File name: Pandora183s1_LondonderryNH_20231113_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231114T043818.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231113_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231113T121037.2Z 8717.507375 54 1 49.59 2 85.00 120.24 88.41 121.52 0.00 1 0.00 1 0 25 5.817e-01 7.314e-02 4.915e-01 7.679e-02 1.148422e+00 4.499540e-02 1.407665e-02 -6.000000e+00 3.321256e-01 222.97 -2.00 3.55 -2.00 321.67 0.00e+00 -1.670247e-02 1.084407e-02 1.031415e-03 -6.000000e+00 1.507506e-02 278.60 -2.00 20.00 -2.00 321.03 0.00e+00 9.835 0.018 302.00 328.00 3 -1.0680e+00 1.3318e-01 1.1353e-01 -6.0000e+00 8.1965e-01 2.8946e+00 1.5445e-01 6.0901e-02 -6.0000e+00 8.9866e-01 -2.5159e+00 8.8213e-02 2.8280e-02 -6.0000e+00 5.2871e-01 7.5262e-01 4.9692e-02 1.3840e-02 -6.0000e+00 2.2420e-01 1.7874e-05 -3.9561e-03 1.8538e-03 2.0362e-04 -6.0000e+00 1.6518e-02 -1.1214e-03 5.6533e-05 12 8 8 10 0 0 -2.55 22.70 1.14 -0.00112 -0.03085 26 5 1 5 0 1906.930 26.32 20.00 22.70 1.60 26.0 855.71 900000 107742 10700 -19725 -10289 900000 -19892 900000 73031 237844 -15761 195741 -32728 -14893 10221 19304 19224 77261 15333 -9321 188279 -50026 197199 244614 52802 42978 -53272 900000 900000 900000 -44678 900000 40361 26712 900000 -39635 12599 41878 -48641 48953 54351 47018 54458 58073 10402 65883 24715 -19952 -9733 42173 44191 -44450 9801 20099 87498 65715 23037 43333 42221 87963 -40876 -299 1258 -26560 34878 -27632 117392 47522 -50330 -13810 174063 -2893 50349 47148 -29270 175592 54905 43508 55357 7547 -27548 7627 1537 2208 11385 28246 45865 -11735 11727 44352 12301 31699 -25620 11655 -400 4248 -6 1965 8739 10362 -3032 10268 17669 -17931 -4857 -12686 3689 2888 -3675 7968 979 609 -2436 881 -5656 2138 8009 1317 -1747 -5060 7394 2511 -5961 2721 6037 -5801 -13057 -3198 878 3665 3029 1768 -1970 2783 -2048 -2216 959 -171 -1807 -1457 3643 -253 3718 900000 8056 1829 -3898 -1429 900000 -2517 900000 5460 17784 -2266 14635 -6023 -2570 1528 2887 2985 6665 2381 -1715 14078 -10934 14744 18290 4935 4552 -13941 900000 900000 900000 -7516 900000 3772 2996 900000 -6915 1256 3392 -11517 5185 6096 5859 6108 5789 1491 4926 2618 -3232 -1455 3942 4406 -11909 1649 3256 8326 8040 4384 6480 5740 6577 -10002 -49 222 -7041 5453 -8076 8777 6783 -20868 -4506 13015 -944 9240 8012 -9152 13129 5598 5028 6397 1693 -10486 2385 575 871 4256 9216 12782 -5823 4464 11456 4013 7972 -11319 3803 -171 2079 -4 1362 6356 7606 -2391 6212 8527 -11579 -2872 -8537 2207 1885 -2897 6608 1024 720 -3146 1114 -7458 2781 9821 1792 -2560 -7794 9619 3173 -7711 3134 6545 -6897 -16304 -3873 1221 5974 5752 3793 -4787 7034 -5896 -6759 2883 -523 -5553 -4216 9126 -598 7979 SS 20231113T122211.1Z 8717.515406 57 1 49.72 2 83.19 122.32 86.71 123.51 0.00 1 0.00 1 0 25 5.163e-01 1.778e-02 4.174e-01 1.305e-02 9.079449e-01 7.449483e-03 9.827341e-03 -6.000000e+00 2.886839e-01 222.97 -2.00 3.55 -2.00 322.45 0.00e+00 4.735225e-03 4.620056e-03 1.592363e-03 -6.000000e+00 1.323220e-02 278.60 -2.00 20.00 -2.00 322.03 0.00e+00 7.712 0.009 302.00 328.00 3 -1.8388e-01 3.0767e-02 9.1571e-02 -6.0000e+00 7.0965e-01 9.6490e-01 4.3695e-02 5.4057e-02 -6.0000e+00 7.7441e-01 -1.3591e+00 4.1609e-02 2.8531e-02 -6.0000e+00 4.6120e-01 5.4237e-01 1.8964e-02 1.0056e-02 -6.0000e+00 1.9664e-01 1.3559e-04 -1.3639e-03 3.6534e-04 1.3941e-04 -6.0000e+00 1.3636e-02 -1.8791e-03 6.7658e-06 12 8 8 10 0 0 -39.30 22.68 0.39 -0.00188 -0.01213 94 20 1 5 0 528.750 26.32 20.01 22.68 2.51 26.0 863.81 -132099 -108217 125538 -75644 10152 900000 -187756 -153819 -153904 22969 -110244 -128820 900000 -51959 -101363 -9970 45693 8668 167089 207427 24931 900000 -37341 -38762 -86168 6310 -49741 53641 -53513 -39856 47595 -44621 -25657 51895 68844 -49414 33631 875 -3396 67548 63427 51806 7786 10683 8896 28386 181571 1163 44894 39327 26259 53054 67844 30642 31044 41217 1080 10588 25985 -2401 2488 39998 33280 26962 31185 12115 17117 21516 21336 13709 15925 14479 13705 16555 8204 8616 -6287 5485 9322 6627 -4938 1641 2771 269 1281 7046 3758 5469 3807 -832 -4447 -3675 -9475 -3523 -4617 -434 -2237 -1261 -23 -1913 -2791 -3509 812 -4408 -2508 -3851 -1430 -1775 -2321 -1220 -106 179 57 563 -751 3 -674 -642 261 -49 1322 2041 1159 1451 1736 -202 1791 661 594 962 992 607 -717 -592 176 -353 191 482 72 544 -581 -738 -1138 -2844 -2118 1597 -1036 129 900000 -5513 -3312 -3464 292 -1753 -2595 900000 -771 -3117 -148 581 129 2126 2639 317 900000 -792 -863 -3198 94 -1266 682 -1248 -845 606 -1467 -816 900 956 -2058 622 25 -122 1406 1541 1498 360 482 401 1051 2310 59 1558 1547 1306 2271 2747 1949 2083 2574 102 894 1773 -206 201 2406 2464 2464 2994 1415 1901 2389 2616 2093 2634 2529 2362 2566 1234 1136 -984 789 1483 1324 -1211 440 906 96 481 2645 1525 2241 1579 -348 -1805 -1398 -3761 -1403 -2156 -233 -1457 -956 -19 -1670 -2315 -2607 513 -2877 -1720 -2847 -1095 -1486 -2206 -1336 -132 245 81 787 -1027 3 -907 -909 387 -76 1950 2828 1552 1887 2186 -252 2147 859 907 1717 1999 1340 -1718 -1528 485 -1028 565 1432 212 1520 -1513 -1775 -2639 SS 20231113T123313.7Z 8717.523075 60 1 49.64 2 81.50 124.35 85.12 125.44 0.00 1 0.00 1 0 17 6.942e-01 1.303e-02 2.176e-01 4.404e-03 8.076469e-01 2.442048e-03 9.055196e-03 -6.000000e+00 3.864753e-01 222.97 -2.00 3.55 -2.00 322.10 0.00e+00 7.043119e-03 1.442990e-03 2.702305e-03 -6.000000e+00 1.784828e-02 278.60 -2.00 20.00 -2.00 321.65 0.00e+00 6.377 0.005 302.00 328.00 3 -2.5986e-01 9.4470e-03 7.6954e-02 -6.0000e+00 9.5119e-01 3.6852e-01 1.4633e-02 4.6496e-02 -6.0000e+00 1.0380e+00 -5.1416e-01 1.6078e-02 2.7303e-02 -6.0000e+00 6.1926e-01 1.9658e-01 7.2477e-03 1.1190e-02 -6.0000e+00 2.6436e-01 5.8724e-04 -1.0207e-03 1.2271e-04 1.6644e-04 -6.0000e+00 1.8345e-02 -2.1008e-03 1.4540e-05 12 8 8 10 0 0 -10.64 22.68 0.34 -0.00210 -0.00977 214 44 1 5 0 231.920 26.32 20.00 22.68 3.68 26.1 872.04 -263294 -172570 -196425 -203889 -201760 -205498 -266141 -204355 -243166 -89392 -226934 900000 -167447 -140086 -89457 -119757 -93439 -81635 -29034 -112271 -26127 -53139 -84642 -49427 -102624 -6549 -73825 16939 -109042 -22540 -57053 -39576 13104 -23697 -6759 -15515 -20746 -27000 1076 11385 15790 37197 2017 45158 20995 19431 15973 8376 6001 21956 21501 17287 29620 11459 18677 16070 13556 15215 1271 13637 3389 14007 8894 10246 10471 10160 7917 3943 6088 5403 9636 7994 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