File name: Pandora143s1_LibertyTX_20250103_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20250104T063648.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250103_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250103T144155.0Z 9134.612443 73 1 26.67 2 75.02 128.16 109.41 95.80 0.00 1 0.00 1 0 25 2.024e-01 1.021e-02 1.347e-01 5.362e-03 4.525474e-01 2.644352e-03 4.942621e-03 -6.000000e+00 1.101375e-01 224.31 -2.00 3.25 -2.00 319.82 0.00e+00 4.344661e-05 8.253427e-04 7.206397e-04 -6.000000e+00 4.968764e-03 285.30 -2.00 20.00 -2.00 319.12 0.00e+00 3.794 0.001 302.00 328.00 3 3.0085e+00 7.6704e-03 4.3522e-02 -6.0000e+00 2.7167e-01 2.5873e-02 9.3044e-03 2.2036e-02 -6.0000e+00 2.9551e-01 -1.8225e-03 7.8860e-03 1.0957e-02 -6.0000e+00 1.7667e-01 -4.3979e-03 4.1440e-03 3.1746e-03 -6.0000e+00 7.7111e-02 3.5176e-04 2.5759e-05 1.4171e-04 3.0484e-05 -6.0000e+00 4.8296e-03 8.6230e-03 0.0000e+00 12 8 8 10 0 0 99.97 22.29 0.36 0.00862 0.00882 24 24 5 8 0 1111.050 20.00 22.29 21.28 25.79 26.11 25.2 965.99 43732 25546 -27381 -42193 191147 -19427 -65832 -26890 -6166 -36673 -26392 -31842 25134 -16327 7269 -15529 -8426 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-2379 -255 226 -11 927 984 -265 96 -483 644 218 -599 59 119 -1090 480 470 -251 -2463 -322 -1072 -1277 -942 -1030 -1184 740 280 1337 1201 -1241 -103 -270 1897 782 -104 -82 -312 318 832 680 -583 1090 224 1440 307 911 76 285 -1379 -907 -303 -286 -834 1248 1191 -496 612 -788 -1184 SS 20250103T144816.6Z 9134.616859 75 1 14.80 2 73.95 129.19 108.09 96.50 0.00 1 0.00 1 0 17 1.128e-01 1.138e-02 1.060e-01 7.323e-03 4.268273e-01 3.591767e-03 4.733232e-03 -6.000000e+00 6.137319e-02 224.31 -2.00 3.25 -2.00 319.18 0.00e+00 -3.784235e-04 9.189702e-04 3.355992e-04 -6.000000e+00 2.816307e-03 285.30 -2.00 20.00 -2.00 318.45 0.00e+00 3.555 0.001 302.00 328.00 3 4.4555e+00 1.0008e-02 4.0810e-02 -6.0000e+00 1.5132e-01 6.2173e-02 1.1793e-02 2.0569e-02 -6.0000e+00 1.6466e-01 8.3737e-03 9.2162e-03 1.0170e-02 -6.0000e+00 9.8416e-02 -1.3031e-02 4.9314e-03 3.0039e-03 -6.0000e+00 4.2961e-02 1.0463e-04 -1.0042e-03 1.9160e-04 2.7650e-05 -6.0000e+00 2.7379e-03 1.4947e-02 0.0000e+00 12 9 9 12 1 1 96.30 22.26 0.32 0.01495 0.00740 3 7 2 8 0 3698.580 20.00 22.26 21.49 25.79 26.11 25.2 968.09 57112 51861 -7608 -72701 900000 -111 -25955 -33083 15814 -13191 -27974 -9203 11216 -18146 17387 -17237 -727 -593 23508 9987 -7773 7116 7481 -3738 10144 4507 -3760 -4533 -450 -1765 2462 8057 11233 11482 8436 -4213 3431 -3917 3760 -1386 791 -1371 -1250 1474 -2860 -2917 -1024 756 -6866 -5963 2084 -1696 5775 2567 -1319 829 1883 -3806 1864 -761 1367 -847 1680 2337 -2296 -1740 2452 -580 -906 3621 2686 1585 -1352 2633 -485 1541 2368 -2255 222 3123 1096 -1815 -635 -2470 -1351 -2059 878 131 738 1834 -456 877 -839 39 -675 -1075 -491 1053 -336 896 -638 92 -2950 -1405 -503 -1068 -600 -872 -107 -228 974 251 883 -118 1104 407 -71 -148 -996 1089 -806 -210 353 620 188 423 -6 1628 1523 -155 207 141 -929 -291 332 -67 -678 326 280 -348 176 -210 -459 619 693 -193 -3403 900000 -2 -682 -1083 378 -457 -1137 -320 369 -957 790 -1265 -50 -43 1456 740 -712 565 598 -359 941 473 -436 -509 -46 -179 260 929 1426 1583 1152 -611 485 -694 761 -352 221 -416 -394 463 -935 -967 -335 242 -2375 -2083 718 -663 2280 1110 -617 394 915 -1958 895 -365 648 -436 930 1409 -1508 -1097 1398 -330 -546 2385 1962 1224 -1076 1970 -353 1008 1404 -1330 133 2061 831 -1554 -578 -2372 -1344 -2179 954 148 831 2014 -485 865 -785 35 -645 -1131 -564 1310 -454 1218 -841 111 -3399 -1603 -608 -1366 -788 -1187 -150 -343 1544 414 1442 -188 1645 581 -101 -216 -1523 1722 -1313 -336 548 939 278 606 -8 2191 2179 -242 342 239 -1609 -518 614 -130 -1340 648 561 -694 338 -389 -826 SS 20250103T150158.5Z 9134.626372 77 1 47.87 2 71.69 131.50 105.23 98.01 0.00 1 0.00 1 0 17 1.509e-02 4.943e-03 2.589e-03 3.565e-04 3.802309e-01 1.728548e-04 4.190090e-03 -6.000000e+00 8.218447e-03 224.31 -2.00 3.25 -2.00 318.46 0.00e+00 6.154273e-04 3.555789e-05 1.159387e-04 -6.000000e+00 3.706156e-04 285.30 -2.00 20.00 -2.00 317.71 0.00e+00 3.142 0.000 302.00 328.00 3 5.9202e-01 4.6739e-04 3.6045e-02 -6.0000e+00 2.0272e-02 1.1002e-02 5.3674e-04 1.8014e-02 -6.0000e+00 2.2047e-02 -4.2326e-03 3.7318e-04 8.9293e-03 -6.0000e+00 1.3181e-02 -1.6718e-03 2.0026e-04 2.6799e-03 -6.0000e+00 5.7564e-03 8.1109e-03 4.0721e-04 9.2080e-06 2.3889e-05 -6.0000e+00 3.6013e-04 4.8517e-03 0.0000e+00 10 0 0 10 0 0 69.32 22.31 0.18 0.00485 0.00791 1008 262 2 8 0 47.250 19.99 22.31 22.06 25.79 26.11 25.5 974.90 -2020 -4028 -1675 -5214 -5045 -8529 -4210 -4194 -946 -2650 -4547 -4424 -3059 -1163 -797 339 -1044 180 83 797 482 -331 171 686 40 -530 -576 -1532 -1218 -1396 886 561 1715 725 -2274 -2478 -2235 -1356 -252 79 -578 -775 -827 -718 -359 12 -456 -60 -444 -479 610 793 559 847 434 553 876 399 302 282 302 1110 1140 1822 958 -199 -143 -739 202 912 334 527 74 467 483 112 135 -637 -356 -224 -750 -888 -1545 -2006 -1332 -996 -325 -170 231 575 591 691 319 402 445 281 64 580 501 -53 -175 -584 -594 -117 -45 -904 -574 -695 -332 139 304 337 227 176 98 100 303 110 213 -7 -339 -282 92 114 262 545 -129 653 601 348 129 -259 -306 -170 -40 0 -207 364 289 50 -4 -350 -537 -72 -171 -74 -234 -221 -355 -174 -200 -51 -143 -252 -247 -193 -87 -72 35 -118 21 10 104 66 -45 23 99 6 -91 -100 -258 -192 -215 143 104 355 164 -507 -517 -487 -344 -72 27 -224 -322 -331 -292 -146 5 -187 -24 -195 -197 263 376 287 464 250 328 497 229 183 166 180 654 748 1312 732 -146 -97 -482 138 669 277 461 65 398 386 86 93 -416 -240 -173 -632 -791 -1512 -2068 -1361 -1093 -379 -206 265 679 654 742 313 378 444 298 77 733 663 -72 -237 -711 -697 -138 -55 -1185 -783 -942 -472 204 483 535 356 274 148 140 416 157 309 -11 -548 -448 141 168 389 773 -173 900 851 522 210 -416 -501 -290 -69 1 -394 671 539 93 -8 -612 -947 SS 20250103T151913.1Z 9134.638346 87 1 47.96 2 68.96 134.57 101.65 99.91 0.00 1 0.00 1 0 17 1.030e-02 5.036e-03 1.493e-03 3.055e-04 3.364193e-01 1.478178e-04 3.734143e-03 -6.000000e+00 5.606845e-03 224.31 -2.00 3.25 -2.00 317.90 0.00e+00 4.324723e-04 2.568775e-05 8.487313e-05 -6.000000e+00 2.528424e-04 285.30 -2.00 20.00 -2.00 317.14 0.00e+00 2.759 0.000 302.00 328.00 3 7.4566e-01 3.9380e-04 3.1696e-02 -6.0000e+00 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