File name: Pandora143s1_LibertyTX_20250131_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20250201T063725.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250131_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250131T135559.4Z 9162.580549 52 1 16.84 2 81.61 115.54 100.94 95.58 0.00 1 0.00 1 0 25 7.514e-01 3.968e-02 3.519e-01 1.813e-02 7.066401e-01 9.967615e-03 7.848149e-03 -6.000000e+00 4.218281e-01 224.79 -2.00 3.25 -2.00 321.46 0.00e+00 -1.969064e-03 5.043217e-03 5.986346e-03 -6.000000e+00 2.379751e-02 284.67 -2.00 20.00 -2.00 320.91 0.00e+00 6.441 0.003 302.00 328.00 3 1.6971e+00 3.5739e-02 8.1063e-02 -6.0000e+00 1.0496e+00 4.9015e-01 4.8527e-02 6.1670e-02 -6.0000e+00 1.1518e+00 -6.9534e-01 4.3613e-02 2.2261e-02 -6.0000e+00 6.7649e-01 2.8775e-01 2.0667e-02 7.7053e-03 -6.0000e+00 3.0581e-01 7.7918e-05 2.7068e-05 4.9164e-04 6.8744e-05 -6.0000e+00 1.9309e-02 2.1548e-03 0.0000e+00 12 9 9 12 1 1 99.05 22.39 0.41 0.00215 0.00236 5 10 5 8 0 2806.040 20.00 22.39 19.98 25.90 26.21 25.5 1021.74 900000 900000 900000 900000 900000 900000 -175485 900000 -185486 900000 900000 -48899 -12186 -103646 186811 43794 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5023 5341 6236 2997 5010 -966 554 5140 4026 2388 -2301 3869 3557 924 5247 6226 2937 4187 4568 6597 4156 -621 3889 1371 650 1555 2291 2359 2615 1834 293 864 -2631 -5307 -56 -1329 4362 5023 2195 -5957 -2651 -1529 -2922 574 -1073 358 -5895 -2277 -2428 2673 540 -9768 -3870 -3444 -3125 -8628 -210 -4935 1228 -2654 81 584 -1 6573 -3675 2497 -1296 -709 267 -352 3986 6286 2707 -491 4758 3973 5085 2798 5400 -229 3263 -2205 -600 2559 2615 -6136 -898 3005 -3343 -1555 -896 -3791 SS 20250131T141115.0Z 9162.591146 57 1 47.48 2 78.66 117.71 97.74 97.32 0.00 1 0.00 1 0 25 2.415e-01 7.602e-03 1.379e-01 2.787e-03 5.742978e-01 1.423389e-03 6.102112e-03 -6.000000e+00 1.317883e-01 224.79 -2.00 3.25 -2.00 320.60 0.00e+00 -3.367910e-04 5.786866e-04 3.417443e-04 -6.000000e+00 6.204103e-03 284.67 -2.00 20.00 -2.00 319.97 0.00e+00 4.911 0.001 302.00 328.00 3 1.2325e+00 4.4666e-03 5.6042e-02 -6.0000e+00 3.2542e-01 3.7239e-03 5.9040e-03 2.7981e-02 -6.0000e+00 3.5378e-01 -1.2821e-02 5.8305e-03 1.4418e-02 -6.0000e+00 2.1180e-01 2.0921e-03 2.9078e-03 4.3401e-03 -6.0000e+00 9.3609e-02 6.4254e-04 2.9008e-04 7.2663e-05 4.0451e-05 -6.0000e+00 5.9490e-03 3.3020e-03 0.0000e+00 11 8 0 10 0 0 99.84 22.37 0.29 0.00330 0.00548 83 22 5 8 0 571.930 20.00 22.37 20.47 25.90 26.21 25.6 1025.95 -76849 900000 -18589 900000 900000 14265 -78402 -95016 -102870 -85290 49608 -82998 42817 -82081 66633 -48071 22402 -39986 57187 -19470 30225 23894 -29232 11671 -13997 10530 -23903 30815 -17267 10462 -18265 5403 3063 30933 7177 -16082 9241 -28683 5833 -5538 308 172 1645 -5186 5595 -143 -1270 8098 -6882 -391 -273 4403 2446 3890 -550 3926 453 -2044 3047 -1605 1314 -971 1874 1344 2073 -181 3702 -1152 1382 376 1025 1030 -629 2069 2 -94 -834 931 -335 1637 469 -415 -1434 -2372 -1703 -1229 -147 -57 902 763 751 242 449 1029 783 -23 -39 17 -169 67 -177 -57 -1845 303 -725 -812 -1197 -540 -639 20 198 308 517 -55 616 -68 808 -68 -130 -260 -511 -300 218 342 86 646 -39 1237 479 414 -62 220 -281 -107 -199 166 -641 343 286 -55 -10 -417 -129 -531 900000 -96 900000 900000 46 -678 -1150 -1601 -1243 196 -1312 233 -1821 461 -1165 332 -1113 720 -516 560 472 -920 294 -472 330 -1001 792 -629 318 -769 238 149 1390 366 -976 460 -2487 452 -592 36 22 218 -756 737 -20 -186 1100 -1123 -63 -48 833 523 894 -141 1013 127 -595 821 -439 351 -287 612 464 770 -67 1360 -408 516 167 512 546 -342 1050 1 -40 -326 376 -136 769 263 -270 -1049 -1859 -1307 -1008 -127 -51 810 668 618 200 344 774 646 -20 -40 20 -208 85 -212 -65 -1925 306 -804 -970 -1401 -662 -844 29 304 505 852 -88 916 -102 1182 -105 -200 -428 -853 -483 335 544 132 951 -54 1701 738 686 -113 426 -533 -213 -426 359 -1430 770 650 -122 -21 -872 -256 SS 20250131T141758.9Z 9162.595821 60 1 47.67 2 77.37 118.70 96.34 98.09 0.00 1 0.00 1 0 25 9.848e-02 4.594e-03 3.774e-02 1.229e-03 5.258557e-01 6.102671e-04 5.654668e-03 -6.000000e+00 5.372269e-02 224.79 -2.00 3.25 -2.00 320.09 0.00e+00 8.465288e-04 2.113801e-04 2.485646e-04 -6.000000e+00 2.411421e-03 284.67 -2.00 20.00 -2.00 319.44 0.00e+00 4.448 0.001 302.00 328.00 3 2.9113e-01 1.8108e-03 5.0854e-02 -6.0000e+00 1.3269e-01 5.6124e-04 2.2629e-03 2.5398e-02 -6.0000e+00 1.4426e-01 2.3744e-03 2.0952e-03 1.2889e-02 -6.0000e+00 8.6184e-02 -4.9957e-03 1.0838e-03 4.1597e-03 -6.0000e+00 3.7586e-02 2.6663e-03 2.7243e-04 3.1662e-05 3.6917e-05 -6.0000e+00 2.3494e-03 3.1697e-03 0.0000e+00 10 0 0 10 0 0 98.31 22.36 0.17 0.00317 0.00522 227 59 5 8 0 209.990 20.01 22.36 20.66 25.90 26.21 25.6 1027.21 -52002 -7868 -30338 -15980 13410 -32832 -23720 -53831 -25244 -34443 -9914 -34951 -14011 -25102 -1882 -11185 2598 -6373 3236 -5232 -2431 3295 -7050 360 -4777 -1538 -5474 1178 -3472 -3994 -561 380 1551 2215 844 -8286 23 -8309 51 211 -260 -1023 -572 -1908 -351 250 -70 1699 -1660 -252 -156 1885 760 1516 231 868 910 -579 783 -408 264 -73 1100 1553 1394 -129 888 -373 554 1418 465 789 -93 398 166 -69 -463 -357 -85 28 -203 -855 -1314 -1900 -1422 -1113 40 -106 376 694 669 687 348 770 509 167 131 525 235 -144 -63 -477 -435 -183 -271 -967 -559 -641 -380 94 286 292 429 56 238 151 458 33 -127 -222 -550 -222 -14 161 127 557 -144 787 634 224 152 -147 -320 -211 -145 25 -296 296 238 -54 60 -108 -286 -536 -63 -334 -153 87 -315 -219 -787 -327 -541 -126 -599 -233 -539 -40 -316 72 -210 106 -198 -94 120 -290 15 -234 -79 -300 59 -173 -201 -31 25 116 183 69 -696 2 -873 6 31 -44 -191 -103 -357 -65 51 -15 353 -367 -57 -35 467 210 450 74 288 315 -206 268 -137 89 -27 450 715 693 -63 406 -170 269 739 276 496 -60 243 94 -38 -232 -172 -44 16 -133 -643 -1020 -1569 -1240 -1040 40 -110 387 696 629 596 281 652 436 165 138 628 314 -187 -83 -559 -490 -204 -308 -1189 -715 -865 -513 140 444 482 710 89 376 223 663 50 -206 -362 -915 -358 -22 256 195 816 -200 1075 959 364 271 -261 -587 -408 -299 52 -637 643 523 -118 123 -218 -553 SS 20250131T142352.0Z 9162.599907 62 1 47.56 2 76.26 119.58 95.11 98.76 0.00 1 0.00 1 0 17 7.000e-02 4.733e-03 2.179e-02 9.891e-04 4.907389e-01 4.882238e-04 5.311858e-03 -6.000000e+00 3.818930e-02 224.79 -2.00 3.25 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