File name: Pandora183s1_LondonderryNH_20231124_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20231125T044050.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231124_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231124T123621.0Z 8728.525243 200 1 22.99 2 83.39 126.14 124.18 333.05 0.00 1 0.00 1 0 17 5.557e-01 3.795e-02 4.569e-01 3.178e-02 8.515241e-01 1.884719e-02 1.051271e-02 -6.000000e+00 3.242958e-01 222.67 -2.00 3.55 -2.00 322.24 0.00e+00 1.058373e-02 1.030201e-02 8.337588e-03 -6.000000e+00 1.671779e-02 277.34 -2.00 20.00 -2.00 321.80 0.00e+00 7.901 0.009 302.00 328.00 3 6.3490e-01 7.0051e-02 9.6426e-02 -6.0000e+00 8.0615e-01 1.1748e+00 9.0098e-02 5.9598e-02 -6.0000e+00 8.9051e-01 -1.4126e+00 7.6890e-02 3.2123e-02 -6.0000e+00 5.1715e-01 5.4326e-01 3.7489e-02 1.1324e-02 -6.0000e+00 2.1795e-01 4.5744e-05 -8.7447e-04 9.2776e-04 2.5326e-04 -6.0000e+00 1.6097e-02 -2.0100e-03 7.1056e-05 12 9 9 12 1 1 98.93 22.64 0.66 -0.00201 -0.00858 13 6 1 5 0 1641.760 26.21 20.00 22.64 10.53 27.2 927.99 900000 -87354 -14879 -8659 900000 900000 900000 -97954 32256 900000 -157958 900000 900000 900000 17258 900000 102615 -23026 900000 -67177 -24344 76844 900000 -109025 900000 -60332 -38598 219030 900000 900000 900000 -13267 -36723 900000 900000 900000 900000 -29622 -23647 900000 313820 54647 101639 -36171 7474 126621 143301 54645 35478 22067 1334 115476 10665 20362 74617 66416 26023 39414 146905 -2215 67244 11402 27875 14510 12430 6284 16816 30897 11363 34088 49573 36102 26890 44506 33072 31259 50028 9074 -23845 14685 18541 17675 1071 7681 -10319 788 3048 2813 5782 1251 2263 -989 8945 -21840 -8415 -2917 -5465 2567 -7761 -2333 3177 -3839 -5102 -3243 -8442 -7369 834 -6435 2007 -833 -70 1862 -3417 1374 -827 4825 -3943 5206 -1929 1644 3017 1860 1633 1271 2422 2076 -3415 4952 -224 3864 -230 1915 -1942 532 -1030 -865 989 612 791 -1541 756 -3135 615 900000 -3318 -459 -267 900000 900000 900000 -3023 995 900000 -7125 900000 900000 900000 533 900000 3167 -888 900000 -4146 -939 2372 900000 -8412 900000 -2793 -1390 6760 900000 900000 900000 -512 -2078 900000 900000 900000 900000 -1745 -1526 900000 9685 2146 3137 -3653 482 3908 4423 2300 1891 1424 116 3564 1017 1885 4187 4099 2409 3096 4534 -236 3585 1152 2737 1873 1779 952 2265 3727 1817 4973 6815 5875 4677 5994 4454 3771 5095 1298 -5419 3037 4005 4463 354 2773 -4285 309 1223 1276 2534 552 922 -391 3120 -10919 -4233 -1657 -3778 1917 -7162 -2073 2510 -2891 -3464 -2122 -6227 -5708 630 -5680 1827 -902 -86 2443 -4850 1832 -1083 5778 -5220 6620 -2792 2369 4189 2480 2091 1588 2900 2422 -4111 5853 -325 6273 -437 3859 -4340 1244 -2628 -2315 2643 1661 2125 -4022 1785 -7122 1293 SS 20231124T124727.3Z 8728.532955 203 1 49.66 2 81.77 128.19 124.97 336.09 0.00 1 0.00 1 0 17 5.636e-01 1.487e-02 2.104e-01 5.274e-03 7.451100e-01 2.889067e-03 8.742193e-03 -6.000000e+00 3.133659e-01 222.67 -2.00 3.55 -2.00 321.98 0.00e+00 1.023733e-02 1.613196e-03 3.396123e-03 -6.000000e+00 1.383119e-02 277.34 -2.00 20.00 -2.00 321.51 0.00e+00 6.557 0.005 302.00 328.00 3 -1.0646e-01 1.0735e-02 7.6271e-02 -6.0000e+00 7.7118e-01 4.3916e-01 1.5580e-02 4.1876e-02 -6.0000e+00 8.4229e-01 -5.9237e-01 1.6405e-02 2.5872e-02 -6.0000e+00 5.0190e-01 2.3334e-01 7.5520e-03 1.2850e-02 -6.0000e+00 2.1513e-01 4.4566e-04 -1.2444e-03 1.5162e-04 1.9930e-04 -6.0000e+00 1.4980e-02 -2.4216e-03 -6.0785e-07 12 8 8 10 0 0 52.80 22.63 0.40 -0.00242 -0.01177 163 34 1 5 0 304.620 26.21 19.99 22.63 11.55 27.2 934.87 900000 -229723 -139921 -211602 -151732 -212215 -190028 -175755 -199277 -110088 -169396 -137997 -179278 22339 -67116 -44913 -45942 -65554 -20957 -25736 67098 -25002 -23593 20566 -42673 -25172 -26837 5167 -67442 -23345 -62322 12549 13584 30407 -16188 -4438 3462 -7225 8018 23903 10805 31828 21587 30587 11469 37168 -1272 20788 22758 15075 25271 22025 25959 16018 26351 8034 15229 10734 3612 8687 8148 15300 9281 12449 9294 5679 6431 4404 13535 2086 12750 4161 9368 3281 4500 -2693 -1853 -2337 -4900 2225 -1692 948 -1210 -1409 -342 -387 829 1350 2130 783 100 -1756 -1840 -2631 -3826 -2059 -2599 367 -1299 -199 -984 -1446 -1913 -2533 -1873 -2632 -1125 -1861 -349 636 -57 155 101 -393 -1394 -695 -156 409 933 386 1548 1866 1711 596 896 -226 43 1024 110 720 205 297 -509 157 -282 -48 144 372 109 57 157 -1199 -758 900000 -5270 -1439 -4436 -1690 -3910 -2768 -2335 -3586 -849 -2395 -1537 -3841 115 -834 -558 -669 -1292 -287 -386 403 -364 -334 212 -858 -435 -477 65 -1734 -415 -1981 235 298 625 -515 -118 89 -236 270 816 475 1220 969 1301 600 1546 -80 1098 1245 951 1595 1616 2014 1490 2340 883 1588 1159 404 897 865 1659 1232 1845 1547 977 1190 856 2624 523 3199 1192 2519 881 1083 -620 -393 -506 -1229 628 -592 373 -541 -670 -171 -206 460 769 1205 434 52 -875 -886 -1325 -2211 -1379 -2060 329 -1312 -202 -946 -1249 -1492 -1967 -1552 -2335 -1040 -1869 -383 789 -81 234 155 -592 -2020 -963 -217 594 1431 619 2416 2776 2450 837 1212 -299 56 1371 170 1277 405 632 -1155 379 -731 -132 399 1043 305 152 393 -2835 -1725 SS 20231124T125836.2Z 8728.540697 206 1 49.77 2 80.19 130.29 125.67 339.19 0.00 1 0.00 1 0 17 4.916e-01 1.063e-02 3.022e-01 5.693e-03 6.619411e-01 3.083938e-03 7.692995e-03 -6.000000e+00 2.744627e-01 222.67 -2.00 3.55 -2.00 321.64 0.00e+00 7.369123e-03 1.606630e-03 2.492580e-03 -6.000000e+00 1.261738e-02 277.34 -2.00 20.00 -2.00 321.15 0.00e+00 5.608 0.003 302.00 328.00 3 8.9023e-01 1.0840e-02 6.5535e-02 -6.0000e+00 6.7472e-01 1.4052e-01 1.5988e-02 3.6794e-02 -6.0000e+00 7.3671e-01 -1.5921e-01 1.7607e-02 2.3589e-02 -6.0000e+00 4.3868e-01 5.2755e-02 8.2100e-03 1.1381e-02 -6.0000e+00 1.8753e-01 4.4569e-04 -7.6353e-04 1.6597e-04 1.4634e-04 -6.0000e+00 1.2983e-02 -2.2979e-03 5.0786e-06 12 8 8 10 0 0 99.99 22.64 0.26 -0.00230 -0.00804 188 39 1 5 0 264.680 26.21 20.00 22.64 12.35 27.2 940.72 -199569 -165849 900000 -174451 -123032 900000 -239255 -15425 -183251 142829 -109476 -127202 900000 -61304 98153 -35182 -38781 -74668 -43794 -30564 -26808 126641 2708 -41805 -55524 61946 -49481 -54852 -51409 -44718 -14538 -46211 7135 -44530 27619 -20944 -8073 -8094 3572 3289 9328 15663 -12118 20455 -4847 1261 1725 4393 -18884 -10258 19578 6905 19860 5582 10212 1269 1001 8656 -9522 7855 -4692 8225 6487 7294 11278 1454 5101 752 5712 2025 1896 1125 1397 3949 -1987 -497 -2880 -965 -1644 -1645 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