File name: Pandora183s1_LondonderryNH_20231028_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231102T092535.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231028_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231028T114916.2Z 8701.492548 275 1 49.98 2 84.87 113.22 100.16 295.77 0.00 1 0.00 1 0 25 6.397e-01 7.103e-02 5.503e-01 6.455e-02 8.166389e-01 3.750396e-02 9.590213e-03 -6.000000e+00 3.696120e-01 224.42 -2.00 3.55 -2.00 322.12 0.00e+00 1.569557e-02 1.605237e-02 2.866133e-03 -6.000000e+00 1.812017e-02 280.62 -2.00 20.00 -2.00 321.58 0.00e+00 9.635 0.017 302.00 328.00 3 -2.7476e-01 1.2937e-01 1.0773e-01 -6.0000e+00 9.1726e-01 1.7137e+00 1.5114e-01 5.7460e-02 -6.0000e+00 1.0062e+00 -1.8080e+00 9.6744e-02 2.1846e-02 -6.0000e+00 5.9170e-01 6.6817e-01 5.2225e-02 1.0695e-02 -6.0000e+00 2.5238e-01 1.9435e-05 -5.6266e-03 1.9023e-03 1.2566e-04 -6.0000e+00 1.8159e-02 6.7158e-04 -1.9124e-05 12 8 8 10 0 0 -29.59 22.78 1.19 0.00067 -0.04161 24 5 1 5 0 2082.150 26.41 20.00 22.78 20.15 27.9 981.90 900000 -11316 900000 900000 202068 900000 -79769 -5258 -29467 -87477 -53496 60933 900000 79176 -518 101658 900000 134046 2464 86303 -33748 900000 46024 149600 -29355 109020 241468 900000 900000 -65997 -40469 900000 166167 -83271 900000 103346 11957 2543 -35678 -4702 158951 23518 900000 193003 6779 -8723 80789 122465 165694 -18110 30821 900000 20706 225008 900000 28276 105618 61263 164587 -44147 41141 -25122 7032 36283 -15132 87622 -5864 900000 -14161 44555 -5078 16472 22110 -54707 26998 54249 10674 34258 28022 19776 -999 -12678 -13482 28226 -2728 8331 30115 43918 6025 33432 10230 -13718 30539 1075 -14636 102 5609 5047 -4727 4423 13412 -5409 2586 3176 -16042 -10278 3029 -21913 -1568 -6723 2564 4461 5461 1640 -4541 -4651 3834 8642 -1424 7025 -6335 -576 7930 6582 -2933 3561 -2008 -1081 6748 19 1559 676 -3273 -722 -1699 -2272 -179 5105 -1415 -832 1855 -3457 3035 900000 -1116 900000 900000 12682 900000 -8857 -330 -1849 -8446 -3357 3824 900000 4969 -35 6380 900000 8413 226 5416 -4073 900000 2888 9389 -2610 6842 15154 900000 900000 -6558 -3598 900000 10429 -16985 900000 6486 750 186 -4292 -467 9976 1968 900000 12113 674 -1004 5070 7686 10399 -2463 2740 900000 2599 14121 900000 3549 6629 5243 10329 -9571 3756 -4730 1083 4761 -3626 7499 -1238 900000 -3474 6864 -1420 3853 4793 -23721 4621 6190 1705 4300 4157 3836 -285 -4702 -5615 8213 -1136 3280 9966 13030 2612 10682 3852 -6105 8363 405 -7265 52 3200 3398 -3965 3507 9259 -4042 1579 1848 -11990 -7741 2108 -21129 -1368 -7096 2823 5294 6637 2049 -5803 -6305 4789 10793 -2091 9919 -10138 -832 10054 8220 -3902 4313 -2496 -1384 9190 31 2946 1404 -7539 -1735 -4435 -6317 -499 13681 -4050 -2277 4598 -8375 6552 SS 20231028T120054.4Z 8701.500630 278 1 49.49 2 82.93 115.30 101.95 297.88 0.00 1 0.00 1 0 25 5.335e-01 1.713e-02 3.544e-01 1.005e-02 7.050891e-01 5.523817e-03 8.653757e-03 -6.000000e+00 2.990064e-01 224.42 -2.00 3.55 -2.00 322.03 0.00e+00 1.033575e-02 3.213680e-03 5.372298e-03 -6.000000e+00 1.365871e-02 280.62 -2.00 20.00 -2.00 321.54 0.00e+00 7.463 0.008 302.00 328.00 3 -5.4046e-02 2.1335e-02 8.4912e-02 -6.0000e+00 7.3927e-01 4.6702e-01 3.0231e-02 4.4153e-02 -6.0000e+00 8.0608e-01 -5.8777e-01 3.0133e-02 2.7042e-02 -6.0000e+00 4.7949e-01 2.2228e-01 1.3828e-02 1.1685e-02 -6.0000e+00 2.0416e-01 1.9132e-04 -1.1988e-03 2.9357e-04 2.1267e-04 -6.0000e+00 1.4068e-02 -7.4188e-04 3.0215e-05 12 8 8 10 0 0 5.96 22.80 0.29 -0.00074 -0.00975 94 20 1 5 0 526.410 26.41 20.00 22.80 21.18 28.0 989.34 38265 -121101 -42605 -147451 14551 -211583 -196163 8167 -215277 900000 -174516 -146560 -134572 79121 215613 -46307 -53238 -82055 -35036 -66509 -65155 900000 -69992 -66623 -89294 118479 60622 58343 -63762 -30678 -45428 -54067 61334 -36600 1730 -24439 -25010 7768 22778 16381 153 -8821 9346 37916 37498 30094 33076 -27501 27470 13999 33913 5944 13178 15328 20853 14695 -702 20233 3342 5829 5049 15216 20606 11224 13976 10399 10648 2066 13304 8669 14434 11091 10236 13228 4733 1044 -228 3359 -5282 -5299 -3472 -504 4675 -1714 2563 -1161 883 1774 3713 2407 -4022 -2219 -5116 -1861 -4749 -2694 -3017 -615 93 -774 725 -4585 -1143 -2625 -2979 -2219 -1075 283 -1637 400 557 1053 -585 85 -1528 -1368 193 -44 2276 -292 2225 40 1244 1230 748 591 11 1285 3 1315 124 -333 37 -891 -105 -434 441 948 490 -330 29 -607 -1312 375 -1187 -418 -1890 143 -4148 -3254 80 -5275 900000 -2994 -2035 -2089 776 2113 -643 -913 -2078 -601 -1630 -1597 900000 -1715 -1633 -2845 1161 594 572 -1562 -629 -1295 -2072 874 -1533 48 -828 -891 228 690 628 8 -527 491 1554 1570 1394 1533 -2426 1469 911 1994 519 1174 1448 1970 1519 -86 2001 378 629 562 1681 2479 1700 2229 1705 1708 370 2324 1831 3203 2668 2463 2911 1033 232 -48 685 -1320 -1595 -1218 -180 1934 -803 1226 -616 484 996 2053 1307 -2180 -1105 -2522 -917 -2723 -1780 -2348 -543 90 -769 668 -4000 -872 -2023 -2482 -1953 -990 278 -1810 492 769 1552 -888 125 -2169 -1866 261 -63 3396 -467 3433 60 1796 1725 1018 780 15 1722 4 2309 245 -707 83 -2148 -269 -1180 1215 2647 1373 -894 74 -1453 -3067 SS 20231028T121157.9Z 8701.508310 281 1 49.69 2 81.11 117.31 103.62 299.93 0.00 1 0.00 1 0 25 4.181e-01 9.393e-03 1.773e-01 3.377e-03 6.057863e-01 1.792790e-03 7.329831e-03 -6.000000e+00 2.339620e-01 224.42 -2.00 3.55 -2.00 321.53 0.00e+00 5.819248e-03 9.300252e-04 3.985923e-03 -6.000000e+00 1.036745e-02 280.62 -2.00 20.00 -2.00 320.99 0.00e+00 6.125 0.004 302.00 328.00 3 -1.5233e-01 6.3635e-03 6.9959e-02 -6.0000e+00 5.7736e-01 1.2674e-01 9.0098e-03 3.8433e-02 -6.0000e+00 6.2920e-01 -1.7133e-01 9.3918e-03 2.3072e-02 -6.0000e+00 3.7540e-01 5.8064e-02 4.4036e-03 8.7073e-03 -6.0000e+00 1.5965e-01 8.6194e-04 -6.1113e-04 9.9188e-05 1.3531e-04 -6.0000e+00 1.1022e-02 -9.3630e-04 -4.5827e-06 12 8 8 10 0 0 14.62 22.79 0.36 -0.00094 -0.00553 222 46 1 5 0 223.760 26.41 20.00 22.79 22.65 28.1 1000.15 -9336 -150147 21184 -126696 -129035 -174905 -144932 -151161 -168179 -78382 -158245 -79175 -116633 -51345 -62621 -56217 -21431 -45984 -10823 -44689 22726 -49791 -21236 -59533 -23288 -27738 -35059 -12247 -42342 -4486 -17541 -10920 -9758 -5131 -11879 -19082 6263 -13646 3661 -9185 3857 3026 7574 4246 -2011 12704 82 3970 -587 -86 4094 1719 11667 2720 6187 -1951 5198 -38 -1800 5282 3716 9489 2903 7360 3589 4301 2549 1029 4596 1080 3128 412 2658 647 -51 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