File name: Pandora143s1_LibertyTX_20250317_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20250318T063444.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250317_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250317 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 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5788 900000 900000 7175 900000 900000 -12260 900000 4272 900000 -1102 -21556 6769 -142 8243 7758 8291 9004 10371 4548 8199 2301 10367 2012 6932 6888 3603 6549 9915 11707 3953 7920 -7895 3120 8234 13488 -580 9048 12848 1764 1853 -1056 8924 -3696 3402 -6095 2087 -4588 -633 3221 2121 -24340 -2665 -4085 -7442 -3708 -7281 -1188 -2448 -5545 -2253 4627 -11678 18498 -9113 11950 3885 -8820 790 -8152 16639 6667 13943 -4167 1252 1032 3007 10098 -2311 4396 -4892 -1977 -2719 19251 -2410 -7623 -8480 7943 -3853 5931 -579 -6717 SS 20250317T131030.9Z 9207.548969 198 1 36.46 2 81.24 96.43 81.10 245.79 0.00 1 0.00 1 0 25 6.466e-01 2.822e-02 3.015e-01 1.035e-02 8.047102e-01 5.920236e-03 8.329088e-03 -6.000000e+00 3.707390e-01 227.22 -2.00 3.25 -2.00 321.74 0.00e+00 2.989458e-03 3.280973e-03 1.376341e-03 -6.000000e+00 1.915453e-02 285.87 -2.00 20.00 -2.00 321.21 0.00e+00 6.203 0.003 302.00 328.00 3 2.0788e+00 2.2560e-02 7.3736e-02 -6.0000e+00 9.2795e-01 4.9999e-01 3.2969e-02 4.1509e-02 -6.0000e+00 1.0197e+00 -7.0353e-01 3.1863e-02 2.2682e-02 -6.0000e+00 6.0280e-01 2.8519e-01 1.4489e-02 7.5240e-03 -6.0000e+00 2.6146e-01 5.8156e-05 -6.1358e-04 2.7352e-04 8.5851e-05 -6.0000e+00 1.6564e-02 -5.3690e-04 0.0000e+00 12 8 8 10 0 0 9.39 22.33 0.41 -0.00054 -0.00515 16 8 5 8 0 2278.380 20.00 22.33 13.80 25.79 26.11 26.2 967.35 900000 900000 900000 -122551 900000 900000 -212230 -264567 -49494 -170246 -147689 -152076 -121337 -119858 900000 900000 -106584 -101441 900000 900000 252198 900000 6423 900000 -107293 900000 58618 36014 900000 900000 900000 79548 900000 900000 900000 -58445 195715 256291 59131 35639 -6025 -3230 22848 51842 24721 16996 31878 91553 -1220 555 29309 25441 64472 30804 35006 62375 39739 -21948 44614 -2076 54078 -628 -16280 18560 15701 20875 38827 26562 8971 26358 1045 14305 3590 11510 -1950 5378 1471 -3821 17558 1224 10279 4192 1355 -6215 352 -2668 5322 -3524 615 4781 3831 738 -222 4313 -503 -436 -5559 -1970 -4390 -3072 -35 1646 -5902 -4589 -2293 -4063 661 -2767 -1498 -3184 -1301 -944 -854 -1072 2535 276 2805 1084 -855 -115 -733 3470 1471 3177 -302 -1 2683 1813 3518 2022 -108 295 349 -29 1162 -771 -543 181 474 -1227 213 -825 -1700 900000 900000 900000 -1396 900000 900000 -4719 -10920 -498 -3348 -2373 -2745 -2036 -2591 900000 900000 -3576 -3545 900000 900000 2536 900000 85 900000 -5040 900000 589 425 900000 900000 900000 923 900000 900000 900000 -2996 1968 2577 1467 1333 -380 -213 1228 2146 1324 995 1654 2777 -95 45 2018 2062 3976 2852 3318 4752 3893 -3860 3987 -276 4202 -89 -3089 2921 2791 3520 5378 4236 1865 5445 306 3880 1070 2999 -524 1196 312 -863 3616 356 3271 1634 605 -3161 177 -1469 2868 -2141 359 2608 1988 369 -108 2058 -284 -289 -4492 -1771 -4517 -3232 -35 1408 -4813 -3631 -1910 -3672 597 -2733 -1598 -3918 -1773 -1389 -1287 -1595 3511 374 3718 1522 -1290 -179 -1143 4988 2056 4293 -411 -2 3303 2296 4979 3338 -200 580 716 -64 2666 -1891 -1350 452 1186 -3034 491 -1785 -3524 SS 20250317T132302.6Z 9207.557669 203 1 47.63 2 78.55 98.06 83.54 247.44 0.00 1 0.00 1 0 25 2.898e-01 5.379e-03 1.741e-01 2.134e-03 6.598088e-01 1.101332e-03 6.938547e-03 -6.000000e+00 1.593291e-01 227.22 -2.00 3.25 -2.00 320.86 0.00e+00 1.510441e-03 4.942094e-04 5.176298e-04 -6.000000e+00 7.250118e-03 285.87 -2.00 20.00 -2.00 320.25 0.00e+00 4.870 0.001 302.00 328.00 3 1.0938e+00 3.6157e-03 5.8189e-02 -6.0000e+00 3.9536e-01 8.0867e-03 4.9958e-03 3.2583e-02 -6.0000e+00 4.2936e-01 -1.6940e-02 5.1804e-03 1.7256e-02 -6.0000e+00 2.5611e-01 1.4736e-03 2.5184e-03 5.8452e-03 -6.0000e+00 1.1109e-01 6.8344e-04 -4.8479e-04 5.3394e-05 5.0673e-05 -6.0000e+00 7.0345e-03 9.7509e-05 0.0000e+00 10 0 0 10 0 0 54.13 22.31 0.20 0.00010 -0.00355 128 33 5 8 0 372.070 20.00 22.31 14.80 25.79 26.11 26.6 977.52 -110060 85678 -59292 -103937 900000 112462 -106720 -99333 -127336 -14590 -70171 -63905 -56813 -75861 44243 -36006 -20289 -28981 56746 -6776 29289 4888 -3535 -5294 -21710 -745 -15159 1898 -9444 -3762 -3503 8090 2253 16245 -2374 -17134 -2653 -30254 3648 958 460 -4487 1710 -6290 5194 -1058 2568 3015 -641 -1990 230 421 4392 2387 -847 4264 1451 -1477 -492 -957 1667 -282 -1299 3295 224 -131 1080 -250 1245 1250 982 661 506 497 -241 -507 -806 -1048 295 1017 155 119 -1372 -1608 -1587 -683 95 -80 746 1125 703 293 326 387 586 -187 83 405 357 -378 166 -491 -1278 -449 -275 -1091 -596 -824 -526 13 270 233 366 104 257 22 624 280 104 -333 -306 -86 293 244 345 391 -177 434 510 289 -33 -320 -328 -279 -231 -172 -338 417 419 48 139 -382 -69 -479 178 -213 -590 900000 234 -585 -601 -1204 -55 -482 -452 -430 -918 230 -470 -261 -455 460 -101 321 68 -55 -94 -513 -15 -376 39 -211 -83 -91 233 82 578 -99 -788 -113 -2043 222 74 41 -460 175 -721 537 -120 288 348 -81 -271 34 65 727 442 -174 875 321 -340 -109 -206 354 -67 -357 995 76 -44 344 -82 441 523 464 332 255 238 -107 -201 -291 -376 115 473 86 71 -921 -1150 -1206 -551 80 -71 657 957 563 218 229 273 460 -173 83 462 426 -468 206 -542 -1266 -438 -291 -1246 -707 -1038 -670 18 434 377 600 166 409 33 926 437 163 -553 -508 -136 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