File name: Pandora143s1_LibertyTX_20241216_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20241217T061856.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20241216_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20241216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [�C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [�C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [�C], 999=no temperature signal Column 96: Temperature in head sensor [�C], 999=no temperature signal Column 97: Temperature at electronics board 1 [�C], 999=no temperature signal Column 98: Temperature at electronics board 2 [�C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241216T142656.4Z 9116.602042 246 1 27.46 2 76.48 127.62 88.91 301.37 0.00 1 0.00 1 0 25 1.125e+00 6.206e-02 2.262e-01 1.307e-02 4.095623e-01 6.529127e-03 7.734792e-03 -6.000000e+00 6.195618e-01 224.25 -2.00 3.25 -2.00 320.06 0.00e+00 4.452107e-02 2.073108e-03 6.563964e-03 -6.000000e+00 2.927484e-02 286.03 -2.00 20.00 -2.00 319.40 0.00e+00 4.174 0.001 302.00 328.00 3 3.9564e+00 1.9421e-02 4.6408e-02 -6.0000e+00 1.5335e+00 5.4504e-01 2.2307e-02 2.5424e-02 -6.0000e+00 1.6760e+00 -8.0627e-01 1.4256e-02 1.9378e-02 -6.0000e+00 9.9796e-01 3.8872e-01 7.6431e-03 2.5746e-02 -6.0000e+00 4.3848e-01 8.1709e-05 -1.7058e-03 3.4277e-04 3.7165e-04 -6.0000e+00 2.7679e-02 1.4093e-02 0.0000e+00 12 8 8 10 0 0 99.79 25.07 0.38 0.01409 0.00128 7 7 5 8 0 3921.930 20.00 25.07 26.78 25.90 26.11 25.1 1001.88 900000 900000 321656 922104 900000 -99124 35806 79848 83273 51490 65377 74857 900000 60673 173897 383643 122770 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11665 10165 4021 6838 2678 -6351 1398 -2655 4882 2454 2703 8113 4229 9713 8927 1255 -3239 49 2330 -362 -2540 -1280 -5136 -2513 261 -5685 860 819 3601 1506 -4136 -7095 -8579 -9829 -7818 -6624 -2598 871 -2230 -2534 -5438 -5792 -9840 -7384 -4710 -1086 -3482 1442 3941 4267 -6908 -4701 -4315 -5434 -2274 -3494 -2600 421 -817 324 5051 -3880 289 2198 3632 1444 2544 5106 6522 9192 7842 5821 5999 6187 7902 4147 5501 3693 2524 3900 2642 -1356 463 -941 -3946 -2818 -2361 -6395 -5990 -3661 -3432 SS 20241216T143219.1Z 9116.605777 249 1 27.18 2 75.57 128.48 89.86 301.99 0.00 1 0.00 1 0 17 5.414e-01 1.811e-02 1.886e-01 7.764e-03 4.457746e-01 3.854597e-03 4.814570e-03 -6.000000e+00 2.944203e-01 224.25 -2.00 3.25 -2.00 320.04 0.00e+00 -1.263254e-03 1.266398e-03 7.445273e-04 -6.000000e+00 1.355667e-02 286.03 -2.00 20.00 -2.00 319.32 0.00e+00 3.927 0.001 302.00 328.00 3 3.3089e+00 1.1392e-02 4.4555e-02 -6.0000e+00 7.2560e-01 2.7998e-02 1.3991e-02 2.2094e-02 -6.0000e+00 7.8960e-01 -4.7888e-02 1.1696e-02 1.0702e-02 -6.0000e+00 4.7215e-01 2.2266e-02 6.0404e-03 3.3951e-03 -6.0000e+00 2.0620e-01 2.3618e-04 2.9406e-04 2.0925e-04 2.9763e-05 -6.0000e+00 1.3138e-02 1.6876e-02 0.0000e+00 12 9 8 11 8 0 99.98 25.01 0.63 0.01688 0.01909 32 32 5 8 0 849.170 20.00 25.01 27.15 25.90 26.11 25.3 1004.91 -77362 148954 58251 -83066 900000 -63334 525899 -90086 -32876 -86087 28598 -65630 176418 -53485 28588 -2531 -22815 47965 59771 35096 -13750 62126 -7561 19597 -12597 9932 -2589 26813 -10121 -4238 19118 -4287 22381 13292 40950 -15784 20759 -40071 25399 1972 3292 1310 2431 3075 -610 4844 -184 18655 -9363 323 -4972 2982 4526 4455 2838 5583 9267 -7703 7825 -4222 10052 -3670 5253 1492 851 -263 7308 -1149 -4968 1790 -231 3280 -1838 3606 -2074 1327 -1951 -1800 1248 1904 -161 -2129 -468 -4174 -1567 -3420 975 562 2144 457 1457 -1421 706 670 -2229 527 -1065 1458 -759 466 -995 769 -4321 522 807 -637 -1216 -2238 -267 -774 1390 -570 1979 -1229 -19 -220 1640 213 110 576 -827 1342 -128 1682 -544 792 -230 2096 806 448 -305 -702 62 -638 80 -192 569 74 668 -584 -19 -692 -613 -2161 1128 549 -2943 900000 -1567 3981 -3558 -879 -4151 473 -2732 1335 -2770 819 -112 -1333 1525 1815 1411 -913 2001 -479 1044 -1006 687 -205 1537 -776 -304 1199 -387 1781 1247 2821 -1763 1740 -7054 2975 345 641 277 530 677 -139 1063 -42 3605 -2380 77 -1332 821 1328 1402 955 1900 3166 -3109 2662 -1567 3306 -1476 2165 704 424 -127 3069 -512 -2461 964 -140 2038 -1201 2162 -1227 689 -945 -838 596 1042 -103 -1556 -366 -3533 -1370 -3251 943 567 2137 452 1349 -1249 566 526 -1930 499 -1144 1706 -987 608 -1246 861 -4670 546 912 -775 -1542 -2993 -370 -1172 2229 -967 3267 -1995 -29 -314 2283 312 171 943 -1391 2173 -203 2566 -818 1137 -316 2820 1188 730 -535 -1278 114 -1231 162 -410 1232 164 1481 -1288 -39 -1397 -1195 SS 20241216T150930.5Z 9116.631603 264 1 4.99 2 69.55 134.83 96.25 306.60 0.00 1 0.00 1 0 21 2.071e-02 6.309e-03 1.745e-02 3.576e-03 3.286675e-01 1.728693e-03 3.654906e-03 -6.000000e+00 1.126091e-02 224.25 -2.00 3.25 -2.00 317.92 0.00e+00 -1.051222e-05 3.013461e-04 1.034260e-04 -6.000000e+00 5.097854e-04 286.02 -2.00 20.00 -2.00 317.14 0.00e+00 2.833 0.000 302.00 328.00 3 3.1968e+00 4.6208e-03 3.2164e-02 -6.0000e+00 2.7766e-02 3.0658e-04 5.2654e-03 1.5549e-02 -6.0000e+00 3.0206e-02 1.3953e-02 3.3991e-03 7.6782e-03 -6.0000e+00 1.8067e-02 -7.2821e-03 1.7866e-03 2.2025e-03 -6.0000e+00 7.8876e-03 8.6991e-04 6.5987e-04 9.2940e-05 2.0397e-05 -6.0000e+00 4.9428e-04 1.2246e-02 0.0000e+00 12 1 1 12 1 1 98.77 25.06 0.19 0.01225 0.01720 7 20 1 8 0 623.590 20.00 25.06 28.03 25.90 26.11 25.2 1010.49 2535 -5942 -6420 -9893 6461 -2128 -9764 -382 -6939 -636 -7562 453 -2992 2680 -665 2995 -1213 1892 918 -1056 -96 -1696 3343 379 -1487 -823 534 -1583 1551 -767 3480 1730 155 3438 -925 -329 -1364 -2734 -404 912 -2201 -207 -670 -212 -498 -285 -1490 -548 -1295 -1424 1389 592 1455 383 253 1562 730 -673 799 919 621 2579 640 2462 553 -46 -476 -439 -363 -500 102 187 214 664 833 -377 877 -1187 369 -542 -247 -959 -1413 -2222 -1211 -851 45 -37 304 550 -150 704 354 838 -381 584 52 347 465 -25 -480 -466 -762 -260 -83 -1232 -728 -445 -149 307 496 467 125 422 320 -1 -12 -132 521 -273 -63 -529 -169 167 533 562 -127 387 929 88 490 4 -91 -437 84 -89 -323 734 189 20 -333 -434 -526 146 -422 -482 -745 372 -123 -635 -26 -581 -54 -684 38 -293 293 -88 430 -192 304 156 -191 -18 -317 602 74 -321 -186 121 -349 314 -154 711 399 40 918 -244 -82 -359 -838 -145 376 -1017 -99 -330 -106 -248 -143 -753 -272 -640 -708 705 325 838 233 159 994 480 -449 518 585 401 1736 470 1908 446 -36 -347 -310 -268 -410 90 171 196 595 713 -302 644 -844 266 -434 -218 -916 -1430 -2328 -1312 -966 54 -45 368 656 -173 757 358 818 -391 640 61 442 625 -34 -630 -572 -887 -306 -103 -1615 -974 -612 -211 455 769 739 196 637 458 -1 -17 -184 756 -416 -98 -815 -255 246 764 783 -171 514 1291 130 756 6 -145 -712 142 -155 -577 1318 343 35 -587 -742 -880 SS 20241216T151528.3Z 9116.635745 267 1 4.28 2 68.65 135.93 97.24 307.39 0.00 1 0.00 1 0 17 2.046e-02 6.764e-03 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