File name: Pandora183s1_LondonderryNH_20231001_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231003T044955.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231001_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231001T123323.3Z 8674.523186 281 1 1.41 2 71.18 113.39 83.15 282.83 0.00 1 0.00 1 0 17 5.654e-02 1.067e-02 4.997e-02 8.541e-03 3.490881e-01 4.262890e-03 4.139220e-03 -6.000000e+00 3.198622e-02 227.26 -2.00 3.55 -2.00 318.23 0.00e+00 2.388915e-04 7.957577e-04 3.492002e-04 -6.000000e+00 1.422108e-03 283.99 -2.00 20.00 -2.00 317.46 0.00e+00 3.062 0.000 302.00 328.00 3 2.1302e+00 1.1469e-02 3.5134e-02 -6.0000e+00 7.9357e-02 3.3442e-02 1.3080e-02 1.8148e-02 -6.0000e+00 8.6245e-02 -1.1461e-02 8.5431e-03 8.8738e-03 -6.0000e+00 5.1448e-02 2.8188e-03 4.4260e-03 2.4760e-03 -6.0000e+00 2.1828e-02 2.0344e-03 -5.3310e-05 2.4115e-04 2.5122e-05 -6.0000e+00 1.4913e-03 -1.4052e-03 6.7542e-05 12 9 9 12 1 1 999.00 22.78 0.12 -0.00141 -0.00181 1 15 1 5 0 701.420 26.41 20.01 22.78 19.83 27.2 973.67 -26348 -8115 13119 9391 8639 10504 -15953 -12335 -27886 -11153 -21973 20705 -3446 -6803 5535 -9791 5919 -7167 8001 -10765 432 9150 2946 6738 -925 -3097 -2865 -4262 -3430 7585 -1833 2800 4010 1928 -2111 -4848 1978 -2723 -1337 -617 -182 -836 -2377 -508 193 747 -346 -2078 1617 -1677 2997 1019 1020 1488 3894 2022 1619 2558 1291 -313 -888 2500 1056 1685 1465 -1169 1351 -2457 190 -676 -254 1411 1566 1062 31 1130 -3190 -1462 -2241 -1203 -981 -683 -1226 -2795 16 -1750 338 244 978 1690 1089 -5 -1002 209 -314 -80 -39 -1188 -367 -413 -1428 -375 -2037 510 -988 -525 -1189 -296 674 1346 321 254 727 -296 -1020 685 102 179 900 -131 584 462 844 -56 295 439 -55 817 -72 -241 5 -119 -103 1425 145 -404 1125 61 -586 219 -577 -632 -1108 -1476 -480 667 485 403 446 -917 -771 -2323 -855 -1903 1190 -284 -686 581 -1370 764 -1110 1126 -1910 71 1372 476 1117 -178 -642 -604 -873 -651 1264 -359 583 915 480 -524 -1179 479 -732 -430 -235 -78 -381 -1048 -224 92 357 -166 -1002 747 -810 1466 508 545 843 2252 1225 1011 1587 794 -192 -562 1643 716 1235 1105 -853 970 -1653 132 -541 -208 1198 1332 942 26 840 -2238 -1041 -1687 -943 -875 -631 -1230 -2792 17 -1986 397 279 1188 1972 1187 -5 -1010 203 -327 -86 -47 -1532 -504 -564 -1847 -467 -2412 602 -1208 -678 -1618 -395 946 2026 492 400 1109 -453 -1450 958 143 246 1321 -206 927 723 1276 -81 410 619 -74 1106 -107 -366 8 -188 -166 2367 246 -724 2038 114 -1107 397 -1012 -1121 -1933 SS 20231001T123843.5Z 8674.526893 284 1 49.49 2 70.29 114.44 84.06 283.70 0.00 1 0.00 1 0 17 2.453e-02 6.693e-03 9.333e-03 1.135e-03 3.317258e-01 5.643735e-04 3.983517e-03 -6.000000e+00 1.387603e-02 227.26 -2.00 3.55 -2.00 318.92 0.00e+00 1.102232e-03 1.286137e-04 6.405635e-04 -6.000000e+00 6.169490e-04 283.99 -2.00 20.00 -2.00 318.15 0.00e+00 2.932 0.000 302.00 328.00 3 1.8518e+00 1.5552e-03 3.3686e-02 -6.0000e+00 3.4426e-02 2.6663e-02 1.7955e-03 1.7532e-02 -6.0000e+00 3.7416e-02 9.1621e-03 1.2675e-03 8.6537e-03 -6.0000e+00 2.2319e-02 -1.0686e-02 6.6622e-04 2.4822e-03 -6.0000e+00 9.4683e-03 3.1063e-03 -2.2325e-04 3.3045e-05 2.7257e-05 -6.0000e+00 6.4706e-04 -1.1116e-03 4.4950e-05 11 8 0 10 0 0 99.68 22.78 0.22 -0.00111 -0.00279 118 25 1 5 0 419.290 26.41 19.99 22.78 19.94 27.2 975.06 -2938 -2903 -6073 -6379 -8577 -7269 -6465 -8499 -6242 -10932 -8387 -8502 -4088 -2087 -1124 -1341 -1938 -140 -644 862 -358 -676 -617 -207 13 -306 -840 -2330 -2911 -1689 -823 7 314 -2039 -3731 -4416 -3736 -2917 -549 -668 -1136 -529 -510 -287 -40 419 -126 -357 -568 -370 520 547 1101 1429 852 1305 828 344 335 167 1033 2077 2621 2868 1151 181 -374 -844 560 823 627 964 428 1046 328 -460 -1276 -1795 -862 -1232 -1356 -1190 -2199 -1503 -718 -632 -6 436 1086 880 692 216 -660 -217 -585 -537 338 696 156 -307 -676 -1509 -867 -402 -1287 -1239 -807 -773 111 504 880 364 426 262 -395 -6 102 144 385 462 -25 444 735 320 627 -147 -47 728 280 78 -230 -454 -279 86 33 -96 286 552 151 -130 -136 -697 -525 -97 -111 -254 -262 -324 -251 -229 -345 -281 -560 -424 -436 -226 -134 -84 -115 -181 -13 -73 100 -43 -82 -76 -27 2 -45 -126 -339 -399 -225 -116 1 54 -382 -680 -772 -692 -622 -139 -201 -385 -189 -189 -108 -15 159 -48 -134 -211 -139 205 234 501 689 431 675 441 184 176 87 545 1165 1609 1908 798 120 -230 -508 352 588 498 729 327 842 248 -316 -797 -1072 -534 -870 -1093 -1068 -1955 -1394 -706 -667 -7 499 1240 974 713 205 -637 -203 -584 -543 381 873 211 -415 -858 -1764 -943 -446 -1565 -1597 -1085 -1091 164 801 1364 581 659 416 -580 -9 140 206 591 752 -41 725 1161 487 907 -204 -62 967 404 122 -384 -784 -493 159 60 -181 554 1087 300 -252 -253 -1247 -1003 SS 20231001T124941.0Z 8674.534503 287 1 49.69 2 68.48 116.63 85.91 285.48 0.00 1 0.00 1 0 17 2.034e-02 6.803e-03 4.877e-03 7.726e-04 3.059298e-01 3.852947e-04 3.661160e-03 -6.000000e+00 1.150379e-02 227.26 -2.00 3.55 -2.00 318.53 0.00e+00 1.183681e-03 7.778075e-05 4.990745e-04 -6.000000e+00 5.114853e-04 283.99 -2.00 20.00 -2.00 317.75 0.00e+00 2.701 0.000 302.00 328.00 3 1.4685e+00 1.0483e-03 3.0975e-02 -6.0000e+00 2.8541e-02 2.1924e-02 1.1980e-03 1.5981e-02 -6.0000e+00 3.1020e-02 9.1131e-03 7.9967e-04 7.9317e-03 -6.0000e+00 1.8504e-02 -9.5917e-03 4.1717e-04 2.3344e-03 -6.0000e+00 7.8492e-03 5.9043e-03 -2.8813e-04 2.2448e-05 2.3758e-05 -6.0000e+00 5.3648e-04 -9.6409e-04 3.2986e-05 11 8 0 10 0 0 81.80 22.79 0.27 -0.00096 -0.00313 199 41 1 5 0 249.610 26.41 19.99 22.79 20.53 27.2 979.66 -3687 -5474 -2990 -5503 -7382 -4740 -9508 -3718 -5041 -3198 -6386 -5889 -4351 -4654 791 -2175 -120 516 714 1033 876 219 -191 666 -1339 541 -1027 -1951 -1591 -1876 263 -263 1360 -1475 -3508 -3863 -4428 -2164 -956 -546 -1475 -4 -377 -316 168 349 -185 -74 -323 -605 1063 595 1116 1181 928 1057 814 483 152 363 889 1860 2276 2523 1223 -137 -101 -902 1096 723 666 826 461 957 68 -349 -1023 -1774 -910 -1224 -1342 -1351 -2172 -1671 -642 -628 -4 333 994 870 554 214 -562 -28 -444 -488 366 737 132 -499 -643 -1530 -902 -563 -1260 -1133 -817 -631 90 715 893 456 475 156 -252 10 146 11 429 131 210 520 656 420 564 -127 8 878 138 48 -197 -453 -207 46 47 -98 369 495 17 -55 -151 -708 -628 -167 -289 -163 -301 -368 -212 -460 -190 -296 -199 -413 -382 -342 -392 81 -262 -15 68 99 148 130 33 -29 105 -230 96 -187 -344 -261 -301 44 -49 273 -323 -749 -787 -966 -535 -282 -191 -581 -2 -161 -138 73 152 -80 -32 -136 -257 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