File name: Pandora143s1_LibertyTX_20250329_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20250330T063026.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250329_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250329 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250329T134832.5Z 9219.575377 68 1 26.87 2 69.89 97.74 70.83 95.47 0.00 1 0.00 1 0 17 9.563e-02 9.009e-03 5.837e-02 5.051e-03 3.791149e-01 2.492219e-03 4.181633e-03 -6.000000e+00 5.272325e-02 228.14 -2.00 3.25 -2.00 319.11 0.00e+00 7.333825e-04 6.085924e-04 1.229091e-04 -6.000000e+00 2.359265e-03 286.67 -2.00 20.00 -2.00 318.33 0.00e+00 2.877 0.000 302.00 328.00 3 4.1452e+00 6.9480e-03 3.4108e-02 -6.0000e+00 1.3113e-01 4.6228e-02 8.1067e-03 1.8396e-02 -6.0000e+00 1.4228e-01 -2.5782e-04 5.9723e-03 9.0590e-03 -6.0000e+00 8.4874e-02 -7.8903e-03 3.1767e-03 2.6545e-03 -6.0000e+00 3.6741e-02 2.8969e-04 -5.9384e-04 1.3402e-04 2.4603e-05 -6.0000e+00 2.2852e-03 -1.0766e-03 0.0000e+00 11 8 0 10 0 0 99.97 22.03 0.30 -0.00108 -0.00554 33 33 5 8 0 814.060 20.00 22.03 26.47 25.90 26.21 27.9 1062.42 -718 26077 -11663 -13604 90959 -17620 -18014 15145 2801 -2726 18033 8860 13150 -16537 1248 -11774 -9084 5761 18266 -4884 1411 2838 5031 -228 -2573 7688 -5632 334 -428 1435 -6007 6048 6357 8738 2286 -5699 3460 -18102 -1730 1602 -229 -3209 1412 -2150 -1343 -1107 477 1079 1618 -522 896 239 1960 573 -574 2261 548 -783 715 -2169 1893 228 656 1733 -61 -1018 291 -636 357 1576 -202 1541 623 1328 1042 -1649 2472 -107 1672 -253 51 -1733 -2158 -2369 -1312 -657 -213 379 812 1520 459 221 -459 -65 709 993 316 908 6 -286 524 -1737 -1299 -465 26 -1310 -432 -1484 -722 460 357 61 829 -155 241 -470 948 882 43 -490 -1062 -162 -49 442 826 818 209 590 1270 254 55 -302 -92 -470 170 -232 -113 173 136 101 -34 276 -985 -20 657 -443 -515 1162 -578 -618 438 105 -116 633 344 560 -1112 85 -1033 -838 487 1457 -508 144 284 496 -25 -316 912 -767 41 -50 163 -783 801 943 1362 360 -912 535 -4016 -402 428 -69 -1062 465 -743 -462 -385 164 365 544 -181 325 95 825 259 -273 1081 275 -399 351 -1071 915 120 377 1078 -40 -645 168 -359 211 1056 -151 1195 490 1007 747 -1100 1440 -60 966 -169 38 -1472 -1976 -2261 -1304 -692 -236 433 926 1690 489 218 -421 -57 656 1012 359 1129 8 -393 680 -2103 -1455 -522 31 -1687 -571 -2054 -1037 701 579 102 1369 -246 357 -663 1304 1256 65 -787 -1752 -262 -77 673 1211 1159 283 787 1798 394 91 -513 -158 -835 316 -453 -224 350 276 203 -67 514 -1796 SS 20250329T135532.5Z 9219.580238 72 1 10.85 2 68.39 98.69 69.35 96.35 0.00 1 0.00 1 0 17 4.812e-02 1.011e-02 3.934e-02 6.864e-03 3.478389e-01 3.365463e-03 3.854366e-03 -6.000000e+00 2.653752e-02 228.14 -2.00 3.25 -2.00 318.12 0.00e+00 3.078160e-04 6.177961e-04 3.275751e-04 -6.000000e+00 1.187443e-03 286.67 -2.00 20.00 -2.00 317.33 0.00e+00 2.690 0.000 302.00 328.00 3 5.3205e+00 9.0623e-03 3.1672e-02 -6.0000e+00 6.6005e-02 7.2102e-02 1.0324e-02 1.6779e-02 -6.0000e+00 7.1606e-02 -3.4910e-03 6.7786e-03 8.2027e-03 -6.0000e+00 4.2715e-02 -5.7225e-03 3.5735e-03 2.2969e-03 -6.0000e+00 1.8498e-02 1.1075e-04 -3.8226e-04 1.7801e-04 2.1009e-05 -6.0000e+00 1.1497e-03 -3.3211e-03 0.0000e+00 12 9 9 12 1 1 999.00 22.04 0.14 -0.00332 -0.00619 2 7 2 8 0 3616.430 20.00 22.04 26.98 25.90 26.21 27.8 1063.89 12447 2064 -22209 -9703 35912 -11154 -10604 -4073 -13188 6484 4316 515 -495 -1716 5021 -3121 -295 -5329 4755 -6347 3005 4299 8982 -3611 -560 3539 -5633 1355 3712 -829 2476 3999 5548 3145 2379 -7796 -4270 -2366 -512 347 1024 -4275 -692 2402 2023 -2381 780 -1057 -36 -5682 806 165 849 3724 617 2291 -72 -338 1160 -1879 298 -2 -131 1737 566 -231 115 317 -134 785 795 1112 471 179 662 -1365 914 -1861 1433 -35 -993 -1614 -1347 -2631 -1456 -30 53 573 1096 1840 498 -179 -202 -301 111 -83 889 310 298 -27 843 -2698 -1090 -1173 -749 -1029 -697 -589 -712 235 1073 916 782 175 168 -1238 659 -800 926 -128 -1 453 863 339 476 339 -169 -867 139 1261 526 -526 -1179 -658 157 -178 -360 1013 364 147 -17 -9 -1046 568 119 -1695 -641 1369 -616 -606 -252 -1022 449 305 38 -42 -172 558 -424 -42 -825 708 -1091 493 691 1389 -665 -109 700 -1223 264 666 -151 464 828 1257 777 563 -1905 -1061 -669 -171 135 435 -1998 -324 1111 938 -1156 368 -499 -17 -2783 392 87 473 2131 375 1403 -46 -218 724 -1180 186 -1 -94 1320 448 -176 82 216 -96 626 688 1001 428 159 558 -1078 649 -1287 991 -27 -863 -1532 -1353 -2753 -1574 -34 63 693 1324 2175 568 -192 -203 -292 111 -91 1047 396 405 -37 1106 -3371 -1270 -1378 -933 -1345 -935 -813 -1016 352 1676 1469 1240 267 243 -1724 894 -1126 1347 -196 -1 700 1299 501 683 472 -226 -1154 193 1860 816 -837 -1901 -1084 268 -317 -652 1841 669 269 -30 -15 -1763 SS 20250329T140208.6Z 9219.584822 75 1 1.10 2 66.98 99.61 67.96 97.18 0.00 1 0.00 1 0 17 1.787e-02 5.738e-03 1.094e-02 2.593e-03 3.292251e-01 1.272248e-03 3.657593e-03 -6.000000e+00 9.857215e-03 228.14 -2.00 3.25 -2.00 317.67 0.00e+00 2.542930e-04 2.057530e-04 1.109709e-04 -6.000000e+00 4.410612e-04 286.67 -2.00 20.00 -2.00 316.87 0.00e+00 2.536 0.000 302.00 328.00 3 1.8096e+00 3.3890e-03 2.9875e-02 -6.0000e+00 2.4517e-02 1.4624e-02 3.8339e-03 1.5802e-02 -6.0000e+00 2.6597e-02 1.0650e-04 2.4034e-03 7.7343e-03 -6.0000e+00 1.5866e-02 -3.4672e-03 1.2437e-03 2.1726e-03 -6.0000e+00 6.8714e-03 4.5537e-03 -3.2027e-04 6.6920e-05 2.0327e-05 -6.0000e+00 4.2704e-04 -3.7216e-03 0.0000e+00 12 1 1 12 1 1 99.49 22.05 0.20 -0.00372 -0.00613 12 146 1 8 0 84.440 20.00 22.05 27.21 25.90 26.21 27.6 1064.79 -4541 -1102 -7925 3931 -6791 701 -5934 7050 -5347 5060 -4571 -1691 -3149 -2563 -512 -1389 1668 -1333 2321 -533 1621 -979 1718 -1276 -39 -1011 -266 -137 -2440 1481 -501 2975 1304 1535 -3792 -1305 -2706 -878 -673 9 -325 -535 -201 -383 332 30 -697 -394 -1564 -117 252 1606 1108 327 397 1156 530 437 94 671 902 1352 942 1633 937 -668 13 -650 529 662 617 161 282 438 238 -82 97 5 -78 406 -1280 -1096 -1676 -1860 -1565 -921 -722 -341 165 357 368 774 137 12 801 377 96 241 548 72 -19 -751 -611 -409 -423 -881 -354 -680 -142 241 470 348 281 50 222 -135 371 118 131 58 -176 89 233 -148 475 299 92 723 445 455 235 -44 -210 -21 -246 0 -288 457 40 76 -158 -272 -727 -333 -89 -715 309 -526 47 -438 530 -516 476 -469 -169 -358 -339 -77 -238 295 -251 445 -109 338 -207 356 -287 -9 -257 -68 -34 -572 328 -118 757 369 460 -1134 -362 -794 -290 -263 4 -159 -274 -106 -204 176 16 -374 -208 -827 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