File name: Pandora143s1_LibertyTX_20240910_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20240911T062048.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240910_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240910 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240910T134558.1Z 9019.573589 65 1 27.95 2 68.24 97.55 150.68 91.86 0.00 1 0.00 1 0 25 1.878e-01 2.611e-02 1.298e-01 1.401e-02 3.249041e-01 6.915084e-03 3.392799e-03 -6.000000e+00 1.039587e-01 228.72 -2.00 3.25 -2.00 318.39 0.00e+00 1.409845e-03 1.429254e-03 2.749673e-04 -6.000000e+00 4.907782e-03 293.69 -2.00 20.00 -2.00 317.47 0.00e+00 2.673 0.000 302.00 328.00 3 6.7091e+00 1.8935e-02 3.0688e-02 -6.0000e+00 2.5818e-01 1.6073e-01 2.1858e-02 1.5299e-02 -6.0000e+00 2.7959e-01 2.4830e-02 1.4522e-02 7.5979e-03 -6.0000e+00 1.6756e-01 -2.5918e-02 7.6782e-03 2.8667e-03 -6.0000e+00 7.3524e-02 2.7709e-05 4.6501e-03 3.7428e-04 2.2917e-05 -6.0000e+00 4.5644e-03 1.2578e-02 0.0000e+00 12 8 8 10 0 0 99.79 21.83 0.60 0.01258 0.04752 7 7 2 8 0 3991.910 19.98 21.83 29.62 25.79 26.11 21.9 1010.15 90950 900000 -23501 -1070 900000 19561 67428 -20496 -3688 38502 160985 -33356 5339 -4339 27034 8677 -11360 17025 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-1145 -2951 1113 -2098 4797 -1151 2639 921 -1933 -1060 -3941 -1047 -3474 4434 -4147 -14 -4166 642 -83 6602 -1385 3013 1146 -1290 5000 -2377 85 -50 600 -562 366 -1546 -4551 3623 2722 -8020 358 -13 -934 2386 -3113 920 2641 -971 -1682 1353 -3093 2004 -2683 5236 959 -3060 2237 -1114 2697 1615 3181 -19 -6847 54 579 -360 244 1844 -652 2219 -2328 1291 2031 -3439 969 4720 -3508 398 743 -2776 SS 20240910T140545.4Z 9019.587331 77 1 27.16 2 64.02 100.33 146.62 93.98 0.00 1 0.00 1 0 17 3.685e-02 1.042e-02 1.904e-02 4.911e-03 2.756333e-01 2.404906e-03 3.046944e-03 -6.000000e+00 2.034268e-02 228.72 -2.00 3.25 -2.00 317.62 0.00e+00 -7.866846e-04 3.919016e-04 2.439229e-04 -6.000000e+00 9.364833e-04 293.69 -2.00 20.00 -2.00 316.68 0.00e+00 2.269 0.000 302.00 328.00 3 5.7920e+00 6.4240e-03 2.6208e-02 -6.0000e+00 5.0538e-02 5.7881e-02 7.2998e-03 1.3380e-02 -6.0000e+00 5.4778e-02 1.5139e-02 4.4767e-03 6.4295e-03 -6.0000e+00 3.2804e-02 -1.0435e-02 2.2903e-03 1.9097e-03 -6.0000e+00 1.4247e-02 1.1819e-04 1.1836e-03 1.2891e-04 1.7229e-05 -6.0000e+00 8.8125e-04 3.0234e-02 0.0000e+00 12 9 8 11 8 0 99.97 21.86 0.71 0.03023 0.03913 11 11 1 8 0 2468.900 19.99 21.86 30.38 25.79 26.11 22.1 1016.55 2846 11769 -5792 -5766 21468 11217 -12370 -3625 -14100 6455 -735 1513 8099 -1324 4688 2482 -7292 -5529 5996 -5496 1976 -885 -343 -4113 3851 5121 -483 -951 -5266 5386 -3657 2040 3133 4124 2615 -6832 -4429 -2734 1848 -291 2010 -2346 -897 -717 1727 -2937 969 -465 747 -1022 589 1478 1067 1823 -3565 2647 -1630 853 1263 413 -445 672 1601 3259 1461 -222 579 -2520 103 351 211 1508 1018 1268 63 -1605 -367 -3157 -1728 -862 -1351 -1812 -1846 -1275 -581 -101 1188 -848 1420 915 -527 613 -99 -309 280 267 961 -34 -261 -634 1350 -146 -2913 -240 -1016 -415 -172 -146 -715 1720 -131 526 705 127 -171 -1502 615 -578 724 10 -188 139 795 74 503 -857 228 360 47 478 231 50 -82 -233 -262 864 -267 205 385 -472 102 -391 -677 238 1003 -599 -566 1435 776 -1133 -354 -1738 693 -83 168 944 -195 751 447 -1500 -1155 1174 -1245 431 -196 -76 -1009 947 1307 -129 -241 -1295 1163 -903 525 874 1188 711 -1934 -1312 -936 732 -136 1002 -1266 -491 -393 926 -1649 518 -246 384 -533 318 852 652 1159 -2438 1757 -1148 589 851 275 -305 486 1242 2656 1222 -175 420 -1813 77 296 193 1414 959 1158 55 -1299 -267 -2233 -1250 -691 -1206 -1767 -1898 -1346 -643 -118 1440 -1072 1763 1116 -615 657 -98 -297 282 292 1137 -44 -358 -869 1725 -175 -3377 -281 -1282 -547 -233 -203 -1035 2585 -208 845 1104 190 -239 -2014 806 -791 1036 15 -291 212 1180 108 703 -1168 293 460 64 689 347 76 -127 -370 -434 1482 -469 365 690 -839 175 -652 -1106 SS 20240910T142243.9Z 9019.599119 86 1 27.33 2 60.42 102.85 143.14 95.66 0.00 1 0.00 1 0 17 1.059e-02 6.094e-03 5.892e-03 2.265e-03 2.461795e-01 1.113381e-03 2.714695e-03 -6.000000e+00 5.846583e-03 228.72 -2.00 3.25 -2.00 316.78 0.00e+00 1.620622e-04 1.464531e-04 5.525090e-05 -6.000000e+00 2.691156e-04 293.69 -2.00 20.00 -2.00 315.88 0.00e+00 2.017 0.000 302.00 328.00 3 4.8892e+00 2.9270e-03 2.3278e-02 -6.0000e+00 1.4525e-02 3.7343e-02 3.2944e-03 1.1757e-02 -6.0000e+00 1.5742e-02 8.6430e-03 1.9354e-03 5.7075e-03 -6.0000e+00 9.4269e-03 -6.4276e-03 9.5093e-04 1.5939e-03 -6.0000e+00 4.0962e-03 3.9425e-04 1.1029e-03 5.8733e-05 1.5325e-05 -6.0000e+00 2.5316e-04 2.7830e-02 0.0000e+00 11 1 0 11 8 0 99.96 21.87 0.13 0.02783 0.03612 18 18 1 8 0 1518.120 19.99 21.87 31.12 25.79 26.11 22.0 1021.06 1382 2776 -158 -3925 3595 -1523 -1605 -1707 -3038 230 2600 -208 1105 805 1221 -820 -1376 -18 1785 -616 1544 -1846 148 -566 736 709 29 -1080 -474 895 766 239 2030 300 -328 -3659 -2154 -611 903 -126 20 -896 -1100 -1002 -359 -1944 122 707 -1176 -570 518 1258 311 656 -547 697 509 620 270 601 346 1355 633 2134 488 -109 -120 -1514 661 1065 123 953 281 812 461 -130 -25 -1616 -112 -639 -740 -1070 -1535 -2027 -814 -754 -279 89 766 518 637 315 -9 12 167 -298 323 398 176 29 281 -660 -1057 -312 -381 -644 -50 -836 -278 409 558 197 435 -39 -123 -6 517 -145 171 -315 5 -34 127 38 492 -31 160 466 785 405 -77 -356 -161 -128 203 0 -116 483 295 54 -32 -512 -797 188 410 -24 -599 452 -187 -207 -251 -512 40 428 -35 203 169 291 -217 -379 -5 510 -186 470 -571 45 -183 250 251 10 -367 -150 271 242 82 744 116 -119 -1302 -803 -259 445 -71 12 -568 -714 -654 -232 -1282 78 440 -729 -350 328 841 219 479 -411 529 394 479 205 452 265 1088 545 1917 447 -94 -96 -1187 535 956 120 948 281 790 431 -113 -20 -1239 -87 -548 -694 -1079 -1626 -2210 -919 -896 -344 112 963 640 752 348 -9 12 173 -332 385 507 235 39 358 -793 -1218 -367 -476 -840 -67 -1149 -392 600 849 303 656 -56 -167 -8 664 -193 238 -460 8 -50 184 53 671 -41 203 586 1034 564 -111 -521 -237 -193 317 0 -192 804 495 89 -52 -811 -1239 SS 20240910T143407.8Z 9019.607034 92 1 27.36 2 58.03 104.63 140.81 96.75 0.00 1 0.00 1 0 17 8.286e-03 5.834e-03 4.119e-03 1.880e-03 2.304648e-01 9.262126e-04 2.556738e-03 -6.000000e+00 4.575993e-03 228.72 -2.00 3.25 -2.00 316.33 0.00e+00 2.113314e-04 1.097094e-04 3.679156e-05 -6.000000e+00 2.106228e-04 293.69 -2.00 20.00 -2.00 315.46 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