 -5753 -2005 -1746 -211 80 -865 -23 395 1000 -355 912 -787 -75 456 342 249 -240 908 818 1931 1088 1676 -262 -1351 -445 -281 1835 -414 130 -37 -244 -1340 443 447 -971 205 1053 -356 970 -255 -1729 2311 482 -822 1144 4392 -482 -823 -1948 964 -212 282 233 -789 -139 -631 1215 -1619 -114 942 -2475 1128 27 -1035 -1136 918 -433 1395 299 -819 171 1176 -649 2265 2354 1768 -972 -3103 -2341 1625 713 49 -286 -446 773 -881 -1830 -2915 165 -1487 -1472 1106 -1499 3281 221 -2656 1485 797 -427 2076 -1323 -87 -300 849 2936 851 1239 805 -865 -1948 2628 -101 3130 -1034 873 640 -482 -54 -4760 -1661 601 1907 -2696 -713 -2268 783 977 1869 1193 3978 3846 -2282 2027 -2589 -292 -2903 -1614 1746 1996 -1123 -516 131 -2938 -6742 -2362 -2211 -276 108 -1210 -32 593 1556 -564 1386 -1138 -100 570 425 322 -331 1311 1213 2815 1557 2311 -353 -1762 -545 -340 2311 -564 183 -52 -349 -1986 678 715 -1600 339 1749 -589 1546 -396 -2660 SS 20240831T152308.7Z 9009.641073 189 1 24.00 2 46.52 108.64 19.37 112.47 0.00 1 0.00 1 0 25 3.487e-02 1.624e-02 1.674e-02 7.563e-03 1.937037e-01 3.720044e-03 2.068470e-03 -6.000000e+00 1.927960e-02 229.06 -2.00 3.25 -2.00 316.31 0.00e+00 6.884549e-04 4.425248e-04 2.308879e-04 -6.000000e+00 8.876798e-04 294.05 -2.00 20.00 -2.00 315.44 0.00e+00 1.451 0.000 302.00 328.00 3 7.2417e+00 9.7180e-03 1.7046e-02 -6.0000e+00 4.7930e-02 7.4542e-02 1.0908e-02 8.9372e-03 -6.0000e+00 5.1925e-02 2.8701e-02 6.3265e-03 4.3270e-03 -6.0000e+00 3.1094e-02 -1.5709e-02 3.0300e-03 1.2167e-03 -6.0000e+00 1.3509e-02 6.9682e-05 1.8861e-03 1.9614e-04 1.1144e-05 -6.0000e+00 8.3369e-04 2.6800e-02 0.0000e+00 12 8 8 10 0 0 87.62 21.66 0.85 0.02680 0.04097 6 6 2 8 0 4000.000 20.01 21.66 34.57 25.79 26.00 21.6 1047.54 9717 6301 -1350 11367 20602 5689 -1968 -8692 946 -2977 9470 565 -43 -6326 1019 -32 713 -5608 6339 -9573 4276 -94 -1653 -3291 66 2644 -1335 3732 -5612 4293 -573 2612 4031 6374 -67 -6551 -6347 -3657 3918 -500 3114 -2204 112 -1921 438 -2309 -3156 -1506 -1934 -2869 482 188 1283 846 -1752 2304 -1 1088 -477 -470 108 2628 3224 3282 2048 -505 413 -2072 -2612 1321 1986 2236 -1 911 2056 -497 -109 -4750 -4382 579 -875 -3435 -1448 -1654 442 1116 2344 801 1795 2628 -167 -957 -2945 -2334 -1371 -2331 961 919 292 -60 792 -1095 -1240 -1483 -915 -645 -684 -526 -221 -268 1304 -131 891 -468 -652 -753 1258 -1361 42 -341 831 1462 3170 383 416 -2211 -990 -407 229 539 -1054 163 -227 -751 839 26 184 1162 755 470 539 -2077 -962 1625 1186 -278 1948 2830 836 -324 -1741 195 -663 1809 116 -10 -1726 294 -10 229 -1945 2035 -3673 1486 -33 -595 -1258 26 1055 -547 1373 -2090 1399 -202 964 1580 2518 -26 -2556 -2633 -1723 2058 -313 2034 -1558 79 -1391 310 -1678 -2268 -1032 -1290 -1903 322 134 949 652 -1408 1818 -1 879 -383 -374 87 2212 2897 3108 1963 -456 336 -1645 -2197 1214 1959 2284 -1 917 1944 -438 -86 -3666 -3449 485 -820 -3559 -1550 -1825 504 1349 2945 1046 2326 3309 -202 -1073 -3057 -2309 -1402 -2598 1131 1171 394 -81 997 -1293 -1398 -1734 -1146 -847 -925 -731 -316 -401 2007 -205 1341 -668 -860 -939 1533 -1755 56 -491 1219 2113 4414 528 551 -2868 -1205 -488 288 717 -1470 227 -318 -1086 1253 41 295 1874 1231 759 846 -3214 -1445 SS 20240831T160734.5Z 9009.671927 205 1 3.77 2 37.71 118.50 11.62 138.10 0.00 1 0.00 1 0 17 6.902e-03 5.659e-03 1.929e-03 1.391e-03 1.613120e-01 6.946999e-04 1.809305e-03 -6.000000e+00 3.815984e-03 229.06 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