File name: Pandora130s1_Lindenberg_20240215_L2Fit_fnvs5c6d20220715p1-8.txt File generation date: 20240215T231958.8Z Data description: Level 2 spectral fitting results file Data file version: fnvs5c6p1-8 Local principal investigator: Lionel Doppler Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 130 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora130_OF_v3d20201102.txt Instrument calibration file used: Pandora130s1_CF_v6d20220715.txt Level 1 file used: Pandora130s1_Lindenberg_20240215_L1_smca1c6d20220715p1-8.txt Full location name: DWD Observatory Lindenberg Short location name: Lindenberg Country of location: Germany Location latitude [deg]: 52.2900 Location longitude [deg]: 14.1200 Location altitude [m]: 127 Local noon date: 20240215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: "AnaLab+fld for 20220715 VP" session 5 from check dispersion First and last pixel inside fitting window: 931 1477 Nominal wavelengths inside fitting window [nm]: 400.0402 400.1723 400.3045 400.4366 400.5688 400.7009 400.8330 400.9651 401.0971 401.2292 401.3612 401.4933 401.6253 401.7573 401.8893 402.0212 402.1532 402.2851 402.4171 402.5490 402.6809 402.8128 402.9446 403.0765 403.2083 403.3402 403.4720 403.6038 403.7356 403.8673 403.9991 404.1308 404.2625 404.3943 404.5260 404.6576 404.7893 404.9210 405.0526 405.1842 405.3158 405.4474 405.5790 405.7106 405.8421 405.9737 406.1052 406.2367 406.3682 406.4997 406.6311 406.7626 406.8940 407.0254 407.1569 407.2882 407.4196 407.5510 407.6823 407.8137 407.9450 408.0763 408.2076 408.3389 408.4701 408.6014 408.7326 408.8638 408.9950 409.1262 409.2574 409.3886 409.5197 409.6508 409.7819 409.9130 410.0441 410.1752 410.3063 410.4373 410.5683 410.6993 410.8303 410.9613 411.0923 411.2233 411.3542 411.4851 411.6160 411.7469 411.8778 412.0087 412.1395 412.2704 412.4012 412.5320 412.6628 412.7936 412.9243 413.0551 413.1858 413.3165 413.4472 413.5779 413.7086 413.8393 413.9699 414.1006 414.2312 414.3618 414.4924 414.6229 414.7535 414.8840 415.0146 415.1451 415.2756 415.4061 415.5365 415.6670 415.7974 415.9279 416.0583 416.1887 416.3190 416.4494 416.5798 416.7101 416.8404 416.9707 417.1010 417.2313 417.3616 417.4918 417.6221 417.7523 417.8825 418.0127 418.1428 418.2730 418.4031 418.5333 418.6634 418.7935 418.9236 419.0536 419.1837 419.3137 419.4438 419.5738 419.7038 419.8338 419.9637 420.0937 420.2236 420.3535 420.4834 420.6133 420.7432 420.8731 421.0029 421.1328 421.2626 421.3924 421.5222 421.6519 421.7817 421.9115 422.0412 422.1709 422.3006 422.4303 422.5599 422.6896 422.8192 422.9489 423.0785 423.2081 423.3377 423.4672 423.5968 423.7263 423.8558 423.9853 424.1148 424.2443 424.3738 424.5032 424.6326 424.7621 424.8915 425.0208 425.1502 425.2796 425.4089 425.5382 425.6675 425.7968 425.9261 426.0554 426.1846 426.3139 426.4431 426.5723 426.7015 426.8307 426.9598 427.0890 427.2181 427.3472 427.4763 427.6054 427.7345 427.8636 427.9926 428.1216 428.2506 428.3796 428.5086 428.6376 428.7665 428.8955 429.0244 429.1533 429.2822 429.4111 429.5399 429.6688 429.7976 429.9264 430.0552 430.1840 430.3128 430.4415 430.5703 430.6990 430.8277 430.9564 431.0851 431.2138 431.3424 431.4710 431.5997 431.7283 431.8569 431.9854 432.1140 432.2425 432.3711 432.4996 432.6281 432.7566 432.8850 433.0135 433.1419 433.2704 433.3988 433.5272 433.6556 433.7839 433.9123 434.0406 434.1689 434.2972 434.4255 434.5538 434.6820 434.8103 434.9385 435.0667 435.1949 435.3231 435.4513 435.5794 435.7076 435.8357 435.9638 436.0919 436.2200 436.3480 436.4761 436.6041 436.7321 436.8601 436.9881 437.1161 437.2440 437.3720 437.4999 437.6278 437.7557 437.8836 438.0115 438.1393 438.2671 438.3950 438.5228 438.6506 438.7783 438.9061 439.0338 439.1616 439.2893 439.4170 439.5447 439.6723 439.8000 439.9276 440.0552 440.1828 440.3104 440.4380 440.5656 440.6931 440.8207 440.9482 441.0757 441.2032 441.3306 441.4581 441.5855 441.7129 441.8404 441.9677 442.0951 442.2225 442.3498 442.4772 442.6045 442.7318 442.8591 442.9863 443.1136 443.2408 443.3681 443.4953 443.6225 443.7497 443.8768 444.0040 444.1311 444.2582 444.3853 444.5124 444.6395 444.7665 444.8936 445.0206 445.1476 445.2746 445.4016 445.5286 445.6555 445.7825 445.9094 446.0363 446.1632 446.2900 446.4169 446.5437 446.6706 446.7974 446.9242 447.0510 447.1777 447.3045 447.4312 447.5579 447.6846 447.8113 447.9380 448.0647 448.1913 448.3179 448.4446 448.5712 448.6977 448.8243 448.9509 449.0774 449.2039 449.3304 449.4569 449.5834 449.7098 449.8363 449.9627 450.0891 450.2155 450.3419 450.4683 450.5946 450.7210 450.8473 450.9736 451.0999 451.2262 451.3524 451.4787 451.6049 451.7311 451.8573 451.9835 452.1097 452.2358 452.3619 452.4881 452.6142 452.7403 452.8663 452.9924 453.1184 453.2445 453.3705 453.4965 453.6225 453.7484 453.8744 454.0003 454.1262 454.2521 454.3780 454.5039 454.6298 454.7556 454.8814 455.0072 455.1330 455.2588 455.3846 455.5103 455.6361 455.7618 455.8875 456.0132 456.1388 456.2645 456.3901 456.5158 456.6414 456.7670 456.8925 457.0181 457.1437 457.2692 457.3947 457.5202 457.6457 457.7712 457.8966 458.0221 458.1475 458.2729 458.3983 458.5237 458.6490 458.7744 458.8997 459.0250 459.1503 459.2756 459.4009 459.5261 459.6513 459.7766 459.9018 460.0270 460.1521 460.2773 460.4024 460.5276 460.6527 460.7778 460.9029 461.0279 461.1530 461.2780 461.4030 461.5280 461.6530 461.7780 461.9029 462.0279 462.1528 462.2777 462.4026 462.5275 462.6523 462.7772 462.9020 463.0268 463.1516 463.2764 463.4012 463.5259 463.6507 463.7754 463.9001 464.0248 464.1495 464.2741 464.3988 464.5234 464.6480 464.7726 464.8972 465.0217 465.1463 465.2708 465.3953 465.5198 465.6443 465.7688 465.8932 466.0177 466.1421 466.2665 466.3909 466.5153 466.6396 466.7640 466.8883 467.0126 467.1369 467.2612 467.3854 467.5097 467.6339 467.7581 467.8823 468.0065 468.1307 468.2548 468.3790 468.5031 468.6272 468.7513 468.8754 468.9994 469.1235 469.2475 469.3715 469.4955 469.6195 469.7434 469.8674 469.9913 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Molecular iodine slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of molecular iodine slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of molecular iodine slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Molecular iodine effective temperature [K] Column 39: Independent uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of molecular iodine effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective molecular iodine fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for molecular iodine [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrogen dioxide effective temperature [K] Column 50: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 56: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Oxygen dimer effective temperature [K] Column 61: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 67: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Ozone effective temperature [K] Column 72: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Iodine dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of iodine dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of iodine dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Iodine dioxide effective temperature [K] Column 83: Independent uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of iodine dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective iodine dioxide fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for iodine dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 89: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 90: Lower limit used for wavelength scaling [nm] Column 91: Upper limit used for wavelength scaling [nm] Column 92: Order of smoothing polynomial Column 93: Smoothing polynomial coefficient, order 0 Column 94: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 95: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 96: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 97: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 98: Smoothing polynomial coefficient, order 1 Column 99: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 100: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 101: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 102: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 103: Smoothing polynomial coefficient, order 2 Column 104: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 105: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 106: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 107: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 108: Smoothing polynomial coefficient, order 3 Column 109: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 110: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 111: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 112: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 113: Smoothing polynomial coefficient, order 4 Column 114: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 115: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 116: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 117: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 118: Mean value of measured data inside fitting window [same units as measurements] Column 119: Offset polynomial coefficient, order 0 Column 120: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 121: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 122: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 123: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 124: Wavelength change polynomial coefficient, order 0 Column 125: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 126: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 127: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 128: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 129: Wavelength change polynomial coefficient, order 1 Column 130: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 131: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 132: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 133: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 134: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 135: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 136: Resolution change polynomial coefficient, order 0 Column 137: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 138: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 139: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 140: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 141: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 142: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 143: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 144: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 145: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 146: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 147: Atmospheric variability [%], 999=no atmospheric variability was determined Column 148: Wavelength effective temperature [°C], 999=no effective temperature given Column 149: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 150: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 151: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 152: Number of bright count cycles Column 153: Number of dark count cycles Column 154: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 155: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 156: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 157: Integration time [ms] Column 158: Spectrometer control temperature [°C], 999=no temperature signal Column 159: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 160: Temperature in head sensor [°C], 999=no temperature signal Column 161: Temperature at electronics board 1 [°C], 999=no temperature signal Column 162: Temperature at electronics board 2 [°C], 999=no temperature signal Column 163: Humidity in head sensor [%], -9=no humidity signal Column 164: Pressure in head sensor [hPa], -9=no pressure signal Columns 165-711: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 712-1258: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240215T120657.7Z 8811.504835 208 1 9.29 2 65.91 193.18 57.74 104.65 0.00 1 0.00 1 0 33 1.719e-03 1.689e-03 1.403e-03 1.381e-03 7.776407e+02 2.551090e+02 6.632149e+01 5.353771e+02 3.290296e+02 266.07 -2.00 20.00 -2.00 445.33 0.00e+00 1.808212e-05 1.535008e-04 2.845320e-06 2.277340e-05 1.892947e-04 266.07 -2.00 20.00 -2.00 454.57 0.00e+00 1.764281e-04 1.248943e-05 1.329250e-06 1.070931e-05 1.576226e-05 224.78 -2.00 2.40 -2.00 435.31 0.00e+00 1.200172e+05 1.892651e+05 1.278186e+04 3.499083e+05 2.451721e+05 250.07 -2.00 11.50 -2.00 457.03 0.00e+00 4.087118e-01 3.940455e-02 2.075196e-03 1.407026e-02 5.364634e-02 223.59 -2.00 3.85 -2.00 453.95 0.00e+00 1.323531e-05 4.964602e-06 1.906673e-07 1.759189e-06 6.639330e-06 266.07 -2.00 20.00 -2.00 455.19 0.00e+00 2.433 0.000 397.00 473.00 4 6.6979e+00 1.4785e-03 6.0566e-03 6.0000e-04 1.7707e-03 4.6319e-02 1.7733e-03 1.2650e-03 3.5587e-04 2.1928e-03 -7.0693e-03 1.0236e-03 1.6695e-04 1.4695e-04 1.2593e-03 -1.5859e-03 3.3826e-04 1.8781e-05 3.7687e-05 4.1819e-04 1.3374e-03 1.7126e-04 3.6767e-06 2.1685e-05 2.0800e-04 1.2859e-03 7.4346e-03 1.0271e-03 6.6962e-06 5.5988e-05 1.1312e-03 -9.5512e-05 1.6687e-05 2.3891e-07 5.8993e-07 2.0309e-05 -1.3758e-05 2.3056e-05 2.4151e-07 7.5102e-07 2.7678e-05 2.4298e-03 -4.2010e-05 5.9633e-01 1.4623e-01 5.5365e-04 3.2867e-03 1.7143e-01 12 9 9 12 33 1 99.45 16.15 1.09 0.00243 0.00150 5 7 1 2 0 1546.680 14.99 16.15 18.09 21.69 21.58 29.9 1030.62 -259 -54 -104 -86 75 339 51 320 -127 64 -161 -348 191 -294 -170 29 123 -260 -162 -145 635 128 -119 80 -63 266 -233 90 47 93 -249 268 -356 201 508 199 119 -166 -227 54 209 -211 -47 -9 96 -206 210 -161 -295 20 60 -1 -76 35 124 -1 265 40 -255 81 -93 220 276 28 221 122 19 -108 -131 239 150 -48 120 -64 -16 -12 -144 12 -232 -65 -81 -28 37 159 -354 151 -143 -66 -225 46 187 31 77 -55 -345 -238 42 126 82 -210 -241 -111 27 206 -62 259 420 203 131 158 -41 75 295 -194 71 -131 52 -549 -78 127 -94 178 -76 31 -107 -6 178 -3 -209 -69 -183 18 -313 -87 -321 -316 112 137 -108 -157 -1 -71 -29 -134 224 -60 -55 -183 35 34 188 -182 14 193 -69 -51 245 0 -156 -140 307 -59 406 -146 249 -234 198 -2 1 -273 46 -339 34 -150 17 -32 -66 -60 9 220 51 455 -6 7 -28 -533 243 68 66 80 213 -285 -106 334 -156 -246 -158 53 75 -116 285 -12 118 344 -246 -12 102 -24 3 -152 -74 32 -129 43 -73 -52 57 8 217 -93 149 55 -24 89 269 41 336 290 -122 4 -41 218 -302 -7 -268 76 -233 175 -419 106 92 -31 34 -13 -294 -285 296 272 -17 -122 -9 270 181 -326 -103 163 -155 74 115 -294 303 122 58 -57 -148 59 91 78 -161 374 309 -235 245 77 -41 81 3 -38 -20 159 15 -130 234 119 37 463 -135 94 36 -86 163 -211 -239 -429 -273 53 -29 32 174 242 -159 219 -224 29 -177 -116 -80 41 113 74 -127 -125 -183 13 49 -347 27 -53 -16 122 58 -86 -243 228 -187 47 -55 67 -46 57 -16 243 -253 -63 -83 -192 48 163 62 82 -154 259 118 45 101 -36 -50 81 1 -14 29 64 -309 149 -2 -195 -92 337 9 369 2 30 36 -14 -162 89 220 -124 10 -14 157 -28 -89 -143 -214 206 24 -192 -325 409 3 -61 -104 -291 -40 5 -15 30 141 -15 -124 -66 -79 29 18 21 184 18 -191 -178 -155 -349 -186 -331 -100 212 -125 60 54 -108 50 -33 -113 106 79 84 3 530 -236 -88 -106 -81 -128 241 -121 -216 -205 128 -188 121 -18 -3 172 133 -77 338 281 -133 54 -33 -154 -42 141 233 40 -42 -119 -170 233 -131 29 134 -73 273 -229 170 -194 54 8 83 59 171 41 191 136 106 28 -45 -136 13 10 -117 11 156 -85 113 -412 -80 -260 81 47 22 -129 112 105 221 74 -108 89 98 -46 59 -127 33 -172 77 95 32 73 -206 -22 72 -69 -238 74 -29 194 24 69 28 299 -30 31 56 211 -112 -26 178 -142 53 -55 -199 -200 103 -96 24 70 -80 -251 61 314 52 -115 -308 138 -90 -123 -44 20 155 154 -21 -153 -192 -3 157 1 -221 -47 -89 -71 63 286 42 279 -110 56 -141 -304 165 -256 -148 26 108 -230 -143 -129 562 112 -105 67 -53 224 -198 81 42 85 -228 240 -314 171 431 164 103 -149 -205 50 189 -186 -42 -8 86 -185 184 -138 -248 17 52 -1 -67 31 113 -1 238 36 -226 72 -82 202 259 26 207 116 18 -105 -128 229 141 -46 110 -58 -14 -11 -121 11 -195 -56 -75 -26 35 151 -343 143 -139 -65 -224 45 181 30 74 -53 -335 -230 40 123 79 -198 -224 -103 25 195 -61 261 420 197 127 150 -39 73 284 -189 69 -125 51 -532 -74 123 -89 174 -76 31 -107 -6 179 -3 -204 -66 -177 17 -293 -82 -306 -307 106 129 -102 -148 -1 -69 -28 -129 217 -58 -54 -183 35 32 177 -168 13 178 -66 -48 239 0 -155 -140 306 -59 402 -143 246 -230 195 -2 1 -265 44 -311 30 -132 15 -29 -65 -58 9 210 48 422 -6 6 -28 -519 238 66 65 77 198 -264 -100 317 -151 -241 -153 50 70 -107 268 -12 116 341 -240 -12 96 -22 3 -138 -68 30 -125 42 -72 -50 55 7 203 -86 138 50 -22 82 251 38 306 259 -102 3 -33 173 -244 -6 -216 59 -180 137 -334 89 83 -30 34 -14 -302 -287 292 257 -16 -111 -8 258 179 -329 -106 166 -157 72 108 -266 263 107 51 -52 -140 57 90 78 -160 360 301 -229 242 75 -41 82 2 -38 -20 165 15 -133 236 118 38 462 -133 91 35 -84 161 -210 -233 -408 -251 47 -26 30 166 230 -154 213 -221 29 -173 -115 -79 41 113 72 -121 -118 -173 13 49 -352 27 -54 -16 124 59 -88 -247 236 -194 48 -56 68 -47 58 -16 248 -258 -63 -85 -190 48 166 65 86 -158 262 120 46 103 -37 -52 83 2 -14 28 63 -300 144 -2 -192 -90 333 9 377 2 31 36 -15 -167 94 228 -130 10 -14 162 -29 -90 -146 -224 218 25 -202 -339 422 3 -64 -109 -307 -42 5 -16 32 151 -16 -136 -71 -85 32 20 23 198 20 -202 -187 -164 -371 -198 -352 -105 225 -129 63 55 -109 51 -33 -116 110 83 87 3 571 -250 -96 -114 -87 -136 253 -126 -224 -218 137 -196 126 -19 -3 188 147 -84 366 310 -145 58 -36 -169 -47 156 257 45 -47 -133 -191 257 -142 31 145 -78 294 -251 188 -211 60 9 90 65 189 45 210 150 117 30 -51 -152 15 11 -131 12 175 -96 127 -463 -90 -290 90 53 25 -145 126 119 249 84 -122 101 111 -52 67 -143 38 -197 88 107 36 82 -235 -25 81 -77 -269 83 -33 215 27 78 32 337 -34 36 65 246 -130 -30 198 -159 57 -59 -218 -224 118 -108 27 80 -92 -284 69 359 59 -129 -349 157 -102 -140 -49 22 175 175 -24 -175 -219 -3 179 1 SQ 20240215T132838.0Z 8811.561551 246 1 3.25 2 70.88 213.94 46.42 124.07 0.00 1 0.00 1 0 33 6.462e-04 6.235e-04 5.939e-04 5.808e-04 1.655228e+03 1.072077e+02 1.607558e+02 5.354017e+02 1.237175e+02 266.07 -2.00 20.00 -2.00 445.80 0.00e+00 -4.200807e-05 6.502097e-05 2.730447e-06 2.303052e-05 7.091638e-05 266.07 -2.00 20.00 -2.00 454.95 0.00e+00 2.140683e-04 5.244502e-06 1.611115e-06 1.071111e-05 5.928465e-06 224.86 -2.00 2.40 -2.00 436.16 0.00e+00 1.337641e+05 7.901229e+04 2.835644e+04 3.498500e+05 9.218444e+04 250.07 -2.00 11.50 -2.00 457.28 0.00e+00 4.610488e-01 1.626942e-02 2.309733e-03 1.400429e-02 2.015498e-02 223.59 -2.00 3.85 -2.00 454.32 0.00e+00 1.317609e-06 2.059838e-06 2.493828e-07 1.760673e-06 2.496326e-06 266.07 -2.00 20.00 -2.00 455.46 0.00e+00 3.019 0.001 397.00 473.00 4 3.9297e+00 6.2234e-04 7.5164e-03 6.0209e-04 6.6499e-04 3.1276e-02 7.5979e-04 1.5696e-03 3.6157e-04 8.3028e-04 -2.6834e-03 4.2922e-04 2.0669e-04 1.4835e-04 4.6758e-04 -1.4772e-03 1.4382e-04 2.4413e-05 3.7804e-05 1.5744e-04 1.3051e-03 7.2899e-05 5.4533e-06 2.2058e-05 7.8178e-05 1.7726e-02 6.5501e-03 4.2600e-04 1.3616e-05 5.5580e-05 4.1585e-04 -1.3991e-04 6.9659e-06 3.7997e-07 5.9351e-07 7.6344e-06 -4.0082e-05 9.7577e-06 4.6092e-07 7.6211e-07 1.0403e-05 2.8298e-03 -4.3594e-05 4.3764e-01 6.2118e-02 1.4762e-03 3.4002e-03 6.4491e-02 12 1 1 12 1 1 91.20 16.16 1.14 0.00283 0.00316 27 96 1 2 0 115.790 14.98 16.16 19.39 21.69 21.58 29.9 1038.52 48 -282 83 -103 -5 -204 -4 -77 25 -23 73 158 73 -14 103 -56 0 -145 94 99 -31 40 63 27 32 83 -10 -43 18 74 8 -16 -60 289 44 -17 26 32 -13 21 -8 27 -130 113 74 50 -86 93 18 18 -95 115 49 -77 18 2 64 -40 -36 118 12 0 -6 -12 46 56 -26 39 12 63 -21 -159 -73 -77 -76 20 -167 79 -257 -10 -89 -86 -45 -27 -39 -59 -114 45 -70 95 69 5 11 -70 23 -48 15 18 -40 -2 63 24 31 3 132 -88 -31 -46 -16 33 -14 -72 59 25 32 4 -1 13 59 -5 -49 -7 38 26 -154 -122 -58 -20 33 -70 -30 -47 25 -100 36 0 22 3 -46 2 49 1 -96 -15 -73 -61 37 111 9 -4 -112 70 -17 -53 10 39 10 -42 -11 120 43 30 -33 27 16 65 -31 21 74 -75 16 53 18 -13 -39 64 -42 116 187 -46 -26 23 -9 -3 -49 26 -10 25 98 40 28 -41 124 47 45 14 -1 -56 -8 101 -97 -4 48 -25 27 -106 12 55 54 -15 1 -11 -22 101 14 -66 -15 55 -107 -55 -39 138 8 5 92 71 -54 34 29 -47 -48 -70 122 34 -42 36 -57 96 -162 -17 -12 56 -93 -4 -69 -29 30 69 -124 91 -84 50 58 -24 -56 1 15 50 -29 -41 -46 49 105 -14 127 22 13 -41 -60 -23 96 -38 -90 -15 -5 0 201 39 -14 -9 138 10 45 95 53 -21 -4 -31 -33 28 48 -69 -79 -96 -55 80 62 63 2 -4 -2 89 -42 -87 -95 -1 -172 -5 -27 -76 -48 56 1 -105 -40 44 -46 -34 10 41 -112 43 11 55 -102 79 -49 125 -13 82 -25 -66 -66 -76 -166 13 30 -13 -54 90 47 48 108 -37 -57 -29 -51 95 44 12 82 64 -65 -79 -7 21 119 26 -9 84 92 21 36 10 79 -54 3 -51 65 7 -82 -22 5 -70 24 7 -23 11 72 5 114 49 16 -24 -54 -20 -14 -44 -8 -87 3 17 -4 -45 -86 -4 -10 -36 -51 -54 -108 -33 -47 -7 5 -31 50 11 -6 -164 -38 1 -90 -30 31 -49 49 55 8 38 123 -82 -12 -13 35 59 55 -47 -27 -73 -37 77 -8 41 -51 -2 104 -64 -49 19 78 -19 68 -22 -45 -82 67 46 -29 -26 -90 16 16 70 -59 -22 5 -17 18 78 9 19 -22 -67 14 30 74 5 -18 51 -67 -71 -57 61 -9 1 -36 72 -54 -86 6 71 -20 3 9 -15 14 13 -6 45 40 76 1 115 -18 110 -19 75 41 -2 3 59 5 -75 16 9 -32 -2 -5 56 11 -39 -38 23 48 5 112 34 55 90 -19 -38 -20 89 -1 -43 44 53 -83 -25 -105 -96 -115 -78 -78 41 37 6 22 -5 64 -24 19 -8 -11 -138 23 39 -233 67 -81 -4 -164 -3 -64 21 -19 61 131 61 -11 86 -47 0 -123 79 84 -26 34 53 23 26 67 -8 -36 15 65 7 -14 -51 235 36 -14 22 28 -11 18 -7 23 -111 96 63 43 -73 76 14 15 -80 97 42 -65 15 1 56 -34 -31 102 10 0 -5 -11 40 50 -24 36 11 60 -20 -143 -66 -68 -66 17 -135 65 -210 -9 -77 -79 -41 -24 -36 -55 -106 43 -66 89 66 4 11 -67 22 -46 14 17 -37 -1 58 22 28 3 126 -86 -30 -43 -15 30 -13 -67 57 23 30 4 -1 12 55 -5 -47 -7 36 25 -150 -118 -57 -19 31 -65 -28 -43 23 -91 33 0 21 3 -43 2 46 1 -90 -14 -69 -58 36 108 9 -4 -103 62 -16 -48 9 36 10 -41 -11 118 42 30 -33 26 15 63 -30 20 73 -72 16 48 16 -11 -35 59 -40 112 177 -44 -24 21 -9 -3 -46 25 -10 24 93 38 26 -38 116 45 43 13 -1 -53 -8 93 -91 -4 48 -25 27 -102 11 49 48 -13 1 -11 -21 96 13 -63 -14 52 -101 -51 -36 125 7 5 83 65 -49 30 25 -39 -38 -55 96 27 -33 28 -44 77 -132 -14 -11 53 -91 -4 -70 -29 29 67 -115 83 -76 47 57 -24 -57 1 15 50 -28 -37 -40 42 93 -13 122 22 13 -41 -59 -22 94 -37 -89 -15 -5 0 200 39 -15 -10 140 10 46 95 53 -21 -4 -30 -32 27 48 -69 -77 -91 -51 73 57 59 2 -4 -2 87 -42 -87 -95 -1 -173 -5 -27 -75 -46 53 1 -103 -40 44 -47 -36 10 41 -112 43 11 56 -106 81 -51 129 -13 83 -26 -68 -67 -78 -168 13 31 -14 -56 93 48 48 110 -38 -60 -30 -53 97 46 13 82 63 -63 -78 -7 21 119 26 -9 87 96 21 37 10 82 -57 3 -54 69 7 -86 -23 5 -72 25 8 -24 12 76 6 120 52 17 -25 -57 -21 -16 -47 -9 -94 4 18 -4 -49 -94 -4 -10 -39 -55 -59 -117 -35 -51 -8 5 -33 53 12 -6 -168 -39 1 -94 -32 32 -52 53 60 8 41 133 -88 -13 -15 37 62 58 -50 -28 -79 -40 85 -9 46 -58 -2 115 -70 -55 21 86 -21 76 -25 -50 -92 76 51 -32 -30 -99 18 18 77 -64 -25 5 -19 21 87 10 21 -24 -73 16 33 82 6 -20 57 -76 -82 -66 71 -11 2 -41 83 -62 -99 7 82 -24 3 11 -18 17 15 -7 53 47 88 1 134 -20 126 -22 88 48 -3 3 68 6 -85 18 10 -36 -3 -6 65 13 -46 -45 27 57 5 133 39 63 101 -21 -42 -23 102 -1 -50 52 63 -97 -29 -121 -111 -134 -92 -92 49 44 7 26 -6 75 -29 22 -9 -12 -159 26