File name: Pandora143s1_LibertyTX_20250102_L2Fit_fwvt1c8d20230920p1-8.txt
File generation date: 20250103T063330.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c8p1-8
Local principal investigator: Yuxuan Wang
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 143
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora143_OF_v1d20230920.txt
Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt
Level 1 file used: Pandora143s1_LibertyTX_20250102_L1_smca1c8d20230920p1-8.txt
Full location name: Sam Houston Regional Library and Research Center
Short location name: LibertyTX
Country of location: United States
Location latitude [deg]: 30.0965
Location longitude [deg]: -94.7635
Location altitude [m]: 3
Local noon date: 20250102
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OOB session based on  clearance session 7
First and last pixel inside fitting window: 1663 1812
Nominal wavelengths inside fitting window [nm]: 492.1080 492.2291 492.3501 492.4712 492.5922 492.7133 492.8343 492.9552 493.0762 493.1972 493.3181 493.4390 493.5599 493.6808 493.8017 493.9225 494.0434 494.1642 494.2850 494.4058 494.5265 494.6473 494.7680 494.8887 495.0094 495.1301 495.2508 495.3714 495.4921 495.6127 495.7333 495.8539 495.9744 496.0950 496.2155 496.3361 496.4566 496.5770 496.6975 496.8180 496.9384 497.0588 497.1792 497.2996 497.4199 497.5403 497.6606 497.7809 497.9012 498.0215 498.1418 498.2620 498.3823 498.5025 498.6227 498.7429 498.8630 498.9832 499.1033 499.2234 499.3435 499.4636 499.5836 499.7037 499.8237 499.9437 500.0637 500.1837 500.3037 500.4236 500.5435 500.6634 500.7833 500.9032 501.0231 501.1429 501.2627 501.3826 501.5023 501.6221 501.7419 501.8616 501.9813 502.1010 502.2207 502.3404 502.4601 502.5797 502.6993 502.8189 502.9385 503.0581 503.1776 503.2972 503.4167 503.5362 503.6557 503.7752 503.8946 504.0140 504.1335 504.2529 504.3723 504.4916 504.6110 504.7303 504.8496 504.9689 505.0882 505.2075 505.3267 505.4459 505.5652 505.6843 505.8035 505.9227 506.0418 506.1610 506.2801 506.3992 506.5182 506.6373 506.7563 506.8754 506.9944 507.1134 507.2323 507.3513 507.4702 507.5892 507.7081 507.8270 507.9458 508.0647 508.1835 508.3023 508.4211 508.5399 508.6587 508.7774 508.8962 509.0149 509.1336 509.2523 509.3709 509.4896 509.6082 509.7268 509.8454 509.9640
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250102T133349.9Z 9133.565161 41 1 6.75 2 87.32 118.47 115.45 99.39 0.00 1 0.00 1 0 22 6.736e-03 6.668e-03 2.500e-03 2.494e-03 1.371302e+04 1.777218e+02 8.979796e+02 -6.000000e+00 3.844314e+02 285.35 -2.00 20.00 -2.00 505.40 0.00e+00 2.411816e-03 7.026577e-05 1.437449e-04 -6.000000e+00 1.916001e-04 285.35 -2.00 20.00 -2.00 500.94 0.00e+00 6.871151e-01 4.842194e-02 9.283394e-02 -6.000000e+00 1.338439e-01 224.31 -2.00 3.25 -2.00 502.46 0.00e+00 14.277 0.036 489.00 513.00 1 5.5332e+00 3.7114e-03 2.2806e-02 -6.0000e+00 1.0286e-02 -3.9855e-02 9.2963e-04 2.5038e-03 -6.0000e+00 2.6509e-03 9.0657e-04 7.4775e-04 2.4177e-04 1.0588e-04 -6.0000e+00 7.1759e-04 1.4699e-02 -2.5332e-04 12 9 9 12 1 1 999.00 21.90 3.86 0.01470 0.01989 2 12 1 2 0 2249.550 20.00 21.90 13.41 25.58 25.90 24.4 908.11 -1305 -1120 -470 -90 417 817 1207 1361 879 842 277 -184 -784 -78 -451 -483 454 180 678 -118 -457 655 876 464 548 83 264 182 -953 -1077 -308 -1141 -633 424 63 204 -82 24 -68 -256 333 227 422 648 353 325 532 506 215 -488 -1573 -1176 -1270 -1062 -236 206 494 582 1031 534 506 939 743 1203 392 149 -424 -84 -666 -934 -671 -573 -596 -508 -22 -841 -630 -738 -390 -1186 -1012 -1174 -1153 -432 -164 -176 -317 -485 -265 -79 568 1105 631 630 829 684 -25 -636 -891 -1333 -934 -1191 -776 -77 156 -410 -190 -518 -563 109 45 327 619 517 1168 1379 778 1121 628 632 -73 229 552 217 739 223 778 -66 405 259 41 -426 -294 -651 -711 -135 -61 -131 394 321 -8 763 387 596 337 386 -521 -820 -994 -833 -1193 -1011 -436 -86 394 788 1179 1338 866 821 268 -177 -748 -74 -425 -459 436 173 660 -117 -457 651 872 466 537 82 258 181 -940 -1037 -291 -1098 -624 414 64 206 -82 24 -67 -253 329 227 427 663 355 328 533 516 216 -483 -1535 -1122 -1210 -1025 -233 208 493 587 1037 541 515 957 762 1227 400 150 -424 -83 -654 -912 -671 -559 -588 -507 -22 -838 -617 -714 -385 -1175 -975 -1141 -1133 -426 -164 -177 -319 -488 -265 -79 570 1117 626 637 817 654 -24 -601 -829 -1235 -869 -1143 -752 -75 157 -419 -194 -526 -572 111 46 333 632 532 1201 1429 821 1189 650 663 -76 234 559 222 756 231 802 -69 420 268 42 -435 -297 -659 -729 -140 -63 -137 419 337 -8 814 416 641 363 411 -552 -858 -1060 -867
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SQ 20250102T134425.7Z 9133.572520 46 1 47.62 2 85.32 119.87 113.27 100.47 0.00 1 0.00 1 0 22 3.619e-03 3.594e-03 1.348e-04 1.346e-04 1.061721e+04 9.335049e+00 7.011998e+02 -6.000000e+00 2.065575e+02 285.35 -2.00 20.00 -2.00 505.36 0.00e+00 1.655625e-03 3.784397e-06 1.049453e-04 -6.000000e+00 1.029281e-04 285.35 -2.00 20.00 -2.00 500.80 0.00e+00 6.541551e-01 2.632989e-03 7.345639e-02 -6.000000e+00 7.187657e-02 224.31 -2.00 3.25 -2.00 502.34 0.00e+00 10.286 0.013 489.00 513.00 1 2.7040e+00 2.0207e-04 1.6325e-02 -6.0000e+00 5.5243e-03 -3.2654e-02 5.0837e-05 1.9256e-03 -6.0000e+00 1.4228e-03 2.7615e-02 -7.1735e-05 1.3304e-05 8.1565e-05 -6.0000e+00 3.8531e-04 5.5321e-03 -1.6317e-04 10 0 0 10 0 0 98.65 21.90 1.50 0.00553 0.00503 558 145 1 2 0 85.330 19.99 21.90 13.63 25.58 25.90 24.2 908.35 -586 -440 -154 74 249 590 675 664 626 419 274 110 -129 -259 -318 -319 -79 115 153 32 111 193 220 375 432 307 242 178 -251 -527 -479 -488 -180 175 59 -65 8 -10 -178 -153 -41 48 195 329 383 389 272 144 -19 -327 -573 -717 -825 -605 -237 -79 -1 97 162 266 398 438 395 350 267 104 -51 -131 -235 -421 -459 -422 -294 -101 -121 -383 -538 -472 -399 -517 -459 -452 -426 -243 -163 -255 -203 -180 -176 -56 90 313 472 355 300 202 -37 -199 -444 -840 -828 -709 -302 -9 -202 -318 -352 -344 -226 -23 46 154 344 491 630 728 831 743 448 310 200 126 257 425 274 213 333 187 212 336 52 -197 -184 -272 -259 54 29 -18 165 280 207 272 284 235 189 3 -252 -522 -575 -487 -538 -412 -145 72 242 586 665 659 620 412 272 108 -126 -249 -306 -309 -78 113 154 32 112 194 222 380 439 312 244 178 -252 -515 -462 -475 -180 176 60 -66 8 -10 -180 -154 -42 48 197 336 394 402 280 147 -19 -327 -559 -703 -807 -586 -235 -79 -1 99 166 273 401 443 402 355 269 106 -51 -130 -231 -411 -456 -412 -290 -101 -122 -382 -528 -467 -391 -506 -451 -438 -417 -240 -163 -251 -200 -177 -173 -55 89 314 475 355 294 196 -36 -188 -414 -796 -772 -678 -293 -9 -201 -320 -352 -343 -225 -23 47 158 348 498 643 749 863 776 467 320 203 126 261 424 275 215 337 189 214 338 52 -199 -184 -272 -261 54 30 -19 171 289 215 285 299 248 199 3 -260 -541 -590 -501
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