File name: Pandora183s1_LondonderryNH_20230818_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20230819T202145.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20230818_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20230818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230818T155611.1Z 8630.664017 6 1 1.11 2 31.97 154.94 49.75 126.50 0.00 1 0.00 1 0 17 1.147e-02 9.195e-03 6.954e-03 5.044e-03 1.536547e-01 2.603464e-03 1.868166e-03 -6.000000e+00 6.596967e-03 231.63 -2.00 3.55 -2.00 314.60 0.00e+00 7.854410e-04 2.112767e-04 4.180951e-05 -6.000000e+00 2.937843e-04 288.24 -2.00 20.00 -2.00 313.97 0.00e+00 1.178 0.000 302.00 328.00 3 2.9011e+00 6.7017e-03 1.4206e-02 -6.0000e+00 1.6516e-02 3.5845e-02 7.4192e-03 8.0928e-03 -6.0000e+00 1.7875e-02 1.8375e-03 4.2444e-03 3.8817e-03 -6.0000e+00 1.0653e-02 -6.9316e-03 1.8408e-03 1.1150e-03 -6.0000e+00 4.4991e-03 7.8880e-03 -3.8208e-04 1.3948e-04 1.3770e-05 -6.0000e+00 3.0286e-04 -3.7148e-03 5.9965e-05 12 9 1 12 1 1 999.00 22.84 0.37 -0.00371 -0.00659 1 22 1 5 0 466.100 26.51 20.00 22.84 27.88 27.8 1042.63 -1309 -1667 929 -1184 -3482 -577 134 -541 -564 70 -212 -2268 -357 -353 -1156 1250 -710 174 1470 1501 1894 1117 1057 2850 511 1211 341 -1165 97 2400 2152 1133 2243 -534 -4186 -1783 -3633 -1855 -406 -876 -896 -688 521 -1070 -565 221 -404 -144 -394 -1222 -518 682 231 1782 -392 380 898 71 758 254 1214 1596 1614 2197 441 795 -625 -516 691 398 803 -198 1114 499 605 13 -1107 -1484 -302 -1309 -1972 -1983 -2057 -1103 -653 -840 -57 148 975 962 277 -250 -1288 116 -551 -76 -116 1248 375 -464 -506 -826 -557 -508 -1138 -1302 -373 -517 -457 1240 883 856 385 141 -216 -234 1029 -403 1156 305 -383 341 923 845 891 -51 -1154 1574 158 -252 -317 -196 -13 -278 443 132 326 413 -272 221 57 -852 -1327 -471 -665 371 -462 -1220 -194 45 -184 -215 28 -84 -889 -145 -160 -547 631 -377 93 793 830 1070 629 591 1617 288 701 200 -657 53 1213 1099 615 1278 -325 -2488 -970 -2117 -1128 -290 -688 -726 -581 445 -938 -490 189 -340 -116 -326 -991 -428 553 198 1562 -361 351 788 63 694 231 1119 1465 1595 2157 441 769 -586 -455 621 380 797 -209 1168 512 619 12 -983 -1300 -263 -1193 -1902 -2098 -2190 -1211 -721 -1001 -68 182 1199 1148 324 -282 -1394 117 -574 -81 -136 1506 460 -567 -612 -976 -621 -585 -1362 -1656 -466 -673 -618 1650 1229 1198 516 184 -270 -287 1234 -484 1473 401 -525 462 1214 1120 1117 -61 -1396 1836 197 -317 -415 -260 -17 -365 613 184 466 603 -404 320 81 -1229 -1886 SS 20230818T180310.8Z 8630.752209 41 1 51.29 2 33.85 213.61 37.70 168.78 0.00 1 0.00 1 0 17 9.839e-03 7.505e-03 2.426e-04 1.397e-04 1.606512e-01 7.099385e-05 1.952028e-03 -6.000000e+00 5.660007e-03 231.62 -2.00 3.55 -2.00 315.65 0.00e+00 5.224132e-04 6.995434e-06 1.118085e-04 -6.000000e+00 2.520247e-04 288.23 -2.00 20.00 -2.00 314.89 0.00e+00 1.203 0.000 302.00 328.00 3 -2.9504e-02 1.8485e-04 1.4623e-02 -6.0000e+00 1.4170e-02 1.9195e-02 2.0565e-04 8.4066e-03 -6.0000e+00 1.5335e-02 4.9555e-04 1.1750e-04 4.0671e-03 -6.0000e+00 9.1390e-03 -6.4837e-03 5.3038e-05 1.1185e-03 -6.0000e+00 3.8607e-03 1.4320e-01 2.9441e-04 3.9266e-06 1.3436e-05 -6.0000e+00 2.5979e-04 -3.8373e-03 1.1927e-04 11 8 0 10 0 0 99.92 22.81 0.26 -0.00384 -0.00162 2672 555 1 5 0 18.330 26.41 19.99 22.81 31.98 27.8 1071.02 284 -431 -107 -2129 -3037 -2114 -1015 879 551 -275 -2194 -1468 -737 -584 470 245 -148 630 702 1366 1112 554 1256 1322 822 869 327 -195 -559 161 979 937 1641 -459 -2984 -2691 -2942 -1715 -668 -443 -943 -510 -597 -604 -92 -139 -434 -532 -895 -588 480 577 880 1051 697 1010 811 413 249 457 958 1564 1709 2165 611 -94 -550 -893 777 619 500 855 508 790 306 -393 -960 -1706 -899 -1225 -1444 -1506 -2350 -1475 -766 -585 -180 345 794 671 393 -32 -801 -218 -403 -426 388 892 141 -290 -486 -1235 -900 -333 -1166 -1100 -762 -770 68 619 999 596 580 200 -167 124 187 66 569 350 205 486 711 457 746 -43 -13 901 248 72 -205 -436 -262 12 -3 -76 246 519 36 -120 -191 -775 -806 65 -110 -28 -596 -753 -470 -226 211 149 -80 -640 -412 -218 -192 172 98 -62 263 301 597 500 248 555 604 396 433 165 -93 -246 66 404 408 754 -224 -1404 -1186 -1371 -905 -379 -294 -692 -389 -467 -477 -72 -108 -331 -389 -632 -404 335 427 682 848 580 848 694 354 210 381 812 1401 1647 2016 577 -89 -474 -731 647 582 476 851 512 772 308 -360 -788 -1302 -688 -1040 -1373 -1573 -2416 -1568 -863 -709 -230 455 1048 859 468 -34 -857 -219 -419 -483 441 1109 187 -382 -603 -1421 -980 -372 -1435 -1436 -1034 -1087 92 872 1463 880 819 283 -216 149 222 83 757 503 282 717 1020 629 969 -53 -15 1137 305 94 -279 -605 -366 17 -4 -113 375 808 58 -186 -288 -1135 -1255 SS 20230818T181402.2Z 8630.759748 44 1 51.20 2 35.01 217.81 37.43 173.12 0.00 1 0.00 1 0 17 9.861e-03 7.443e-03 2.323e-04 1.336e-04 1.633286e-01 6.844914e-05 1.989115e-03 -6.000000e+00 5.670748e-03 231.62 -2.00 3.55 -2.00 315.64 0.00e+00 5.302093e-04 6.691795e-06 1.196052e-04 -6.000000e+00 2.525504e-04 288.23 -2.00 20.00 -2.00 314.87 0.00e+00 1.220 0.000 302.00 328.00 3 -1.1681e-01 1.7812e-04 1.4845e-02 -6.0000e+00 1.4197e-02 1.6803e-02 1.9815e-04 8.5471e-03 -6.0000e+00 1.5366e-02 1.3887e-03 1.1328e-04 4.1405e-03 -6.0000e+00 9.1573e-03 -6.7371e-03 5.0969e-05 1.1408e-03 -6.0000e+00 3.8669e-03 1.5291e-01 -1.2841e-04 3.7615e-06 1.3999e-05 -6.0000e+00 2.6038e-04 -3.0508e-03 4.8323e-05 11 8 0 10 0 0 65.65 22.79 0.26 -0.00305 -0.00402 2645 549 1 5 0 18.520 26.41 20.01 22.79 34.26 27.6 1086.47 255 -414 -170 -2229 -3119 -2230 -938 799 546 -287 -2231 -1530 -677 -596 488 268 -137 698 709 1377 1243 520 1316 1276 856 829 314 -236 -606 178 953 939 1635 -457 -3027 -2695 -2876 -1732 -548 -447 -920 -504 -533 -586 -89 -71 -459 -487 -925 -640 468 587 875 961 656 963 829 382 222 426 961 1537 1770 2199 636 -87 -570 -926 772 593 509 832 521 781 314 -359 -932 -1698 -935 -1163 -1420 -1450 -2297 -1421 -734 -570 -140 367 827 691 384 -63 -833 -276 -470 -449 351 873 89 -299 -464 -1211 -879 -298 -1158 -1070 -731 -742 62 642 1004 650 619 291 -141 156 156 60 545 316 184 462 710 453 752 -53 -12 897 217 47 -226 -455 -299 -8 -27 -90 227 500 51 -102 -153 -747 -787 63 -104 -44 -616 -763 -490 -206 190 146 -82 -644 -425 -199 -195 177 107 -57 290 303 600 556 232 579 582 411 413 158 -113 -266 73 394 410 753 -224 -1429 -1193 -1345 -918 -312 -298 -679 -387 -419 -466 -70 -55 -352 -359 -658 -443 330 438 684 785 552 817 716 331 190 359 823 1392 1581 2071 608 -83 -498 -768 651 565 491 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