File name: Pandora183s1_LondonderryNH_20231215_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240123T205657.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231215_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231215T124707.0Z 8749.532720 58 1 50.06 2 85.15 128.29 112.10 105.98 0.00 1 0.00 1 0 25 7.891e-01 1.214e-01 5.620e-01 9.064e-02 8.392091e-01 4.981890e-02 9.697648e-03 -6.000000e+00 4.548882e-01 222.39 -2.00 3.55 -2.00 321.41 0.00e+00 -3.479927e-02 1.333284e-02 7.026159e-03 -6.000000e+00 1.996124e-02 274.99 -2.00 20.00 -2.00 320.69 0.00e+00 10.065 0.019 302.00 328.00 3 -2.5685e-01 1.5396e-01 1.2634e-01 -6.0000e+00 1.1255e+00 1.9775e+00 1.8223e-01 1.0554e-01 -6.0000e+00 1.2351e+00 -1.7957e+00 1.0174e-01 2.2594e-02 -6.0000e+00 7.2938e-01 5.3498e-01 5.4064e-02 2.4137e-02 -6.0000e+00 3.0935e-01 1.3250e-05 6.5237e-03 2.4659e-03 2.0217e-04 -6.0000e+00 2.1672e-02 -2.8338e-03 7.6445e-05 12 8 8 10 0 0 9.79 22.63 1.39 -0.00283 0.04619 18 4 1 5 0 2780.780 26.21 19.99 22.63 6.42 27.0 908.72 122758 132916 -25371 211278 -40490 185366 -103115 -15692 900000 -36552 322399 209937 40352 900000 207590 157398 66909 900000 50896 53116 -27052 128997 59180 -9737 175862 111578 69150 2119 93375 20670 900000 79660 900000 900000 -31403 -22647 900000 33223 -76801 106647 -24509 116883 900000 9007 37220 -36294 900000 900000 98196 71433 2852 900000 -20897 206734 38950 18932 53081 196988 208236 51351 19694 19010 64334 -23855 61894 41864 900000 87260 26163 26031 6731 54794 21373 75513 126180 -82241 266147 8013 65782 -20154 -7314 14680 40792 51974 7249 48917 -7237 29024 -45738 41159 33405 -27395 36468 8475 33960 4201 21997 -3416 38791 12499 -6737 3718 -15463 2314 -4471 14804 7555 38395 -6899 -2892 24141 -600 10906 -870 -8480 -1595 3232 -5280 -7595 -2432 -4765 -4800 5318 5466 14761 -1617 124 -5888 5997 -4533 9928 -4736 -3306 -5118 -2783 1770 4371 2934 1508 972 -6322 3605 1091 10826 11722 -4155 18633 -5101 16347 -27281 -2342 900000 -8927 28432 18514 4380 900000 18307 13881 5901 900000 4488 4684 -4588 11376 5219 -1783 15509 9840 7115 343 8235 1975 900000 7025 900000 900000 -5308 -3329 900000 3662 -32172 9405 -8105 10308 900000 1787 4924 -9069 900000 900000 8660 6300 503 900000 -5529 18232 6584 4174 8582 17372 18364 6999 3474 3505 8252 -8033 8932 7048 900000 9794 6083 6887 2321 11861 6169 11503 11128 -46154 23471 1735 8966 -7594 -2815 5179 12100 14584 3371 15687 -4178 11635 -37403 13199 10713 -15374 10818 3601 12797 2459 12345 -2793 22081 9019 -5401 2385 -11157 1447 -3226 9258 5390 21855 -6969 -3223 23032 -780 12766 -1116 -11218 -1918 3783 -7069 -10960 -3374 -6533 -6900 6706 6700 16012 -1997 149 -8360 8833 -8474 17774 -10566 -7814 -13361 -7657 4855 11912 8201 4190 2554 -16615 8074 2511 SS 20231215T125855.4Z 8749.540919 61 1 49.24 2 83.48 130.43 110.11 107.67 0.00 1 0.00 1 0 17 4.632e-01 2.770e-02 4.085e-01 1.900e-02 8.133291e-01 1.078333e-02 9.153751e-03 -6.000000e+00 2.599717e-01 222.39 -2.00 3.55 -2.00 322.19 0.00e+00 9.845764e-04 5.740000e-03 5.792436e-03 -6.000000e+00 1.234913e-02 274.99 -2.00 20.00 -2.00 321.75 0.00e+00 7.996 0.010 302.00 328.00 3 1.1535e-01 3.9761e-02 9.4489e-02 -6.0000e+00 6.4106e-01 1.0049e+00 5.2964e-02 5.7898e-02 -6.0000e+00 7.0190e-01 -1.2915e+00 4.8355e-02 2.9126e-02 -6.0000e+00 4.1560e-01 5.1383e-01 2.3157e-02 8.3210e-03 -6.0000e+00 1.7874e-01 8.1931e-05 -1.0689e-03 5.5787e-04 1.5759e-04 -6.0000e+00 1.2943e-02 -2.5536e-03 2.8106e-05 12 8 8 10 0 0 30.95 22.63 0.50 -0.00255 -0.01059 54 11 1 5 0 911.630 26.21 20.00 22.63 7.28 27.1 916.19 13602 900000 900000 -112482 900000 -104198 -107058 900000 -129976 -50429 -150739 -81267 900000 -37629 -5403 3811 6859 134492 68365 -27858 64446 67987 44613 900000 -10916 87198 -43808 900000 900000 -62068 21443 867 900000 -24689 61061 96847 157864 -15604 11753 51641 15197 187020 58002 36701 -8588 61465 139307 -12392 66695 21096 16381 29452 78520 20050 27219 47465 13016 41358 17712 -398 9270 85524 12610 24458 51445 10569 11269 26373 11823 6750 25477 20918 8905 22336 -2966 37700 5755 -11909 2816 -1778 4168 -1183 4009 -1862 3682 -1064 502 2795 3147 -4335 -7843 -1971 -17366 -4307 -9872 -232 4308 -5543 526 -720 -1165 -892 -4802 -1249 -3564 -58 -4287 1326 -802 275 168 -26 393 -579 1857 -3632 1109 -4686 1587 1216 2686 4365 1171 2301 -735 3528 -1479 2730 966 1129 -704 -1207 -732 253 -468 -1056 2376 1236 417 211 -1431 -1646 -1012 252 900000 900000 -4802 900000 -2966 -3047 900000 -5179 -933 -7508 -2082 900000 -986 -125 94 180 2488 1265 -1117 1192 1258 825 900000 -353 1613 -1959 900000 900000 -2871 496 29 900000 -1332 1318 1792 2921 -840 573 1998 946 3460 2536 1975 -708 2481 2577 -1063 2692 1419 1267 2229 3962 1956 2609 3832 1510 3547 1817 -46 967 4459 1548 3044 5278 1618 1687 3504 1988 1374 4756 4257 2007 4095 -629 4692 910 -2283 526 -419 1101 -382 1369 -717 1424 -458 223 1246 1392 -2189 -3830 -853 -8546 -1952 -5406 -136 2853 -4717 468 -660 -1008 -688 -3456 -857 -2690 -45 -3672 1162 -803 314 219 -37 567 -830 2491 -4972 1463 -6884 2322 1849 3950 6016 1601 3026 -966 4307 -1849 3475 1450 1959 -1391 -2592 -1667 611 -1225 -2922 6475 3448 1163 561 -3592 -3842 -2261 SS 20231215T131002.1Z 8749.548636 64 1 49.66 2 81.95 132.49 108.25 109.26 0.00 1 0.00 1 0 17 5.903e-01 1.186e-02 2.966e-01 5.973e-03 7.136977e-01 3.242718e-03 8.440586e-03 -6.000000e+00 3.277578e-01 222.39 -2.00 3.55 -2.00 321.90 0.00e+00 6.746457e-03 1.746156e-03 4.787561e-03 -6.000000e+00 1.430112e-02 274.99 -2.00 20.00 -2.00 321.44 0.00e+00 6.691 0.006 302.00 328.00 3 2.2793e-02 1.1705e-02 7.7876e-02 -6.0000e+00 8.0675e-01 2.9125e-01 1.7724e-02 4.4616e-02 -6.0000e+00 8.8120e-01 -3.4151e-01 1.9674e-02 2.8874e-02 -6.0000e+00 5.2479e-01 1.2176e-01 9.0576e-03 1.2183e-02 -6.0000e+00 2.2309e-01 3.6911e-04 -5.2070e-04 1.7269e-04 1.9354e-04 -6.0000e+00 1.5550e-02 -2.9243e-03 -4.5721e-06 12 8 8 10 0 0 15.71 22.63 0.45 -0.00292 -0.00684 134 28 1 5 0 370.530 26.21 20.00 22.63 8.26 27.0 922.44 -267383 36957 -196614 -165594 -169042 -118723 -236551 -196284 -147398 -173467 -214885 -150443 -120824 -120205 -15092 -70901 -90536 -35680 -63805 58023 2026 -9995 -9041 13752 -45843 -55121 -47272 -68970 -53099 -51541 -9791 -56103 -32001 14016 -12680 4776 -10923 -13615 -3236 -2309 8419 8338 -5086 -3171 19792 5166 13204 1957 6657 9504 9511 10860 860 24523 12869 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