File name: Pandora183s1_LondonderryNH_20231106_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231107T043407.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231106_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231106T121044.6Z 8710.507460 284 1 49.96 2 83.41 119.05 26.94 194.24 0.00 1 0.00 1 0 17 6.279e-01 3.700e-02 4.889e-01 2.802e-02 8.127866e-01 1.597263e-02 9.499302e-03 -6.000000e+00 3.598023e-01 223.60 -2.00 3.55 -2.00 322.25 0.00e+00 9.249894e-03 9.151001e-03 6.413791e-03 -6.000000e+00 1.819624e-02 279.48 -2.00 20.00 -2.00 321.80 0.00e+00 7.916 0.009 302.00 328.00 3 5.7510e-01 6.2862e-02 9.4098e-02 -6.0000e+00 8.9747e-01 1.1712e+00 7.7978e-02 5.4772e-02 -6.0000e+00 9.8582e-01 -1.4912e+00 6.1087e-02 2.7112e-02 -6.0000e+00 5.7275e-01 5.8778e-01 2.9911e-02 8.2940e-03 -6.0000e+00 2.4492e-01 5.1660e-05 -2.0711e-03 8.2044e-04 2.0504e-04 -6.0000e+00 1.7803e-02 -1.2546e-03 7.1488e-05 12 8 8 10 0 0 99.57 22.72 0.64 -0.00125 -0.01682 47 10 1 5 0 1062.760 26.32 20.00 22.72 6.44 26.5 887.43 900000 100388 900000 94619 900000 39409 -156530 900000 900000 900000 900000 -54685 -57774 -39558 -5051 103472 43855 3082 -8782 298862 45902 216108 -82703 -27031 -72718 205456 22465 900000 17539 3275 900000 45483 -9917 900000 239210 68150 27527 59387 66084 97119 -24998 37237 64051 214845 11621 172046 103164 82716 1474 52655 80946 16263 900000 38631 34553 73804 44295 44408 44586 45725 4708 93086 -536 40471 65897 33104 5251 12155 30088 13418 30063 42572 15251 -1142 12129 52303 24815 11869 -15609 -25743 -5578 -6823 11436 -5255 4900 -5732 5280 -7898 -5990 3306 -17823 -2090 1413 -1076 5223 -13062 -4650 726 -1511 1612 -19 -4594 2406 -7507 -646 -3090 -2458 4853 87 6064 -1958 2903 84 -63 -6318 -827 1838 -990 1405 104 1808 4123 3031 -1724 1277 912 394 -2007 -228 1585 597 941 -328 -655 -1534 -1673 982 2544 1816 -59 -427 -1920 -1865 900000 2738 900000 2580 900000 1075 -12806 900000 900000 900000 900000 -1491 -1939 -1411 -159 2822 1196 133 -439 8150 1252 5894 -6954 -1290 -5454 5603 613 900000 478 97 900000 1240 -541 900000 6524 1859 938 1620 1952 2649 -2329 2123 2858 5859 864 4692 3069 3076 128 2872 3612 1532 900000 3352 3255 4757 3844 3743 3537 3401 525 4616 -77 4415 6045 4186 859 1899 4252 2562 5366 6966 3214 -263 2195 5576 3199 1766 -3444 -7595 -1604 -2301 3572 -2059 1835 -2530 2186 -3838 -2851 1385 -8616 -808 511 -416 2162 -7707 -2986 517 -1229 1298 -17 -3658 1594 -5384 -463 -2418 -2025 4023 85 6383 -2548 3919 120 -88 -9080 -1087 2375 -1385 2038 159 2672 5678 4050 -2350 1637 1139 481 -2654 -343 2719 1158 1974 -742 -1591 -4041 -4649 2710 7000 5007 -157 -1067 -4514 -4206 SS 20231106T122120.2Z 8710.514817 287 1 49.75 2 81.73 120.98 27.53 199.54 0.00 1 0.00 1 0 17 5.490e-01 1.336e-02 3.261e-01 6.000e-03 7.258604e-01 3.276462e-03 8.365849e-03 -6.000000e+00 3.062793e-01 223.60 -2.00 3.55 -2.00 321.95 0.00e+00 8.589012e-03 1.875333e-03 2.757024e-03 -6.000000e+00 1.354949e-02 279.48 -2.00 20.00 -2.00 321.47 0.00e+00 6.527 0.005 302.00 328.00 3 1.2218e-01 1.2443e-02 7.5472e-02 -6.0000e+00 7.5474e-01 3.3599e-01 1.8591e-02 4.1293e-02 -6.0000e+00 8.2307e-01 -4.4371e-01 1.9721e-02 2.5399e-02 -6.0000e+00 4.9104e-01 1.6543e-01 8.9745e-03 1.2011e-02 -6.0000e+00 2.0903e-01 3.7973e-04 -9.3202e-04 1.7166e-04 1.7028e-04 -6.0000e+00 1.4467e-02 -1.3722e-03 4.0725e-05 12 8 8 10 0 0 98.78 22.72 0.32 -0.00137 -0.00838 142 29 1 5 0 350.250 26.32 20.00 22.72 7.18 26.7 894.31 -231150 -81375 -172126 -176066 -231008 -42109 -179927 -33940 -253206 32378 35100 -204986 -99766 -151062 40117 -86343 64315 -56730 -12049 -6974 5281 26719 -66416 123361 -63419 55255 -12169 12321 -36055 -63165 -24606 -33066 19930 -9089 9703 -34288 875 -4371 -11855 22571 -10392 -4564 14050 12352 157 7808 39201 -873 23863 397 15454 16513 21529 19337 8930 12918 2972 4279 7075 6064 11413 6592 8656 9122 10733 2865 12388 -623 11339 6608 4166 9635 7734 4292 1775 89 -9144 -3835 -2880 -5263 1029 -1347 -1207 -1545 1208 -565 750 1132 712 2332 -1175 305 -2874 -728 -3846 -2137 -3 259 -105 -1034 -564 -2348 -958 -2310 -2311 -1347 -1673 -232 41 696 118 1069 196 -352 -956 -790 26 -662 298 491 588 869 1387 816 303 584 -127 1053 74 552 113 -259 -159 -181 -603 -204 679 1049 50 112 -294 -587 -1099 -3017 -476 -1704 -1823 -4055 -246 -1755 -199 -6050 189 205 -3598 -778 -2652 235 -1305 376 -830 -123 -71 49 195 -1231 722 -1268 382 -168 131 -614 -1512 -484 -879 371 -251 217 -1131 21 -130 -460 744 -542 -243 658 611 9 424 1606 -56 1257 28 1052 1256 1718 1718 936 1347 351 496 772 652 1190 792 1174 1417 1781 512 1983 -117 2276 1462 1053 2661 2158 1168 451 21 -2146 -866 -726 -1638 358 -554 -550 -751 609 -309 426 662 419 1307 -638 153 -1433 -368 -2271 -1459 -2 235 -106 -1067 -544 -2066 -750 -1821 -1959 -1202 -1584 -233 46 873 167 1613 302 -532 -1382 -1097 36 -973 461 788 930 1314 2008 1152 415 772 -164 1417 115 981 224 -552 -358 -435 -1563 -554 1868 2922 139 300 -740 -1391 -2534 SS 20231106T123829.7Z 8710.526732 292 1 49.71 2 79.08 124.18 28.82 207.66 0.00 1 0.00 1 0 17 3.481e-01 6.991e-03 8.013e-02 1.816e-03 5.897990e-01 9.415797e-04 6.888216e-03 -6.000000e+00 1.942266e-01 223.60 -2.00 3.55 -2.00 321.14 0.00e+00 2.853005e-03 4.408778e-04 2.758846e-03 -6.000000e+00 8.592506e-03 279.48 -2.00 20.00 -2.00 320.61 0.00e+00 5.088 0.002 302.00 328.00 3 -3.6535e-02 3.1265e-03 5.9777e-02 -6.0000e+00 4.7862e-01 4.6658e-02 4.3093e-03 3.4773e-02 -6.0000e+00 5.2196e-01 -5.4448e-02 4.4972e-03 1.9220e-02 -6.0000e+00 3.1140e-01 7.5863e-03 2.1639e-03 6.2934e-03 -6.0000e+00 1.3255e-01 2.0357e-03 -5.9390e-04 5.1871e-05 9.0968e-05 -6.0000e+00 9.1754e-03 -1.6018e-03 1.4113e-05 11 8 0 10 0 0 99.43 22.70 0.31 -0.00160 -0.00606 323 67 1 5 0 153.880 26.32 20.00 22.70 9.63 27.0 911.33 -110645 -128365 -126607 -108632 -106390 -104896 -136902 -100177 -116527 -80177 -81117 -80496 -91252 -57777 -50290 -39147 -42244 -37237 -11155 -22542 -14783 -24568 -20317 -29746 -6974 -12078 -22257 -24647 -19439 -9444 -11132 -8029 -3253 1670 -9435 -7797 -8189 -8183 941 -4769 -976 -239 1596 2561 1433 221 777 -177 -763 2988 2613 1407 3654 3268 2425 1848 3067 888 4 -2219 77 1886 2847 4644 2965 1834 234 -119 1360 1414 2088 1456 1339 597 144 -1566 -1853 -3098 -2116 -1480 -1141 -984 -1994 -1117 -841 -124 631 673 1655 958 671 -300 -1446 -1013 -995 -709 353 936 214 -6 -805 -1403 -830 -682 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