File name: Pandora183s1_LondonderryNH_20231216_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240123T205843.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231216_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231216T124754.3Z 8750.533268 58 1 48.63 2 85.15 128.37 119.81 94.01 0.00 1 0.00 1 0 25 5.767e-01 9.924e-02 4.895e-01 9.632e-02 8.368704e-01 5.256691e-02 9.470752e-03 -6.000000e+00 3.265734e-01 222.40 -2.00 3.55 -2.00 320.92 0.00e+00 -3.250305e-03 1.105580e-02 1.579128e-03 -6.000000e+00 1.580787e-02 274.90 -2.00 20.00 -2.00 320.19 0.00e+00 10.055 0.019 302.00 328.00 3 -4.3253e-01 1.4823e-01 1.0824e-01 -6.0000e+00 8.0543e-01 2.3689e+00 1.7243e-01 4.2513e-02 -6.0000e+00 8.8303e-01 -2.0486e+00 9.8149e-02 2.0013e-02 -6.0000e+00 5.2219e-01 5.8653e-01 5.3480e-02 6.5085e-03 -6.0000e+00 2.2276e-01 1.3179e-05 3.8941e-03 2.6804e-03 7.2993e-05 -6.0000e+00 1.5577e-02 -4.0314e-03 1.4035e-04 12 8 8 10 0 0 9.70 22.66 1.24 -0.00403 0.02523 18 4 1 5 0 2700.960 26.32 20.00 22.66 8.81 27.3 927.67 123086 900000 10558 900000 -21579 900000 -87 33393 900000 -16289 141663 -40169 900000 37141 138755 126771 15815 900000 27795 197075 900000 900000 -39240 -41533 900000 93548 3338 -14689 9065 -56455 127876 35951 -33499 56883 6442 10673 11886 97214 -17772 234706 51327 900000 65661 59848 36449 -21884 86903 -30295 118005 -42199 900000 73098 -11963 215071 -5068 62172 33552 32033 -15061 2173 7013 1302 114702 37117 87215 -15171 102632 -59164 113866 74521 34017 44537 -2442 109183 8570 66739 11933 -17673 49961 28325 12916 2219 33686 2916 123223 -11252 30601 16887 6992 18130 -175 7446 48244 -2417 -4266 -15104 14632 -15072 17822 -22404 -1918 22746 2289 -3727 1887 604 -16538 -2395 -5042 16330 -7587 15902 17215 -7900 -5155 -3066 4117 648 4146 5565 -6543 5712 -9397 7970 1933 6891 -17255 2406 7933 367 -285 1066 7114 1694 -3023 -1028 -1882 -675 -3072 4833 -1602 8115 -3962 12361 900000 3110 900000 -5779 900000 -15 4574 900000 -3641 13278 -10716 900000 5891 13005 11882 3877 900000 5812 18472 900000 900000 -11600 -12877 900000 8768 602 -2754 1274 -14993 11986 4774 -9681 6665 1107 1584 1764 9112 -4581 21999 8018 900000 8719 7947 5694 -5812 8145 -8282 11061 -13514 900000 8564 -3457 20159 -1465 9227 6552 6005 -4117 500 1494 311 10751 7591 11147 -5171 10494 -31256 11643 12700 9275 11005 -915 12094 2264 8530 2440 -4969 8088 6758 4182 907 10907 1342 17850 -6520 11994 7626 3396 7415 -79 2918 12332 -1092 -2254 -10425 8728 -13871 12757 -23672 -1520 12404 1385 -2414 1238 422 -14515 -1980 -4812 14471 -9632 17073 18483 -10636 -6457 -3658 4666 801 5229 7065 -9088 7335 -13564 9412 2355 7751 -24421 3067 11227 646 -563 2248 15136 4111 -8302 -2900 -5468 -1968 -9070 12502 -4115 17721 -9656 SS 20231216T125945.2Z 8750.541496 61 1 49.68 2 83.47 130.52 117.73 95.82 0.00 1 0.00 1 0 25 5.359e-01 2.450e-02 4.398e-01 1.727e-02 8.078888e-01 9.583552e-03 9.211266e-03 -6.000000e+00 2.978958e-01 222.40 -2.00 3.55 -2.00 322.26 0.00e+00 6.254890e-03 5.289334e-03 4.465420e-03 -6.000000e+00 1.336057e-02 274.90 -2.00 20.00 -2.00 321.82 0.00e+00 7.985 0.010 302.00 328.00 3 -6.9914e-03 3.5729e-02 9.1095e-02 -6.0000e+00 7.3274e-01 8.8017e-01 4.8836e-02 4.7446e-02 -6.0000e+00 8.0088e-01 -1.1185e+00 4.6924e-02 2.7973e-02 -6.0000e+00 4.7653e-01 4.3193e-01 2.2234e-02 1.1192e-02 -6.0000e+00 2.0453e-01 9.6245e-05 -1.0194e-03 4.9181e-04 1.9604e-04 -6.0000e+00 1.4468e-02 -9.4218e-04 -1.1435e-05 12 8 8 10 0 0 67.63 22.67 0.49 -0.00094 -0.00860 68 14 1 5 0 730.450 26.32 20.00 22.67 9.88 27.3 935.78 900000 -95357 -103409 -108945 900000 6446 -122072 35446 -138906 152309 -78993 -196268 -17630 -53779 -62962 -44553 -48606 84009 -65048 20455 -46753 900000 -51839 20546 -13689 -39890 263025 -36964 32769 -89808 79458 -10609 -20631 -4987 150622 194102 -18950 -17528 -39718 122432 -2699 80424 14534 30590 116612 23894 34773 -17198 29921 5809 103975 -10841 15840 54595 34133 29497 7623 22263 3311 52239 16317 33414 31584 15419 39993 11688 7391 2897 31851 22482 9126 28653 6352 26560 -12203 15086 4624 9888 11327 -7956 4242 -500 3141 -545 5044 4046 -1553 3984 1993 4346 494 2501 -4074 -5883 -2638 -2992 -950 -4021 526 -1290 -2478 -5970 -28 -3457 -5964 -496 -5201 34 -2720 877 704 147 -811 -615 -1209 -3791 -45 464 1821 2234 1765 517 2092 3363 -13 2778 -2155 1477 454 2214 697 -1178 698 -1743 -118 16 915 977 237 1123 -1176 -484 -2529 900000 -1852 -2277 -2399 900000 109 -2213 597 -3238 2564 -1330 -8642 -297 -981 -1590 -1125 -1432 1414 -2555 344 -1509 900000 -1600 346 -307 -1175 4428 -985 552 -4032 1338 -313 -782 -175 2536 3268 -754 -778 -2614 2061 -161 2216 801 1451 2320 1207 1597 -1369 1557 409 3024 -1112 1358 3426 2769 2573 840 2079 355 3278 1473 2762 3045 2006 4407 1699 1109 470 4241 3785 1941 5219 1419 4512 -2745 2286 722 1498 1924 -1985 1117 -160 1077 -206 1915 1647 -701 1750 980 2012 222 1036 -1756 -2714 -1350 -1823 -670 -3412 474 -1201 -2194 -4885 -19 -2450 -4659 -390 -4545 30 -2812 1007 921 210 -1194 -888 -1683 -5240 -61 656 2694 3408 2653 751 2874 4439 -17 3470 -2761 1944 702 3891 1391 -2589 1605 -4405 -317 44 2597 2809 682 3052 -3041 -1157 -5962 SS 20231216T131047.7Z 8750.549163 64 1 49.85 2 81.96 132.57 115.79 97.49 0.00 1 0.00 1 0 17 5.625e-01 1.527e-02 2.579e-01 5.881e-03 7.253441e-01 3.191961e-03 8.660339e-03 -6.000000e+00 3.123076e-01 222.40 -2.00 3.55 -2.00 321.95 0.00e+00 8.168789e-03 1.724866e-03 5.082323e-03 -6.000000e+00 1.362227e-02 274.90 -2.00 20.00 -2.00 321.50 0.00e+00 6.692 0.006 302.00 328.00 3 -5.2398e-02 1.1554e-02 7.8506e-02 -6.0000e+00 7.6877e-01 4.1578e-01 1.6813e-02 4.5065e-02 -6.0000e+00 8.3975e-01 -5.7046e-01 1.7850e-02 2.7811e-02 -6.0000e+00 5.0008e-01 2.2657e-01 8.2560e-03 1.1463e-02 -6.0000e+00 2.1253e-01 3.8922e-04 -9.9125e-04 1.6898e-04 2.0099e-04 -6.0000e+00 1.4818e-02 -1.7410e-03 7.7502e-06 12 8 8 10 0 0 65.10 22.67 0.45 -0.00174 -0.00919 151 31 1 5 0 330.040 26.32 20.00 22.67 11.05 27.3 944.09 -205830 -4418 -218819 -150434 -181344 -178544 -164520 -185045 36850 -210549 -112135 -162941 -116824 -122332 -41392 -20154 -6035 118564 -42603 -4346 -66664 34370 -58237 -6311 -21022 -74734 -47048 -42865 -18587 -45624 125188 67221 -27527 9633 684 -21933 -28954 21390 -14346 28187 58417 21688 32902 14347 8994 18979 41415 36089 37948 23344 23604 8184 11842 20619 4219 21475 11462 13931 10262 6031 14353 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