File name: Pandora183s1_LondonderryNH_20231006_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231007T150529.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231006_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231006 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231006T134057.2Z 8679.570107 330 1 49.70 2 61.89 129.40 39.00 261.90 0.00 1 0.00 1 0 17 1.835e-02 7.464e-03 1.281e-02 2.736e-03 2.479688e-01 1.355259e-03 2.983779e-03 -6.000000e+00 1.036180e-02 226.67 -2.00 3.55 -2.00 318.39 0.00e+00 7.510385e-04 2.539582e-04 4.999512e-04 -6.000000e+00 4.604613e-04 283.36 -2.00 20.00 -2.00 317.57 0.00e+00 2.112 0.000 302.00 328.00 3 3.3553e+00 3.6782e-03 2.4441e-02 -6.0000e+00 2.5678e-02 2.7062e-02 4.1972e-03 1.2931e-02 -6.0000e+00 2.7919e-02 7.9718e-03 2.6715e-03 6.3764e-03 -6.0000e+00 1.6656e-02 -1.2672e-02 1.3599e-03 1.8189e-03 -6.0000e+00 7.0730e-03 1.7214e-03 2.3554e-04 8.2241e-05 1.9250e-05 -6.0000e+00 4.8397e-04 -1.8496e-03 1.1201e-04 11 8 0 10 0 0 99.99 22.74 0.26 -0.00185 -0.00008 385 80 1 5 0 129.070 26.32 20.00 22.74 26.94 27.9 1022.93 -4418 -2570 -1254 2255 -8819 4632 -5277 245 -875 807 -1068 -5826 -1249 -4458 1641 -1565 -1551 2229 -578 3787 -2788 2630 -845 1004 -420 1574 -742 -3528 -1233 -3158 3374 -1795 3863 314 -4021 -3045 -5116 -525 -1210 692 -952 -436 -1068 -635 416 -644 862 -1244 -728 -1009 1525 1414 1367 1969 -200 1815 441 805 -301 806 507 1272 2421 1976 1205 -245 -878 -1315 825 922 442 1672 15 1623 -151 37 -1039 -1972 -777 -1576 -1173 -1988 -1889 -1743 -237 -289 193 507 665 872 46 260 -968 -461 -357 -740 531 429 143 -802 -264 -1421 -1031 -371 -1760 -893 -1250 -597 19 990 898 528 523 159 -248 -150 164 -181 550 465 0 554 663 614 404 -197 -444 898 175 46 -35 -696 -120 -40 -172 -152 151 737 86 35 -332 -116 -851 -302 -195 -98 165 -639 269 -375 18 -75 73 -98 -558 -125 -531 212 -233 -244 349 -97 631 -511 453 -151 185 -83 319 -156 -726 -229 -576 600 -364 805 71 -988 -702 -1277 -145 -403 268 -415 -199 -507 -305 197 -309 401 -575 -327 -452 694 693 710 1072 -115 1044 263 478 -177 463 299 796 1632 1435 892 -171 -564 -816 524 664 354 1388 13 1312 -117 25 -652 -1172 -470 -1079 -902 -1706 -1736 -1673 -239 -314 220 599 789 998 49 253 -867 -394 -320 -734 578 518 185 -1036 -318 -1589 -1082 -398 -2086 -1113 -1634 -811 27 1481 1420 849 810 230 -362 -205 222 -257 834 685 0 911 1059 941 589 -275 -590 1182 249 71 -56 -1150 -200 -69 -318 -295 301 1491 176 69 -642 -215 -1565 SS 20231006T134524.9Z 8679.573204 333 1 3.31 2 61.27 130.44 39.79 262.76 0.00 1 0.00 1 0 17 2.509e-02 1.062e-02 1.965e-02 7.176e-03 2.437132e-01 3.564402e-03 2.957638e-03 -6.000000e+00 1.415900e-02 226.67 -2.00 3.55 -2.00 316.91 0.00e+00 9.366231e-04 4.701157e-04 2.913475e-04 -6.000000e+00 6.293003e-04 283.36 -2.00 20.00 -2.00 316.18 0.00e+00 2.070 0.000 302.00 328.00 3 3.6556e+00 9.3295e-03 2.3912e-02 -6.0000e+00 3.5087e-02 3.5214e-02 1.0502e-02 1.2517e-02 -6.0000e+00 3.8157e-02 2.1467e-03 6.1971e-03 6.1538e-03 -6.0000e+00 2.2763e-02 -5.8035e-03 3.0026e-03 1.7644e-03 -6.0000e+00 9.6615e-03 1.3292e-03 -4.6514e-04 2.0222e-04 1.8654e-05 -6.0000e+00 6.6173e-04 -9.3271e-04 1.4866e-05 12 9 9 12 1 1 999.00 22.73 0.26 -0.00093 -0.00443 1 6 1 5 0 1651.480 26.32 20.00 22.73 26.87 27.7 1021.65 9302 -5971 4160 11163 4164 667 -5390 -413 -5069 -6251 -5367 -3307 -5014 -3499 1495 -2292 -623 -2891 -4367 2183 3142 5453 604 1520 5982 4334 77 -2377 -4262 1523 -2658 -2557 2372 4995 -4151 -2045 -6830 -1639 2631 410 -2340 -1824 414 -613 495 484 -1312 -2514 -829 343 -9 301 1545 723 -630 1451 878 1351 1553 1455 1287 2458 2078 3831 1603 -994 -197 -793 519 -475 1034 1241 547 169 -403 -288 -873 -1832 -230 -3194 -954 -1150 -1807 -888 -426 -435 -740 1034 -97 619 323 434 -1195 -1191 -914 -1719 101 567 -176 649 -1046 -755 -825 -452 -1228 -812 -1061 -737 1403 934 1095 389 439 268 145 -1 342 -32 546 812 264 193 356 -514 787 872 -622 882 1072 -754 553 -483 -1197 -271 -48 386 702 297 231 194 -385 -1021 -645 1061 -894 588 1422 504 76 -671 -54 -787 -1054 -894 -535 -902 -712 333 -592 -167 -817 -1305 632 928 1561 182 474 1888 1450 27 -818 -1384 449 -848 -882 845 1825 -1574 -718 -2667 -701 1177 221 -1441 -1078 247 -374 298 319 -866 -1634 -517 210 -6 206 1014 504 -460 1058 656 1005 1130 1048 950 1916 1771 3438 1373 -880 -158 -614 415 -434 951 1197 534 160 -361 -251 -686 -1361 -173 -2774 -913 -1126 -1910 -972 -461 -506 -913 1298 -124 759 369 484 -1233 -1176 -944 -1973 117 728 -227 879 -1351 -892 -990 -516 -1538 -1074 -1470 -993 1942 1383 1707 580 672 383 203 -2 444 -44 741 1175 394 286 511 -714 1097 1156 -793 1110 1439 -1105 784 -710 -1798 -419 -79 621 1156 502 394 323 -620 -1700 -1049 SS 20231006T134907.2Z 8679.575778 336 1 1.62 2 60.75 131.32 40.45 263.46 0.00 1 0.00 1 0 17 1.413e-02 8.715e-03 8.593e-03 3.803e-03 2.398846e-01 1.900980e-03 2.933644e-03 -6.000000e+00 7.970900e-03 226.67 -2.00 3.55 -2.00 316.45 0.00e+00 7.116293e-04 2.231250e-04 1.857972e-04 -6.000000e+00 3.542790e-04 283.36 -2.00 20.00 -2.00 315.72 0.00e+00 2.038 0.000 302.00 328.00 3 2.2832e+00 4.9414e-03 2.3558e-02 -6.0000e+00 1.9752e-02 2.3293e-02 5.5471e-03 1.2366e-02 -6.0000e+00 2.1483e-02 4.5780e-03 3.2324e-03 6.0667e-03 -6.0000e+00 1.2816e-02 -6.3213e-03 1.5247e-03 1.7175e-03 -6.0000e+00 5.4379e-03 5.4785e-03 -4.8276e-04 1.0648e-04 1.9780e-05 -6.0000e+00 3.7264e-04 -4.8748e-04 -3.9746e-05 12 9 1 12 1 1 94.74 22.72 0.27 -0.00049 -0.00412 3 26 1 5 0 404.030 26.32 20.00 22.72 26.76 27.9 1021.83 -395 -1402 -4366 967 -4497 -2018 -4469 -1587 -992 -4458 -1498 -4727 -2022 1067 -497 500 -133 891 1689 1118 774 631 2215 1948 3416 -194 428 -555 -368 531 299 1156 652 508 -2920 -2842 -3875 -1953 -515 -285 -1291 -1128 -548 42 500 589 -187 -780 -1200 -929 1040 543 1989 708 1462 830 1391 360 588 95 1078 1160 2252 2675 873 498 -1228 -851 681 134 682 1068 805 953 121 -514 -1515 -2370 -294 -1520 -1598 -1738 -2323 -1259 -682 -1058 -540 527 690 200 458 28 -182 -617 -456 67 525 1158 -150 -434 -635 -1616 -942 -478 -938 -908 -607 -1029 316 673 1253 555 836 426 -260 -100 51 89 388 409 74 799 911 498 672 -234 59 1216 391 -75 -164 -349 -103 188 -766 -84 551 521 334 -224 -320 -961 -886 -63 -253 -770 171 -746 -299 -696 -267 -187 -934 -303 -980 -446 262 -129 143 -41 276 541 373 266 216 748 691 1263 -78 172 -214 -131 180 105 437 269 220 -1238 -1141 -1670 -874 -273 -164 -833 -764 -381 30 347 409 -129 -525 -791 -606 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