File name: Pandora143s1_LibertyTX_20250403_L2Fit_fout2c9d20230920p1-8.txt File generation date: 20250404T062606.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20250403_L1_smca1c9d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20250403 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0307 305.1715 305.3123 305.4532 305.5940 305.7348 305.8756 306.0164 306.1572 306.2979 306.4387 306.5794 306.7201 306.8609 307.0016 307.1423 307.2829 307.4236 307.5643 307.7049 307.8456 307.9862 308.1268 308.2674 308.4080 308.5486 308.6892 308.8297 308.9703 309.1108 309.2513 309.3919 309.5324 309.6729 309.8133 309.9538 310.0943 310.2347 310.3752 310.5156 310.6560 310.7964 310.9368 311.0772 311.2175 311.3579 311.4982 311.6386 311.7789 311.9192 312.0595 312.1998 312.3401 312.4804 312.6206 312.7609 312.9011 313.0413 313.1815 313.3217 313.4619 313.6021 313.7423 313.8824 314.0226 314.1627 314.3028 314.4429 314.5830 314.7231 314.8632 315.0033 315.1433 315.2834 315.4234 315.5634 315.7034 315.8434 315.9834 316.1234 316.2633 316.4033 316.5432 316.6831 316.8231 316.9630 317.1029 317.2427 317.3826 317.5225 317.6623 317.8022 317.9420 318.0818 318.2216 318.3614 318.5012 318.6409 318.7807 318.9204 319.0602 319.1999 319.3396 319.4793 319.6190 319.7587 319.8983 320.0380 320.1776 320.3173 320.4569 320.5965 320.7361 320.8757 321.0153 321.1548 321.2944 321.4339 321.5734 321.7129 321.8524 321.9919 322.1314 322.2709 322.4104 322.5498 322.6892 322.8287 322.9681 323.1075 323.2469 323.3862 323.5256 323.6650 323.8043 323.9436 324.0829 324.2223 324.3616 324.5008 324.6401 324.7794 324.9186 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250403T140247.9Z 9224.585277 83 1 5.47 2 65.53 98.11 108.84 39.74 0.00 1 0.00 1 0 17 4.443e-02 8.201e-03 5.415e-02 7.081e-03 2.908157e-01 3.487623e-03 3.218638e-03 -6.000000e+00 2.454220e-02 228.52 -2.00 3.25 -2.00 319.06 0.00e+00 1.078083e-03 8.111525e-04 4.951732e-04 -6.000000e+00 1.098061e-03 287.00 -2.00 20.00 -2.00 318.25 0.00e+00 2.397 0.000 302.00 328.00 3 1.8595e+00 9.6927e-03 2.7778e-02 -6.0000e+00 6.1090e-02 -1.2536e-01 1.1223e-02 1.4165e-02 -6.0000e+00 6.6245e-02 9.1073e-02 7.8697e-03 7.0298e-03 -6.0000e+00 3.9513e-02 -2.5383e-02 4.1589e-03 2.0599e-03 -6.0000e+00 1.7108e-02 5.4359e-03 -5.5160e-04 1.9344e-04 1.9582e-05 -6.0000e+00 1.0615e-03 -5.0830e-03 0.0000e+00 11 8 0 10 0 0 14.20 22.48 0.07 -0.00508 -0.00923 2264 2038 5 8 0 2.400 20.01 22.48 30.67 26.00 26.21 28.1 1087.65 1284 3517 8854 18578 17830 4705 -2312 2474 33545 2671 2305 -12466 4102 -10059 10851 1350 950 -693 -2766 98 -903 -3568 1362 6029 -1418 -742 -7165 -17 -315 -5630 8189 -4178 5604 -266 -75 -1661 -2170 -2682 123 -923 -184 986 1093 1668 199 -1243 -463 857 -666 -156 -951 1573 -978 -1466 1332 373 -216 -627 709 -1123 447 1264 1319 631 426 -122 -714 -1790 301 1901 58 343 1236 497 915 -609 -899 -1992 -1439 -1805 -1898 -1947 -1543 -619 -505 -527 -1 623 550 1581 1212 417 -614 -1210 -71 -562 474 581 1473 526 -428 -1501 -1399 -1512 -669 -523 -358 82 552 1037 938 1753 597 251 -577 -901 -408 -705 -378 -246 296 69 902 -293 120 -388 -839 -1351 -661 -607 178 -163 -794 -400 -194 291 317 865 440 296 228 -653 -190 51 156 395 749 653 180 -97 113 1333 149 129 -791 251 -811 848 129 97 -75 -319 12 -112 -451 166 741 -201 -111 -1146 -3 -43 -786 1060 -671 912 -49 -13 -277 -382 -550 30 -266 -59 329 378 584 71 -456 -169 303 -236 -55 -354 622 -425 -677 622 180 -108 -318 350 -555 222 667 764 400 281 -76 -411 -992 171 1228 43 264 955 377 656 -404 -536 -1123 -825 -1173 -1405 -1603 -1365 -566 -488 -550 -1 716 636 1783 1292 411 -555 -1044 -64 -559 520 706 1938 710 -551 -1772 -1529 -1678 -804 -672 -479 114 795 1601 1547 2965 1001 398 -846 -1237 -546 -984 -563 -393 488 113 1425 -454 178 -552 -1131 -1790 -929 -933 289 -271 -1345 -699 -359 569 638 1768 917 612 455 -1252 -351 SS 20250403T140253.5Z 9224.585342 83 2 5.49 2 65.51 98.12 108.83 39.76 0.00 1 0.00 1 0 17 3.185e-02 8.041e-03 4.600e-02 6.678e-03 2.947146e-01 3.290115e-03 3.256589e-03 -6.000000e+00 1.759468e-02 228.52 -2.00 3.25 -2.00 319.02 0.00e+00 5.579191e-04 7.521286e-04 3.116589e-04 -6.000000e+00 7.872086e-04 287.00 -2.00 20.00 -2.00 318.21 0.00e+00 2.395 0.000 302.00 328.00 3 1.7861e+00 9.1291e-03 2.7855e-02 -6.0000e+00 4.3797e-02 -1.0084e-01 1.0551e-02 1.4311e-02 -6.0000e+00 4.7492e-02 6.8170e-02 7.2866e-03 7.0305e-03 -6.0000e+00 2.8328e-02 -1.6505e-02 3.8424e-03 1.9983e-03 -6.0000e+00 1.2265e-02 5.8059e-03 -5.6287e-04 1.8250e-04 1.9107e-05 -6.0000e+00 7.6101e-04 -5.2539e-03 0.0000e+00 11 8 0 10 0 0 12.81 22.48 0.09 -0.00525 -0.00948 2264 2038 5 8 0 2.400 20.01 22.48 30.67 26.00 26.21 28.1 1087.65 -5636 13977 7036 -5902 -2601 -201 -11908 -12273 12238 -7513 -5619 -675 -377 8258 216 1320 -7725 -3128 -314 2158 -6311 2935 5093 3163 146 4740 -1245 -5317 7144 -4967 3194 -3037 2229 2392 292 -5579 -968 133 109 210 -920 208 -1334 1764 -756 -514 -948 -405 -1304 289 934 1141 901 1438 1913 -1795 594 -581 972 372 -1285 787 2155 2249 1203 -206 -1341 -2337 -1109 1568 1204 856 424 815 596 -252 -288 -3419 -2361 -2695 -1611 -1333 -1608 -972 -786 113 -269 880 756 1549 345 -42 -910 -1622 -608 -417 -412 1196 837 325 582 -1818 -1055 -1139 -456 52 -407 -314 444 1208 1025 1069 490 621 85 -648 -813 -863 -409 -396 46 410 250 -280 -133 2 -395 -747 -237 288 -78 -595 -409 82 -402 11 -123 1048 498 220 217 -560 -443 -254 601 338 -310 -120 -8 -571 -672 617 -482 -354 -41 -25 593 19 131 -883 -357 -37 258 -849 363 618 413 21 697 -196 -832 943 -710 444 -495 383 438 52 -986 -172 27 27 61 -301 71 -481 630 -277 -191 -352 -147 -471 103 346 459 388 653 901 -897 299 -299 483 184 -653 420 1249 1415 793 -129 -780 -1309 -644 1020 876 659 332 618 430 -166 -171 -1958 -1367 -1769 -1192 -1093 -1426 -893 -764 117 -299 1009 875 1747 371 -41 -825 -1407 -547 -414 -456 1447 1109 439 742 -2156 -1148 -1258 -545 66 -543 -437 640 1858 1687 1818 823 980 124 -888 -1095 -1209 -608 -634 77 670 397 -433 -197 3 -529 -982 -332 438 -126 -998 -690 143 -744 22 -249 2134 1035 453 432 -1070 -816 SS 20250403T140259.2Z 9224.585408 83 3 5.62 2 65.49 98.13 108.82 39.78 0.00 1 0.00 1 0 17 4.146e-02 8.718e-03 4.843e-02 6.833e-03 2.911626e-01 3.361167e-03 3.220672e-03 -6.000000e+00 2.290031e-02 228.52 -2.00 3.25 -2.00 319.04 0.00e+00 2.125627e-04 7.729204e-04 4.886432e-04 -6.000000e+00 1.024612e-03 287.00 -2.00 20.00 -2.00 318.22 0.00e+00 2.394 0.000 302.00 328.00 3 1.8265e+00 9.3328e-03 2.7785e-02 -6.0000e+00 5.7003e-02 -1.1868e-01 1.0796e-02 1.4332e-02 -6.0000e+00 6.1814e-02 7.9364e-02 7.4939e-03 6.9397e-03 -6.0000e+00 3.6870e-02 -2.0635e-02 3.9528e-03 1.9602e-03 -6.0000e+00 1.5963e-02 5.6584e-03 -4.7751e-04 1.8693e-04 1.8343e-05 -6.0000e+00 9.9056e-04 -4.8785e-03 0.0000e+00 11 8 0 10 0 0 40.64 22.48 0.02 -0.00488 -0.00847 2264 2038 5 8 0 2.400 20.01 22.48 30.67 26.00 26.21 28.1 1087.65 1356 3932 3087 11169 4558 -26449 -802 20598 12941 -4497 1258 -15561 -11739 2421 5747 -223 -6614 3525 -5473 3806 -5944 6181 -3266 5821 2746 3027 1478 -1700 2079 -3464 1888 -1058 4111 -1032 967 -1923 3007 -1615 2128 1570 -2332 -1101 -425 -1315 -800 727 -49 889 -870 -1659 2481 226 -850 939 -3 -1554 390 167 -936 1592 1001 1033 1685 2902 -41 971 -790 -2629 -1253 240 -74 1526 125 1531 917 -1127 266 -3854 -2917 -2293 -1405 -1946 -1760 -590 -907 820 106 911 910 1634 746 395 -951 -1697 -478 -225 220 815 1624 -364 -308 -1686 -1143 -1005 -910 -815 -234 -323 272 1063 1038 1520 922 505 -172 -812 -1034 -209 -373 -441 338 242 406 73 -150 -446 -1049 -435 -364 -344 -36 -339 -542 -329 145 -98 45 582 735 646 -70 -108 -847 57 182 150 497 194 -1372 -35 838 643 -280 74 -1062 -859 181 485 -22 -739 375 -662 442 -786 732 -423 737 386 450 226 -257 285 -485 264 -168 687 -193 169 -326 512 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