File name: Pandora143s1_LibertyTX_20250322_L2Fit_fwvt1c9d20230920p1-8.txt File generation date: 20250323T063934.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250322_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1663 1812 Nominal wavelengths inside fitting window [nm]: 492.0785 492.1995 492.3206 492.4416 492.5626 492.6836 492.8046 492.9256 493.0465 493.1674 493.2883 493.4092 493.5301 493.6510 493.7718 493.8926 494.0135 494.1342 494.2550 494.3758 494.4965 494.6173 494.7380 494.8587 494.9793 495.1000 495.2206 495.3413 495.4619 495.5825 495.7030 495.8236 495.9441 496.0646 496.1852 496.3056 496.4261 496.5466 496.6670 496.7874 496.9078 497.0282 497.1486 497.2690 497.3893 497.5096 497.6299 497.7502 497.8705 497.9907 498.1110 498.2312 498.3514 498.4716 498.5917 498.7119 498.8320 498.9521 499.0722 499.1923 499.3124 499.4324 499.5525 499.6725 499.7925 499.9124 500.0324 500.1524 500.2723 500.3922 500.5121 500.6320 500.7518 500.8717 500.9915 501.1113 501.2311 501.3509 501.4706 501.5904 501.7101 501.8298 501.9495 502.0691 502.1888 502.3084 502.4281 502.5477 502.6672 502.7868 502.9064 503.0259 503.1454 503.2649 503.3844 503.5038 503.6233 503.7427 503.8621 503.9815 504.1009 504.2203 504.3396 504.4589 504.5782 504.6975 504.8168 504.9360 505.0553 505.1745 505.2937 505.4129 505.5320 505.6512 505.7703 505.8894 506.0085 506.1276 506.2467 506.3657 506.4847 506.6038 506.7227 506.8417 506.9607 507.0796 507.1985 507.3174 507.4363 507.5552 507.6740 507.7929 507.9117 508.0305 508.1493 508.2680 508.3868 508.5055 508.6242 508.7429 508.8616 508.9802 509.0989 509.2175 509.3361 509.4547 509.5732 509.6918 509.8103 509.9288 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250322T125902.4Z 9212.541000 167 1 9.45 2 82.40 93.43 59.97 187.18 0.00 1 0.00 1 0 15 2.844e-03 2.823e-03 1.367e-03 1.366e-03 5.403341e+03 8.911861e+01 3.872719e+02 -6.000000e+00 1.629781e+02 286.20 -2.00 20.00 -2.00 505.29 0.00e+00 9.079232e-04 3.823970e-05 5.803893e-05 -6.000000e+00 8.107309e-05 286.20 -2.00 20.00 -2.00 500.58 0.00e+00 5.795853e-01 2.697538e-02 3.452611e-02 -6.000000e+00 5.680503e-02 227.60 -2.00 3.25 -2.00 502.15 0.00e+00 7.016 0.004 489.00 513.00 1 6.2124e+00 2.0706e-03 1.0614e-02 -6.0000e+00 4.3640e-03 -4.2301e-03 5.2785e-04 1.0140e-03 -6.0000e+00 1.1272e-03 1.3514e-03 1.7386e-03 1.3945e-04 4.8110e-05 -6.0000e+00 3.0339e-04 -3.8900e-03 -1.6809e-05 12 1 1 12 1 1 99.01 21.90 1.02 -0.00389 0.00817 4 15 2 2 0 1888.250 20.00 21.90 17.96 25.90 26.11 26.6 998.17 -395 -202 -125 323 172 782 465 482 387 207 261 96 -124 64 -186 -88 219 316 61 -261 -171 142 257 210 278 0 155 73 -279 -252 -92 -468 -156 120 64 -94 -41 111 -35 -4 -156 99 151 195 147 236 184 15 -94 -228 -354 -601 -701 -558 -548 -266 -23 -340 64 67 276 9 271 83 515 -92 69 48 -118 -270 -385 -98 -230 -62 -335 -417 -342 -251 18 -53 -465 -250 -172 -9 -31 -116 -105 -77 -139 -2 181 380 57 226 240 195 -13 170 -540 -541 -725 -449 -363 -221 -371 -235 -514 -232 -128 246 122 -271 252 423 272 174 447 563 312 451 -3 -61 228 235 74 468 389 197 73 514 161 68 58 -316 -50 -20 412 60 283 80 -66 291 68 101 -78 153 -132 -424 -108 -380 -378 -197 -123 317 174 803 475 496 398 211 261 97 -124 63 -184 -88 222 320 63 -268 -176 146 264 218 288 0 160 74 -284 -250 -91 -462 -157 122 67 -98 -43 114 -35 -4 -159 101 156 199 151 243 188 15 -96 -226 -350 -582 -677 -545 -550 -267 -23 -344 64 68 278 9 275 84 516 -94 69 47 -116 -267 -380 -97 -225 -62 -334 -412 -333 -246 18 -51 -454 -245 -166 -9 -31 -115 -105 -77 -138 -2 178 379 58 226 237 192 -13 164 -514 -508 -684 -432 -354 -218 -373 -237 -515 -230 -126 244 122 -272 254 428 277 176 452 568 314 456 -3 -61 224 232 73 464 385 195 73 506 158 67 56 -307 -49 -19 406 60 283 81 -68 298 68 102 -78 156 -132 -419 -107 -378 SQ 20250322T130406.2Z 9212.544516 170 1 26.93 2 81.30 94.08 60.11 188.41 0.00 1 0.00 1 0 22 2.393e-03 2.381e-03 2.265e-04 2.263e-04 4.915915e+03 1.463964e+01 3.441771e+02 -6.000000e+00 1.371336e+02 286.20 -2.00 20.00 -2.00 505.29 0.00e+00 8.589796e-04 6.336559e-06 5.439894e-05 -6.000000e+00 6.820721e-05 286.20 -2.00 20.00 -2.00 500.58 0.00e+00 4.964572e-01 4.476045e-03 3.390481e-02 -6.000000e+00 4.775100e-02 227.60 -2.00 3.25 -2.00 502.15 0.00e+00 6.242 0.003 489.00 513.00 1 4.0322e+00 3.4364e-04 9.5148e-03 -6.0000e+00 3.6691e-03 -5.4744e-03 8.7634e-05 9.4579e-04 -6.0000e+00 9.4654e-04 1.3462e-02 4.2711e-04 2.3200e-05 4.1440e-05 -6.0000e+00 2.5512e-04 6.7270e-04 2.7848e-05 10 0 0 10 0 0 99.38 21.91 1.05 0.00067 0.00364 155 155 2 2 0 173.710 20.00 21.91 18.17 25.90 26.11 26.6 999.57 -354 -294 -62 62 181 516 475 466 438 286 218 115 -6 -56 -116 -164 26 99 65 -94 9 142 138 256 263 173 128 104 -142 -431 -335 -319 -150 96 -12 -73 36 29 -83 -96 -39 1 85 152 192 262 160 35 4 -213 -441 -517 -607 -473 -224 -138 -98 -65 52 127 256 294 250 253 176 87 -58 -44 -174 -287 -306 -243 -208 -88 -67 -264 -377 -201 -171 -314 -316 -327 -255 -119 -70 -130 -43 -38 -47 5 90 250 320 225 170 105 -67 -79 -193 -482 -524 -510 -259 -108 -263 -333 -239 -252 -144 39 -2 72 161 306 327 409 494 423 268 230 169 109 206 316 68 123 199 87 169 285 65 -28 -43 -136 -157 116 86 -44 123 159 167 272 249 212 83 13 -168 -300 -376 -324 -340 -282 -61 62 181 525 491 476 446 294 221 116 -6 -56 -115 -165 26 101 67 -98 9 148 141 263 271 178 131 107 -143 -433 -332 -317 -150 99 -12 -75 37 30 -84 -99 -40 1 87 157 201 273 165 36 4 -213 -439 -506 -590 -466 -221 -138 -100 -67 53 130 261 302 252 260 179 87 -58 -44 -172 -282 -298 -238 -205 -86 -65 -263 -370 -194 -164 -301 -304 -317 -250 -118 -68 -128 -43 -37 -47 4 90 248 320 225 168 104 -66 -76 -185 -457 -498 -486 -251 -106 -263 -334 -238 -248 -141 39 -2 72 162 310 333 418 499 427 274 232 168 107 206 310 68 122 197 86 167 279 65 -27 -42 -131 -152 114 85 -44 123 160 170 277 250 214 84 13 -168 -300 -371 -320 SQ 20250322T131145.9Z 9212.549836 172 1 4.92 2 79.65 95.06 60.37 190.27 0.00 1 0.00 1 0 22 2.124e-03 2.113e-03 8.894e-05 8.885e-05 4.206333e+03 5.689940e+00 2.959791e+02 -6.000000e+00 1.216980e+02 286.20 -2.00 20.00 -2.00 505.30 0.00e+00 8.999515e-04 2.487460e-06 5.517661e-05 -6.000000e+00 6.052943e-05 286.20 -2.00 20.00 -2.00 500.56 0.00e+00 4.336063e-01 1.759348e-03 2.968802e-02 -6.000000e+00 4.237255e-02 227.60 -2.00 3.25 -2.00 502.14 0.00e+00 5.340 0.002 489.00 513.00 1 5.9826e-01 1.3509e-04 8.1831e-03 -6.0000e+00 3.2559e-03 -5.0788e-03 3.4501e-05 8.1538e-04 -6.0000e+00 8.3984e-04 4.7725e-01 3.2437e-04 9.1443e-06 3.7509e-05 -6.0000e+00 2.2639e-04 -2.1711e-03 5.2192e-05 10 0 0 10 0 0 15.54 21.91 1.10 -0.00217 0.00008 1054 1054 2 2 0 4.650 20.00 21.91 18.46 25.79 26.11 26.7 1002.60 -208 -233 -52 2 102 362 434 402 408 239 205 120 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