File name: Pandora183s1_LondonderryNH_20230909_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20230910T044857.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20230909_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20230909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230909T112438.5Z 8652.475446 249 1 49.46 2 78.76 93.19 22.19 127.96 0.00 1 0.00 1 0 17 3.566e-01 1.739e-02 2.889e-01 1.101e-02 5.520069e-01 5.941620e-03 7.865330e-03 -6.000000e+00 2.038856e-01 229.68 -2.00 3.55 -2.00 321.31 0.00e+00 8.940734e-03 2.880003e-03 7.498682e-03 -6.000000e+00 9.927992e-03 286.46 -2.00 20.00 -2.00 320.69 0.00e+00 4.952 0.002 302.00 328.00 3 2.6927e+00 2.0746e-02 6.5936e-02 -6.0000e+00 5.0960e-01 1.6178e-01 2.7383e-02 5.1556e-02 -6.0000e+00 5.5350e-01 -2.1840e-01 2.5038e-02 2.5923e-02 -6.0000e+00 3.2871e-01 7.7284e-02 1.2045e-02 7.0108e-03 -6.0000e+00 1.4081e-01 1.4997e-04 -9.2310e-04 3.2924e-04 1.6227e-04 -6.0000e+00 9.6038e-03 -2.4025e-04 4.1057e-05 12 8 8 10 0 0 98.98 22.72 0.52 -0.00024 -0.00718 26 5 1 5 0 1902.160 26.32 20.00 22.72 28.18 27.6 1031.15 900000 -161776 111840 900000 -92197 -76375 -188420 -137275 20233 900000 -94599 900000 53616 -48426 -75275 -52227 118219 -39813 15443 20808 -57107 -21133 44768 -23512 -56438 -9139 -24902 -48509 10267 -13018 -1197 -21942 -3016 -5572 40552 -47788 3881 -10481 12911 25525 4503 3034 17161 8440 -5037 13282 20630 10212 14126 -3073 5379 -7254 15913 19294 12040 2757 -1015 4271 -7458 5311 -4161 6765 14507 5501 8486 1457 8810 -86 3580 -2255 886 4105 880 5143 1737 -1047 -1568 215 -4976 -7137 -803 1023 -901 -2308 2503 -2927 1322 -803 5945 24 -83 -803 -3051 -80 -5153 -1531 -887 1068 1294 94 -1152 -5573 -3314 -2264 -2198 -726 -98 -1585 -1645 1982 1022 2232 658 376 -2735 -120 1481 -1104 1616 197 1630 590 1050 1420 -251 1719 -176 552 -1173 170 -795 -1004 -862 -62 412 -338 639 780 638 -309 -6 -480 -1111 900000 -3739 1200 900000 -1066 -820 -5289 -2701 217 900000 -1438 900000 575 -780 -2020 -1355 1269 -1139 276 372 -2298 -586 641 -694 -2423 -253 -824 -1996 230 -419 -40 -1070 -141 -294 1306 -3543 182 -654 768 1594 391 287 1490 832 -580 1309 1932 1086 1488 -402 703 -1196 2267 2861 2020 522 -204 813 -1557 964 -856 1366 3071 1433 2277 408 2200 -24 1020 -783 332 1566 346 1847 595 -331 -457 61 -1621 -2799 -345 492 -484 -1331 1614 -1942 888 -628 4370 18 -59 -530 -1942 -50 -3711 -1224 -813 1098 1453 107 -1253 -5729 -3055 -2079 -2182 -755 -106 -1870 -2108 2721 1557 3531 1052 578 -4065 -166 2023 -1625 2473 321 2630 934 1598 2082 -358 2318 -232 749 -1811 289 -1487 -1989 -1779 -133 950 -829 1588 1973 1618 -763 -15 -1066 -2419 SS 20230909T113035.1Z 8652.479573 252 1 50.48 2 77.68 94.22 21.37 130.64 0.00 1 0.00 1 0 25 3.977e-01 1.284e-02 2.995e-01 8.479e-03 5.384089e-01 4.515362e-03 6.538581e-03 -6.000000e+00 2.279340e-01 229.68 -2.00 3.55 -2.00 321.08 0.00e+00 3.173265e-03 2.061708e-03 3.649829e-03 -6.000000e+00 1.027076e-02 286.46 -2.00 20.00 -2.00 320.43 0.00e+00 4.549 0.002 302.00 328.00 3 2.7963e+00 1.5262e-02 5.5749e-02 -6.0000e+00 5.6768e-01 1.1110e-01 2.0049e-02 3.6051e-02 -6.0000e+00 6.1565e-01 -1.1981e-01 1.8497e-02 1.7683e-02 -6.0000e+00 3.6651e-01 3.0497e-02 8.9603e-03 4.6759e-03 -6.0000e+00 1.5483e-01 2.0144e-04 -4.5905e-04 2.5190e-04 8.2775e-05 -6.0000e+00 1.0507e-02 -7.4349e-04 4.1664e-05 12 8 8 10 0 0 99.63 22.73 0.29 -0.00074 -0.00419 30 6 1 5 0 1682.300 26.32 20.00 22.73 28.62 27.4 1034.42 -44581 -115624 -91794 8233 -156228 900000 -175317 -96931 -78974 -5999 -20948 -71003 -77796 -96308 227787 85099 -46455 -587 104458 -16497 -10134 20163 -34064 122411 44059 49724 6766 -11592 256 -19058 37439 -21297 18918 -4886 -6513 -3668 12198 6537 7942 8193 -13860 6867 9136 -2666 5275 2143 -5755 14773 1313 636 7096 -2761 8153 -368 2734 12423 4096 3668 -8346 2532 2464 277 7855 6143 5383 2435 -1767 3092 1521 1804 2033 -995 -2765 2774 -3051 2337 -1826 -7193 -2156 -3362 -2036 -2961 577 -532 1486 933 895 1390 2095 1669 1421 -1007 -2891 -1570 -1378 -1451 1177 94 -99 -774 142 -2991 -1451 -914 -2135 -2666 -811 -110 1175 351 207 1121 1220 -71 -1247 -778 -894 112 492 939 42 1155 1052 517 425 -557 265 700 27 -103 -590 -564 120 -536 -465 29 1308 778 -133 -140 -182 -93 -1108 -369 -1618 -1109 68 -3552 900000 -4711 -1336 -1034 -50 -173 -1027 -1447 -2720 1883 704 -1344 -12 864 -443 -265 389 -1150 1012 861 972 208 -418 8 -731 929 -1120 768 -275 -362 -190 578 383 561 696 -1667 723 989 -335 619 264 -779 1654 173 88 1003 -479 1385 -73 561 2400 887 800 -2001 535 533 67 1972 1754 1635 738 -535 897 485 660 827 -439 -1241 1124 -1209 866 -646 -2641 -818 -1512 -1052 -1596 361 -357 1043 706 716 1143 1716 1329 1058 -711 -1960 -1055 -1015 -1225 1110 102 -117 -925 158 -3103 -1364 -863 -2210 -2944 -925 -132 1513 505 326 1835 1980 -111 -1855 -1097 -1268 165 769 1536 69 1834 1618 772 608 -773 350 953 41 -176 -1095 -1104 242 -1154 -1071 69 3193 1946 -336 -340 -420 -204 -2391 SS 20230909T114026.5Z 8652.486418 258 1 49.89 2 75.88 95.94 20.08 135.48 0.00 1 0.00 1 0 17 1.340e-01 7.079e-03 1.245e-01 3.438e-03 4.765523e-01 1.781292e-03 5.676970e-03 -6.000000e+00 7.646058e-02 229.68 -2.00 3.55 -2.00 320.61 0.00e+00 1.231991e-03 7.059772e-04 2.120659e-03 -6.000000e+00 3.404700e-03 286.46 -2.00 20.00 -2.00 319.90 0.00e+00 4.007 0.001 302.00 328.00 3 2.2507e+00 5.6183e-03 4.7951e-02 -6.0000e+00 1.9063e-01 2.2093e-03 7.1072e-03 2.8617e-02 -6.0000e+00 2.0674e-01 -1.7644e-02 6.3815e-03 1.3669e-02 -6.0000e+00 1.2327e-01 -5.3390e-03 3.1889e-03 3.6071e-03 -6.0000e+00 5.2139e-02 6.4140e-04 -4.3738e-04 1.0175e-04 5.0829e-05 -6.0000e+00 3.5366e-03 -2.5844e-04 9.2818e-06 11 8 0 10 0 0 98.37 22.75 0.28 -0.00026 -0.00355 61 13 1 5 0 817.730 26.32 19.99 22.75 29.14 27.3 1036.60 -33308 -29799 -14493 27705 -63237 -54058 17828 -33078 -66706 -40249 2753 -27455 -28441 -45395 -21331 -14062 -8797 -13016 -25265 13793 -3688 -4228 -14958 -15989 -5379 -16835 -9722 -2021 -258 -8390 6834 -13320 -3474 -8044 -6383 -6119 -1132 -9728 -4055 1151 -703 315 -2903 1863 2761 -4051 -3008 -1404 754 1930 818 2120 1568 3407 491 2677 1834 1340 406 1394 -1152 3260 2693 3399 2528 624 -453 580 349 1301 84 1552 1254 803 74 -177 -1218 -3809 -1952 -1053 -611 -1392 -1454 -1332 -1094 271 904 524 1305 1491 130 -176 -382 -1408 -1233 -724 337 836 437 -359 -721 -1653 -999 -505 -1336 -1414 -1148 -898 240 310 805 324 832 -47 -391 -133 -136 330 178 164 468 623 773 603 247 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