File name: Pandora183s1_LondonderryNH_20231214_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240123T205510.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231214_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231214T124611.0Z 8748.532072 56 1 49.77 2 85.17 128.17 103.50 116.46 0.00 1 0.00 1 0 25 5.649e-01 8.101e-02 5.429e-01 7.865e-02 1.166418e+00 4.484934e-02 1.419028e-02 -6.000000e+00 3.218051e-01 222.40 -2.00 3.55 -2.00 322.01 0.00e+00 -4.578817e-02 1.315100e-02 8.049672e-03 -6.000000e+00 1.478771e-02 275.10 -2.00 20.00 -2.00 321.39 0.00e+00 10.098 0.020 302.00 328.00 3 -1.0799e+00 1.4627e-01 1.4515e-01 -6.0000e+00 7.9500e-01 2.7350e+00 1.6963e-01 1.4693e-01 -6.0000e+00 8.7043e-01 -2.4398e+00 9.7811e-02 3.2869e-02 -6.0000e+00 5.1460e-01 6.9118e-01 5.7996e-02 3.4636e-02 -6.0000e+00 2.1845e-01 1.7171e-05 3.2489e-03 1.9206e-03 4.3567e-04 -6.0000e+00 1.5738e-02 2.2681e-03 -8.5067e-05 12 8 8 10 0 0 3.82 22.61 1.07 0.00227 0.02668 31 6 1 5 0 1605.150 26.21 20.00 22.61 1.61 26.3 871.69 177389 37224 22556 62534 -43511 -17190 798 900000 900000 110754 900000 537 79536 315555 -24613 2474 13192 -1005 -31917 113100 5073 -8311 1560 -29205 92872 50563 -22731 48069 57153 -96206 -66703 -15704 900000 1878 -30841 57796 -71850 900000 -13860 15136 84507 -3776 900000 41206 67954 225274 900000 -5906 8587 9687 84465 135900 24113 -3884 47150 66317 58948 1592 -15901 900000 97319 -10701 33722 -18783 -31985 -22812 23049 62830 88721 157572 29071 68783 77833 28571 24344 82250 -65149 6667 -40082 -20171 46006 46472 46994 49462 14434 23692 8815 34779 6094 -22459 29780 3458 -17219 16057 12404 12113 15628 -2135 13793 -3900 16984 17539 -26148 -8964 -13257 -18348 14266 -13547 -19426 13169 7994 1384 9394 -3965 -2929 -9748 -1463 -1376 -482 9018 9643 -946 -4379 9802 -6384 -1129 3374 3530 7457 5946 -280 -5212 -157 2500 -1689 -4332 703 2918 -324 4857 -2378 -653 -722 13585 3054 1851 4789 -4284 -1316 61 900000 900000 8482 900000 79 6091 24166 -4350 335 1554 -130 -5265 8661 478 -832 156 -5161 7112 5808 -4932 3988 4377 -22717 -12345 -1904 900000 204 -4133 4426 -14214 900000 -2388 2415 7550 -819 900000 4470 5204 17252 900000 -678 877 1051 6468 10407 3078 -719 6237 7849 7797 355 -3653 900000 7453 -1788 3991 -4185 -8462 -5400 3530 6999 8647 12067 6274 10056 9754 5172 3898 6299 -20410 1068 -11720 -5758 8007 9382 10469 11364 4924 7587 3314 9927 2206 -10007 7256 1059 -6713 5030 4750 5482 7943 -1487 8835 -2933 9459 8425 -17294 -4993 -8214 -12518 7449 -10280 -18123 10543 7847 1599 10464 -5052 -3589 -13735 -1927 -1887 -680 11464 11446 -1159 -5332 10134 -7577 -1236 3540 4191 10337 9927 -569 -12294 -387 6567 -5019 -13800 2158 8805 -981 12981 -6211 -1540 -1686 SS 20231214T125745.8Z 8748.540113 59 1 49.56 2 83.53 130.27 101.69 118.15 0.00 1 0.00 1 0 25 4.681e-01 1.845e-02 4.505e-01 1.489e-02 1.057877e+00 8.684165e-03 1.125989e-02 -6.000000e+00 2.599458e-01 222.40 -2.00 3.55 -2.00 322.61 0.00e+00 1.152605e-02 5.203942e-03 6.397886e-03 -6.000000e+00 1.218158e-02 275.10 -2.00 20.00 -2.00 322.22 0.00e+00 8.048 0.010 302.00 328.00 3 -6.8203e-01 3.4753e-02 1.1021e-01 -6.0000e+00 6.3978e-01 1.4474e+00 4.8531e-02 9.3680e-02 -6.0000e+00 6.9889e-01 -1.7829e+00 4.7536e-02 3.7575e-02 -6.0000e+00 4.1694e-01 6.8697e-01 2.2339e-02 1.4578e-02 -6.0000e+00 1.7908e-01 1.1807e-04 -1.8537e-03 3.9294e-04 1.6879e-04 -6.0000e+00 1.2512e-02 -6.6117e-04 -8.8958e-06 12 8 8 10 0 0 7.28 22.60 0.41 -0.00066 -0.01459 101 21 1 5 0 490.570 26.21 20.01 22.60 2.15 26.4 876.74 -21515 143915 900000 900000 -31136 60315 -176044 47083 16463 152204 -59637 900000 -85546 -74346 5800 -68967 49879 -17 3685 39105 53129 -51328 -85272 -45457 -80141 -63513 -53960 128913 -95221 172623 -65001 -37013 -20129 -23057 23823 -21090 25328 -12361 31094 173524 95671 71726 -26833 47438 13331 101492 5423 52343 13919 22 125640 17742 29034 7694 32094 42688 40196 17359 6209 15456 -21826 38879 17828 2180 29707 24171 2520 3397 27209 12893 37590 15402 20841 20119 6947 2725 -6463 -10628 -197 7562 3758 4354 5438 -1103 3041 5241 3173 -2542 7418 5278 -463 4428 -5530 1262 -11404 513 -3333 -640 -563 -1917 324 -3525 -1300 -5257 2515 -2030 -1517 -2398 -2588 896 1228 251 -1528 -410 -997 -2270 436 -2209 769 1598 2441 1634 3459 -247 -705 -1185 699 2822 309 12 -25 -178 33 -440 -566 15 1170 880 356 -24 -360 -1255 -1256 -312 2088 900000 900000 -452 875 -5699 683 239 2209 -865 900000 -1448 -1528 84 -2168 724 0 71 567 771 -1428 -3093 -1099 -2714 -1766 -1305 1871 -3109 2505 -2122 -1164 -633 -809 534 -668 501 -391 738 2518 1515 1514 -1557 1314 510 1607 229 1450 606 1 2155 1006 1609 568 1948 2365 2280 1191 442 938 -1900 2000 1317 221 2547 2232 293 412 2872 1803 4513 2377 2942 2601 898 320 -776 -1402 -28 1217 763 1034 1435 -330 1011 1787 1042 -992 2594 1808 -156 1349 -1854 429 -5196 253 -2065 -459 -455 -1610 250 -2486 -781 -3158 1482 -1326 -1046 -1827 -2261 896 1433 329 -2137 -569 -1355 -3048 579 -3164 1126 2366 3439 2165 4272 -308 -861 -1417 807 3460 466 21 -52 -407 82 -1178 -1636 45 3527 2673 1071 -69 -935 -2998 -2857 SS 20231214T130847.1Z 8748.547768 62 1 49.67 2 82.01 132.31 100.00 119.77 0.00 1 0.00 1 0 17 6.600e-01 1.484e-02 2.395e-01 5.221e-03 9.305346e-01 2.942051e-03 1.015187e-02 -6.000000e+00 3.664456e-01 222.40 -2.00 3.55 -2.00 322.32 0.00e+00 5.357278e-03 1.727607e-03 3.455548e-03 -6.000000e+00 1.599657e-02 275.10 -2.00 20.00 -2.00 321.91 0.00e+00 6.735 0.006 302.00 328.00 3 -5.5849e-01 1.1401e-02 8.4165e-02 -6.0000e+00 9.0197e-01 7.0246e-01 1.7936e-02 5.4052e-02 -6.0000e+00 9.8522e-01 -9.2309e-01 1.9743e-02 3.2139e-02 -6.0000e+00 5.8678e-01 3.5829e-01 8.8762e-03 1.2729e-02 -6.0000e+00 2.4941e-01 4.7211e-04 -5.5779e-04 1.3938e-04 2.0052e-04 -6.0000e+00 1.7387e-02 -1.4103e-03 1.6980e-05 12 8 8 10 0 0 15.13 22.61 0.40 -0.00141 -0.00560 216 45 1 5 0 229.900 26.21 20.00 22.61 3.22 26.5 885.21 -132249 -190789 -200601 -143215 -198867 -216591 -113555 -263806 -190747 -216036 -200745 -206360 -154959 -131960 -93608 -92153 -52557 -49697 -34468 -88358 -68955 -48508 -84942 -83660 -47262 -56208 -43844 -103270 -20801 -57929 -74865 -20588 -25419 21159 11722 -29280 4328 -32288 24977 -5590 51349 29950 43245 18187 2584 15317 18197 33275 22919 24352 10141 34407 25851 24091 24273 19555 21932 22308 22999 11457 15122 11097 23323 17665 19049 22818 10447 16527 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