File name: Pandora143s1_LibertyTX_20250416_L2Fit_fwvt1c9d20230920p1-8.txt
File generation date: 20250417T063015.0Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c9p1-8
Local principal investigator: Yuxuan Wang
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 143
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora143_OF_v1d20230920.txt
Instrument calibration file used: Pandora143s1_CF_v9d20230920.txt
Level 1 file used: Pandora143s1_LibertyTX_20250416_L1_smca1c9d20230920p1-8.txt
Full location name: Sam Houston Regional Library and Research Center
Short location name: LibertyTX
Country of location: United States
Location latitude [deg]: 30.0965
Location longitude [deg]: -94.7635
Location altitude [m]: 3
Local noon date: 20250416
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1663 1812
Nominal wavelengths inside fitting window [nm]: 492.0785 492.1995 492.3206 492.4416 492.5626 492.6836 492.8046 492.9256 493.0465 493.1674 493.2883 493.4092 493.5301 493.6510 493.7718 493.8926 494.0135 494.1342 494.2550 494.3758 494.4965 494.6173 494.7380 494.8587 494.9793 495.1000 495.2206 495.3413 495.4619 495.5825 495.7030 495.8236 495.9441 496.0646 496.1852 496.3056 496.4261 496.5466 496.6670 496.7874 496.9078 497.0282 497.1486 497.2690 497.3893 497.5096 497.6299 497.7502 497.8705 497.9907 498.1110 498.2312 498.3514 498.4716 498.5917 498.7119 498.8320 498.9521 499.0722 499.1923 499.3124 499.4324 499.5525 499.6725 499.7925 499.9124 500.0324 500.1524 500.2723 500.3922 500.5121 500.6320 500.7518 500.8717 500.9915 501.1113 501.2311 501.3509 501.4706 501.5904 501.7101 501.8298 501.9495 502.0691 502.1888 502.3084 502.4281 502.5477 502.6672 502.7868 502.9064 503.0259 503.1454 503.2649 503.3844 503.5038 503.6233 503.7427 503.8621 503.9815 504.1009 504.2203 504.3396 504.4589 504.5782 504.6975 504.8168 504.9360 505.0553 505.1745 505.2937 505.4129 505.5320 505.6512 505.7703 505.8894 506.0085 506.1276 506.2467 506.3657 506.4847 506.6038 506.7227 506.8417 506.9607 507.0796 507.1985 507.3174 507.4363 507.5552 507.6740 507.7929 507.9117 508.0305 508.1493 508.2680 508.3868 508.5055 508.6242 508.7429 508.8616 508.9802 509.0989 509.2175 509.3361 509.4547 509.5732 509.6918 509.8103 509.9288
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250416T124330.8Z 9237.530218 186 1 27.04 2 79.55 84.05 80.33 231.58 0.00 1 0.00 1 0 22 2.231e-03 2.223e-03 2.423e-04 2.420e-04 6.904377e+03 1.633251e+01 4.664676e+02 -6.000000e+00 1.286507e+02 287.87 -2.00 20.00 -2.00 505.30 0.00e+00 1.254407e-03 6.814154e-06 7.689783e-05 -6.000000e+00 6.381871e-05 287.87 -2.00 20.00 -2.00 500.57 0.00e+00 3.846220e-01 4.804419e-03 4.698683e-02 -6.000000e+00 4.455513e-02 229.48 -2.00 3.25 -2.00 502.15 0.00e+00 5.292 0.002 489.00 513.00 1 3.1370e+00 3.6905e-04 8.7751e-03 -6.0000e+00 3.4252e-03 -1.6075e-02 9.3674e-05 1.1841e-03 -6.0000e+00 8.8330e-04 3.7685e-02 5.7565e-04 2.4488e-05 5.3746e-05 -6.0000e+00 2.3776e-04 -2.5498e-03 6.2436e-05 10 0 0 10 0 0 96.04 25.63 1.07 -0.00255 0.00144 140 140 5 2 0 193.150 20.00 25.63 21.25 25.90 26.21 27.8 1012.86 -234 -318 -138 -32 122 445 421 414 396 244 180 101 -33 -106 -223 -163 -144 90 62 -63 -5 135 140 244 353 160 178 147 -91 -286 -85 -179 -67 163 -57 -201 -42 -14 -110 -133 -57 7 107 195 278 276 145 21 -93 -230 -381 -366 -447 -386 -157 -144 -98 -80 78 124 221 239 216 198 133 87 -18 -37 -146 -284 -268 -240 -203 -59 -53 -332 -415 -220 -179 -295 -216 -277 -251 -108 -73 -142 -80 -112 -54 7 77 238 301 162 140 92 -55 -132 -245 -474 -490 -415 -193 -76 -322 -393 -221 -201 -61 37 44 42 190 242 370 438 498 461 238 253 208 80 198 327 96 163 272 111 154 257 56 -103 4 -117 -122 139 70 -85 92 118 108 179 206 152 67 -26 -221 -323 -382 -258 -223 -310 -136 -32 123 451 433 429 409 249 181 103 -34 -106 -221 -163 -143 91 63 -65 -5 140 145 253 368 167 184 151 -92 -284 -83 -177 -68 167 -59 -208 -43 -14 -113 -136 -58 8 109 201 288 287 150 21 -95 -230 -379 -356 -433 -380 -155 -147 -100 -81 79 127 226 246 223 203 136 87 -18 -37 -145 -278 -261 -235 -201 -59 -52 -332 -408 -212 -172 -282 -208 -269 -246 -107 -71 -140 -79 -110 -53 7 77 239 299 161 139 89 -53 -125 -232 -443 -461 -391 -188 -75 -320 -393 -219 -197 -60 37 44 42 190 244 374 445 510 473 244 254 206 80 197 325 94 161 268 110 152 252 56 -100 4 -112 -119 136 69 -85 92 119 110 183 211 153 69 -26 -221 -323 -378 -254
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SQ 20250416T125443.8Z 9237.538007 190 2 4.97 2 77.13 85.40 82.21 233.16 0.00 1 0.00 1 0 15 2.073e-03 2.065e-03 9.380e-05 9.370e-05 5.608117e+03 6.187153e+00 3.830422e+02 -6.000000e+00 1.195876e+02 287.87 -2.00 20.00 -2.00 505.30 0.00e+00 1.030371e-03 2.635268e-06 6.436227e-05 -6.000000e+00 5.932040e-05 287.87 -2.00 20.00 -2.00 500.57 0.00e+00 2.798450e-01 1.859482e-03 3.876072e-02 -6.000000e+00 4.141139e-02 229.48 -2.00 3.25 -2.00 502.15 0.00e+00 4.370 0.001 489.00 513.00 1 8.3563e-01 1.4286e-04 7.2462e-03 -6.0000e+00 3.1836e-03 -1.4218e-02 3.6364e-05 9.7389e-04 -6.0000e+00 8.2088e-04 4.3525e-01 3.4241e-04 9.5491e-06 4.5242e-05 -6.0000e+00 2.2098e-04 -2.9492e-03 7.2610e-05 10 0 0 10 0 0 16.76 25.61 1.12 -0.00295 -0.00057 939 938 2 2 0 5.220 20.00 25.61 21.82 25.90 26.21 27.9 1017.92 -201 -212 -44 29 108 358 410 401 404 246 211 116 -4 -104 -146 -141 -147 56 26 -103 10 146 138 260 278 145 108 134 -138 -299 -158 -178 -80 134 -57 -196 -33 15 -83 -54 -10 35 101 170 195 199 144 40 -26 -227 -381 -407 -490 -356 -183 -151 -149 -62 68 142 262 247 204 166 142 58 -52 -56 -129 -276 -238 -221 -214 -59 -112 -291 -323 -190 -149 -249 -253 -258 -251 -88 -47 -144 -76 -68 -61 14 46 200 269 138 122 69 -48 -89 -223 -448 -447 -399 -210 -73 -309 -345 -220 -176 -62 59 31 57 148 257 308 397 486 386 223 203 192 94 207 299 94 114 216 93 158 285 63 -77 -11 -79 -83 103 47 -55 105 157 108 175 186 117 90 -32 -162 -297 -340 -248 -193 -207 -43 29 111 365 425 410 411 253 214 116 -4 -104 -146 -142 -147 58 26 -106 10 151 144 271 285 149 113 138 -139 -299 -155 -177 -81 137 -59 -203 -34 15 -85 -55 -10 35 103 176 202 207 149 41 -27 -227 -378 -396 -474 -349 -180 -153 -151 -63 70 144 267 253 210 170 144 58 -53 -56 -127 -270 -232 -216 -211 -58 -112 -289 -316 -183 -146 -243 -243 -250 -245 -87 -46 -142 -75 -67 -60 14 46 198 268 137 122 68 -47 -84 -211 -421 -422 -377 -206 -73 -308 -345 -218 -172 -61 58 31 58 148 259 312 405 498 396 227 204 190 94 206 298 94 112 213 92 155 283 63 -75 -11 -76 -80 101 46 -55 106 157 108 177 189 120 91 -32 -161 -295 -333 -243
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