File name: Pandora183s1_LondonderryNH_20231105_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231106T043412.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231105_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231105T130834.1Z 8709.547616 314 1 49.73 2 74.44 129.91 34.55 240.11 0.00 1 0.00 1 0 17 2.783e-01 1.361e-02 2.631e-01 1.031e-02 4.897617e-01 5.314519e-03 5.914133e-03 -6.000000e+00 1.552438e-01 223.69 -2.00 3.55 -2.00 320.79 0.00e+00 6.892847e-04 2.104464e-03 2.870755e-03 -6.000000e+00 7.005799e-03 279.61 -2.00 20.00 -2.00 320.18 0.00e+00 3.662 0.001 302.00 328.00 3 3.5871e+00 1.6781e-02 4.6419e-02 -6.0000e+00 3.8260e-01 4.6729e-02 2.1292e-02 3.2412e-02 -6.0000e+00 4.1756e-01 -4.5074e-02 1.9631e-02 1.4903e-02 -6.0000e+00 2.4915e-01 6.2514e-03 9.7869e-03 3.8731e-03 -6.0000e+00 1.0707e-01 2.2530e-04 -1.0042e-03 3.1387e-04 6.1012e-05 -6.0000e+00 7.4755e-03 3.8719e-04 -1.9517e-04 12 8 8 10 0 0 99.98 22.80 0.24 0.00039 -0.00716 107 22 1 5 0 464.710 26.41 20.00 22.80 15.98 27.5 956.29 900000 -63358 67010 900000 -108643 3422 -126602 91209 -127634 45106 -80370 -2058 -15792 -55796 -1979 3318 139127 -32235 -6689 14803 -24135 18216 -36128 44576 650 -1022 7221 -35392 -17724 -9465 28771 -117 26210 -3247 4644 -10669 -28815 12646 -4708 3001 -904 26266 -7097 8731 -7370 -1393 8193 -429 6331 4100 12773 -3757 8685 10050 2515 6871 -1636 136 -2179 -2555 -4792 2017 4764 787 3705 850 6831 -3602 6046 -1250 1213 2109 471 1420 -1877 1423 -1504 -2562 -954 -2425 999 -3062 -2079 -2085 57 -1491 -139 2780 1772 253 -1487 -203 -391 -789 -1002 -1614 1801 102 995 -2600 667 -2931 -1816 -2231 -1243 -1020 -2089 -570 -200 2593 1180 421 410 774 0 -347 1390 271 374 -790 -218 371 1025 1222 -18 193 -183 844 -127 -361 271 -1392 614 -747 64 -902 723 361 24 605 -806 276 -440 900000 -833 674 900000 -2185 34 -3035 917 -4047 453 -1803 -24 -251 -1636 -41 78 1399 -1296 -224 422 -1051 519 -1816 1083 27 -45 303 -2194 -876 -436 1012 -6 1252 -226 288 -742 -2583 959 -521 370 -131 3121 -1233 1325 -1320 -238 1281 -74 1036 712 2206 -848 1881 2315 660 1790 -479 39 -625 -722 -1415 603 1550 295 1412 320 2310 -1353 2227 -569 598 1082 245 698 -880 579 -576 -969 -384 -1150 530 -1912 -1400 -1483 42 -1205 -117 2343 1509 212 -1174 -146 -265 -537 -746 -1373 1688 110 1150 -3104 721 -2971 -1681 -2106 -1257 -1091 -2372 -675 -254 3529 1771 663 636 1250 0 -501 1975 407 599 -1343 -370 609 1615 1851 -26 271 -247 1162 -195 -616 496 -2708 1214 -1577 142 -2140 1726 882 59 1420 -1820 585 -918 SS 20231105T135713.1Z 8709.581401 343 1 20.30 2 68.16 140.34 42.65 252.44 0.00 1 0.00 1 0 17 4.918e-02 7.762e-03 3.384e-02 3.438e-03 3.625595e-01 1.696297e-03 4.413816e-03 -6.000000e+00 2.745992e-02 223.69 -2.00 3.55 -2.00 319.11 0.00e+00 2.068119e-03 4.114159e-04 9.056320e-04 -6.000000e+00 1.214764e-03 279.60 -2.00 20.00 -2.00 318.44 0.00e+00 2.664 0.000 302.00 328.00 3 3.3108e+00 4.6776e-03 3.2229e-02 -6.0000e+00 6.7679e-02 2.5790e-02 5.4355e-03 1.8823e-02 -6.0000e+00 7.3786e-02 -4.1621e-03 4.0337e-03 9.7973e-03 -6.0000e+00 4.4021e-02 -6.7378e-03 2.1313e-03 3.2487e-03 -6.0000e+00 1.8749e-02 8.8581e-04 -1.7309e-04 9.9718e-05 3.5840e-05 -6.0000e+00 1.2960e-03 -3.9706e-03 8.0935e-05 12 9 1 12 1 1 99.97 22.80 0.49 -0.00397 -0.00527 21 11 1 5 0 922.490 26.41 20.00 22.80 17.56 27.6 966.47 -6202 -4340 -15875 10193 -27856 -10447 4348 1110 -21774 -7874 -2609 -27273 1904 -11634 3010 -8212 3064 -2443 -2689 10827 3869 -4757 -4920 -834 -2247 -1296 -2185 -3996 -3282 -5951 -2448 -2458 -1765 -1540 -1354 -5640 -4969 1395 -1044 -2632 -48 -666 2086 -1448 2285 262 1462 -2662 477 624 160 1791 -493 506 613 1988 250 637 -452 1619 1264 1279 3330 3230 1217 550 -177 -304 1541 1003 748 475 557 335 349 123 -1242 -2510 79 -1589 -853 -1104 -1805 -2064 -802 -410 -407 355 1208 542 350 -48 -426 -872 -598 -536 296 868 -109 -351 -1128 -1092 -942 -525 -1475 -1099 -1230 -905 -27 674 1383 452 694 306 -282 -283 261 -370 388 406 168 598 933 409 421 -133 -71 818 195 -113 -128 -245 -237 -306 -27 -183 99 892 172 28 -351 -673 -427 -172 -138 -605 295 -1061 -309 114 33 -936 -319 -102 -1388 82 -691 184 -651 236 -211 -247 908 396 -528 -551 -95 -277 -166 -288 -517 -397 -730 -313 -353 -281 -262 -221 -913 -848 259 -240 -732 -15 -217 689 -507 774 91 503 -946 164 217 59 711 -215 233 294 964 127 321 -225 779 624 679 1914 2030 805 346 -105 -176 926 691 573 384 451 262 253 81 -745 -1455 47 -1094 -666 -967 -1565 -1883 -771 -421 -442 395 1341 586 352 -49 -402 -805 -587 -535 330 1078 -147 -473 -1436 -1267 -1014 -573 -1764 -1389 -1629 -1258 -39 1059 2312 719 1171 487 -417 -393 359 -535 596 661 278 969 1461 618 606 -184 -94 1081 282 -178 -215 -426 -424 -572 -50 -351 193 1768 345 55 -656 -1317 -813 SS 20231105T140125.8Z 8709.584326 346 1 2.91 2 67.67 141.30 43.39 253.36 0.00 1 0.00 1 0 17 2.576e-02 7.883e-03 1.189e-02 2.066e-03 3.574154e-01 1.019916e-03 4.306277e-03 -6.000000e+00 1.438112e-02 223.69 -2.00 3.55 -2.00 318.21 0.00e+00 1.398840e-03 1.905534e-04 5.387830e-04 -6.000000e+00 6.362220e-04 279.60 -2.00 20.00 -2.00 317.53 0.00e+00 2.610 0.000 302.00 328.00 3 1.1386e+00 2.7217e-03 3.1483e-02 -6.0000e+00 3.5444e-02 -4.3725e-03 3.0993e-03 1.8198e-02 -6.0000e+00 3.8644e-02 -5.0773e-03 2.0500e-03 9.1497e-03 -6.0000e+00 2.3055e-02 -1.9371e-03 1.0721e-03 2.7680e-03 -6.0000e+00 9.8183e-03 8.3887e-03 -2.6627e-04 5.8138e-05 2.8423e-05 -6.0000e+00 6.7879e-04 -3.8649e-03 5.4524e-05 12 9 1 12 1 1 97.78 22.80 0.27 -0.00386 -0.00587 19 71 1 5 0 144.990 26.41 20.00 22.80 17.79 27.7 968.94 -4901 -7350 -3876 -3379 -10160 -10475 -10152 -5245 -7118 -4000 -11769 -5023 -4404 -3504 1237 -2309 -529 -1406 1011 -1985 2153 -931 701 287 -393 1709 -1155 -1123 -3432 -1052 -1207 -91 2132 -295 -2100 -5953 -3393 -3260 -1013 -700 -1463 662 -120 -5 638 1426 356 126 -883 -365 654 795 1991 1108 1565 1125 823 -157 56 -27 524 2059 2155 2867 754 656 -110 -1227 1247 872 1027 828 352 765 254 -596 -859 -1790 -1368 -1326 -1357 -1500 -2019 -1612 -927 -601 -54 433 1161 773 586 41 -948 -622 -740 -359 529 904 -441 -363 -718 -1424 -885 -330 -1123 -1489 -564 -859 -2 606 1116 814 470 190 -385 28 398 106 486 299 427 590 1136 424 686 -179 -166 885 75 79 -449 -323 -335 13 -10 -100 326 661 115 -224 -12 -905 -722 -235 -419 -228 -195 -563 -538 -536 -295 -463 -274 -885 -359 -355 -334 134 -298 -73 -206 153 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