File name: Pandora183s1_LondonderryNH_20231116_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231117T064915.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231116_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231116T122532.2Z 8720.517734 58 1 50.25 2 83.34 123.35 118.57 103.99 0.00 1 0.00 1 0 17 6.889e-01 3.230e-02 4.736e-01 2.563e-02 9.107537e-01 1.476763e-02 1.041360e-02 -6.000000e+00 3.921358e-01 222.77 -2.00 3.55 -2.00 322.41 0.00e+00 -5.100363e-03 8.590909e-03 7.438564e-03 -6.000000e+00 2.010759e-02 278.24 -2.00 20.00 -2.00 321.98 0.00e+00 7.853 0.009 302.00 328.00 3 5.4731e-01 5.8307e-02 9.8698e-02 -6.0000e+00 9.6458e-01 1.2945e+00 7.0310e-02 6.4273e-02 -6.0000e+00 1.0590e+00 -1.7798e+00 5.1373e-02 2.8873e-02 -6.0000e+00 6.2855e-01 7.0595e-01 2.6056e-02 7.9199e-03 -6.0000e+00 2.6434e-01 5.4572e-05 -2.1148e-03 7.2884e-04 2.0334e-04 -6.0000e+00 1.8684e-02 -1.4048e-03 -1.5026e-05 12 8 8 10 0 0 30.95 22.68 0.69 -0.00140 -0.01730 43 9 1 5 0 1168.320 26.32 19.99 22.68 7.16 26.7 899.83 -84904 128008 -13057 900000 92377 16015 121813 -93336 -71629 105585 900000 -40631 -44261 15628 79913 -25422 12342 900000 -8201 306006 -40172 60323 -8430 -45700 900000 900000 900000 43998 51747 -30820 -18970 102334 170686 900000 -17588 103454 -31118 -8212 -49199 124015 114919 95252 900000 34484 350864 -8577 -16218 19575 -27475 284686 4766 69407 125748 60026 45639 219547 87139 34616 27487 24748 85045 26357 97215 46317 -16167 44070 -3603 51838 17279 41378 20885 43543 -808 15922 5497 8166 47718 -23389 18945 3049 6738 19156 -4148 8870 -8545 6368 3750 14311 -3355 4416 3314 6521 -8568 -6959 -1398 -2569 -8223 -4590 -1210 1657 -3781 903 -284 -1646 -3939 -1951 -1890 -8821 -789 1887 421 -1175 2239 -590 -3267 -2304 -365 -92 979 -897 -2615 4809 3718 642 3745 2038 489 1032 3154 -398 390 76 -225 546 461 351 -1302 1135 -255 2096 220 -3208 -1720 -6357 3195 -501 900000 2305 400 3040 -4838 -3163 2635 900000 -1326 -1699 390 1994 -1375 488 900000 -409 7637 -2506 1505 -333 -2756 900000 900000 900000 1098 1291 -1282 -789 2554 4260 900000 -951 2582 -1747 -410 -4400 3095 2868 3026 900000 1956 8756 -681 -1361 1155 -2680 7105 389 3307 3709 3677 3417 5479 4547 2984 2370 2021 3666 2153 4411 3993 -2824 4199 -548 4704 2431 5257 3601 6224 -176 2709 923 1167 4222 -4298 2579 588 1498 4390 -1346 2697 -3276 2225 1404 4935 -1370 1603 1249 2246 -3379 -2866 -628 -1391 -5582 -3517 -1002 1365 -3104 631 -179 -1027 -2693 -1392 -1429 -7771 -723 1959 512 -1599 3056 -824 -4534 -3070 -482 -127 1416 -1366 -3955 6397 4788 832 4570 2462 586 1311 4597 -704 773 166 -525 1367 1244 999 -3834 3295 -742 5660 557 -7749 -3918 SS 20231116T123638.9Z 8720.525450 61 1 49.60 2 81.66 125.39 116.69 105.55 0.00 1 0.00 1 0 17 5.825e-01 1.504e-02 2.996e-01 7.242e-03 8.051248e-01 4.005375e-03 9.061919e-03 -6.000000e+00 3.258131e-01 222.77 -2.00 3.55 -2.00 322.12 0.00e+00 8.977657e-03 2.341311e-03 2.046607e-03 -6.000000e+00 1.430964e-02 278.24 -2.00 20.00 -2.00 321.67 0.00e+00 6.482 0.005 302.00 328.00 3 3.5469e-01 1.5401e-02 7.7404e-02 -6.0000e+00 8.0256e-01 5.1399e-01 2.2803e-02 4.5978e-02 -6.0000e+00 8.7699e-01 -7.1318e-01 2.3874e-02 2.5859e-02 -6.0000e+00 5.2299e-01 2.7987e-01 1.0853e-02 1.1988e-02 -6.0000e+00 2.2165e-01 2.8106e-04 -1.0886e-03 2.0152e-04 1.7285e-04 -6.0000e+00 1.5382e-02 -1.6452e-03 -2.1253e-05 12 8 8 10 0 0 9.22 22.67 0.45 -0.00165 -0.00983 112 23 1 5 0 442.750 26.32 20.00 22.67 8.33 26.8 909.00 -207652 -195597 -140479 -219607 -119106 -120737 -195539 -71272 -225306 -178785 -168093 75321 -174134 -122453 -67520 -72826 900000 -96943 -12038 -35893 15677 -88804 -36690 -78403 -56927 -41020 -24952 110904 -80670 6561 -30846 -38014 -13395 1784 9499 -33048 -10951 180 3060 20497 41266 10270 1373 21636 9550 14633 32920 19557 15132 11845 19320 6872 20016 25036 20584 19311 21349 11800 10955 14697 14157 6789 13619 17478 13372 9998 11074 9170 18614 10443 9057 7723 8504 2537 26 -2727 -2111 -2090 -2310 3697 -2668 1644 -1544 -804 3805 -1533 1800 3358 2554 2194 2088 -3261 -4814 -1862 -2939 -3216 -855 -609 -1096 114 -1330 -2936 -1566 -2430 -2957 -2739 -2880 -778 -1012 341 367 644 -104 396 -1264 -558 -121 -863 -201 338 1804 1075 1803 1134 1238 -212 181 1469 189 1061 107 34 173 -102 -460 -200 578 521 89 -226 50 -767 -1165 -2820 -2869 -1297 -4414 -841 -853 -2646 -503 -4640 -2420 -2077 532 -3177 -1801 -755 -1071 900000 -2339 -135 -528 138 -2143 -518 -1753 -1072 -676 -384 783 -2071 76 -634 -1049 -344 44 207 -1040 -288 5 96 645 1192 435 67 889 448 667 1289 916 787 684 1153 525 1478 1913 1744 1711 1891 1136 1020 1274 1254 710 1539 2199 1914 1483 1614 1413 2868 2018 1971 1780 1916 567 6 -566 -406 -412 -520 953 -876 600 -648 -356 1709 -772 920 1741 1333 1109 988 -1529 -2230 -878 -1604 -2089 -641 -532 -1068 112 -1239 -2476 -1166 -1800 -2362 -2317 -2583 -739 -1076 411 502 951 -157 586 -1819 -769 -168 -1267 -311 537 2769 1581 2526 1553 1637 -275 228 1942 294 1887 214 74 397 -252 -1223 -558 1629 1488 254 -616 127 -1812 -2667 SS 20231116T125431.8Z 8720.537868 67 1 49.66 2 79.05 128.77 113.71 108.06 0.00 1 0.00 1 0 17 5.260e-01 8.291e-03 1.054e-01 2.156e-03 6.678720e-01 1.134078e-03 7.766580e-03 -6.000000e+00 2.925333e-01 222.77 -2.00 3.55 -2.00 321.44 0.00e+00 4.182548e-03 5.717672e-04 3.233820e-03 -6.000000e+00 1.291522e-02 278.24 -2.00 20.00 -2.00 320.94 0.00e+00 5.075 0.002 302.00 328.00 3 1.3020e-01 3.9035e-03 6.2362e-02 -6.0000e+00 7.1986e-01 8.4100e-02 5.6387e-03 3.9585e-02 -6.0000e+00 7.8564e-01 -1.2097e-01 6.1322e-03 2.2952e-02 -6.0000e+00 4.6865e-01 3.6049e-02 2.8867e-03 8.1342e-03 -6.0000e+00 1.9964e-01 1.5844e-03 -6.7181e-04 6.0427e-05 1.2288e-04 -6.0000e+00 1.3859e-02 -2.5332e-03 1.1841e-05 11 8 0 10 0 0 15.15 22.66 0.33 -0.00253 -0.00758 306 64 1 5 0 162.250 26.32 20.01 22.66 11.11 27.4 930.40 -226537 -184441 -152175 -180873 -101048 -171286 -179823 -181440 -156558 -140331 -125907 -123515 -140349 -72552 -81530 -7484 -58936 -44719 -34860 -35133 -9424 -52144 -40938 -50476 -3585 -33335 -25851 -28208 -50254 -21462 -39739 -6035 -15153 -3505 -13262 -4295 -8929 -4794 -8151 -2953 980 1034 4136 3602 4214 6096 1597 3897 1475 241 6521 4220 6063 3834 5694 3032 5199 -891 1744 -832 762 4185 3074 6670 2638 4547 1593 1592 3298 1998 2635 1229 1692 479 195 -1491 -2002 -4460 -2993 -1385 -2252 -410 -1900 -1128 -276 -32 437 811 1607 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