File name: Pandora183s1_LondonderryNH_20231226_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240113T083832.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20231226_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20231226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231226T162027.0Z 8760.680868 418 1 3.18 2 66.48 173.59 109.88 358.11 0.00 1 0.00 1 0 17 5.290e-02 1.095e-02 4.532e-02 8.253e-03 3.468509e-01 4.053232e-03 4.186351e-03 -6.000000e+00 2.941980e-02 222.78 -2.00 3.55 -2.00 318.16 0.00e+00 3.335708e-04 7.354080e-04 3.462138e-04 -6.000000e+00 1.277994e-03 274.28 -2.00 20.00 -2.00 317.59 0.00e+00 2.488 0.000 302.00 328.00 3 3.3341e+00 1.0769e-02 3.0102e-02 -6.0000e+00 7.2494e-02 4.7768e-02 1.2220e-02 1.7615e-02 -6.0000e+00 7.9162e-02 -4.5293e-03 8.1113e-03 8.8271e-03 -6.0000e+00 4.7113e-02 -4.8861e-03 4.2571e-03 2.5524e-03 -6.0000e+00 2.0006e-02 1.0431e-03 -6.2212e-04 2.3229e-04 2.6622e-05 -6.0000e+00 1.3933e-03 -4.2355e-03 3.3133e-05 12 9 9 12 1 1 999.00 22.66 0.46 -0.00424 -0.00891 1 6 1 5 0 1584.470 26.32 20.00 22.66 15.74 27.9 982.27 -28200 -13849 1406 -15429 -16556 -15224 -3303 -22100 -3106 28363 -1087 8286 -7430 -12174 2784 871 -7973 271 -4686 3517 -1086 4870 5756 1251 -5210 87 -3402 3230 -2830 4437 943 -2161 -2331 -3993 -4714 -4190 585 -3658 1682 260 3259 209 -2116 -893 1059 2568 3216 -1491 -704 2433 -688 1529 1449 2518 2935 261 750 -702 182 436 1251 2046 1570 1816 708 -501 -1545 -177 362 1695 569 1417 217 -2327 -733 -2920 649 -150 454 -1635 -1925 -2 -2940 -420 -1140 -699 380 836 1168 37 1041 309 -1403 -730 -234 -1044 -11 2067 -443 843 -962 -500 -1304 449 -830 -2897 -1261 -139 -424 -51 1308 804 630 69 -422 -586 -386 138 -425 766 -236 1884 837 1109 1036 -93 640 907 -23 263 -833 392 -738 -171 297 170 -583 964 336 -47 -111 -848 -1283 -1671 -821 84 -1068 -1039 -870 -173 -1565 -207 1507 -79 554 -652 -1323 307 112 -1213 40 -766 552 -184 776 917 222 -1057 18 -728 621 -540 768 180 -473 -567 -1057 -1206 -1012 143 -1078 569 97 1323 93 -1000 -425 494 1184 1464 -702 -326 1102 -340 803 817 1492 1810 156 456 -434 109 279 809 1289 1093 1373 557 -377 -1090 -120 257 1351 509 1222 190 -2012 -629 -2305 446 -107 310 -1291 -1739 -2 -2990 -437 -1274 -774 440 997 1394 44 1205 330 -1400 -702 -237 -1193 -13 2665 -588 1100 -1284 -606 -1481 510 -1035 -3912 -1752 -187 -606 -79 1988 1260 964 107 -602 -786 -550 190 -629 1191 -377 2890 1258 1598 1523 -131 856 1221 -33 391 -1329 640 -1169 -281 516 310 -1038 1722 605 -88 -199 -1460 -2166 SS 20231226T162518.5Z 8760.684242 421 1 4.97 2 66.39 174.80 109.90 359.20 0.00 1 0.00 1 0 17 2.240e-02 7.477e-03 7.707e-03 1.606e-03 3.401944e-01 7.880312e-04 4.114398e-03 -6.000000e+00 1.245906e-02 222.78 -2.00 3.55 -2.00 317.91 0.00e+00 1.105054e-03 1.333827e-04 3.671411e-04 -6.000000e+00 5.412355e-04 274.27 -2.00 20.00 -2.00 317.33 0.00e+00 2.479 0.000 302.00 328.00 3 1.3375e+00 2.0822e-03 2.9798e-02 -6.0000e+00 3.0701e-02 1.7736e-02 2.3598e-03 1.7196e-02 -6.0000e+00 3.3525e-02 -3.3146e-04 1.5231e-03 8.6688e-03 -6.0000e+00 1.9952e-02 -4.1020e-03 7.9183e-04 2.6198e-03 -6.0000e+00 8.4717e-03 7.9235e-03 -3.3100e-04 4.5002e-05 2.7139e-05 -6.0000e+00 5.9010e-04 -3.8534e-03 2.6929e-05 12 9 1 12 1 1 92.97 22.65 0.26 -0.00385 -0.00634 25 54 1 5 0 190.640 26.32 20.00 22.65 16.11 28.0 985.01 -7623 -1124 -4163 -7376 -8758 -9991 -6277 -4711 -7048 -1847 -6368 -7481 -3163 -2947 -1735 -935 214 1009 866 2217 470 -259 147 738 -252 521 -237 -3241 -1275 -386 916 -310 1659 -856 -3394 -3603 -3712 -2198 -455 -420 -778 41 -147 -269 951 258 304 470 -694 -170 558 658 1151 1713 997 1493 660 343 83 499 932 1496 2091 3179 1033 169 -504 -915 644 654 788 745 215 475 348 -491 -1437 -1903 -857 -1468 -1244 -1264 -2117 -1855 -1085 -733 -89 289 1104 605 300 23 -798 -265 -540 -394 180 987 411 -217 -637 -1346 -780 -348 -1171 -1081 -812 -766 267 502 1009 482 694 197 -183 116 333 89 455 424 203 470 864 539 599 -63 -61 774 284 72 -175 -576 -303 11 -188 -119 230 579 142 -116 -259 -567 -716 -468 -75 -303 -544 -587 -626 -390 -322 -561 -151 -553 -666 -304 -335 -230 -141 34 170 154 406 90 -50 28 150 -55 120 -56 -756 -273 -80 201 -77 445 -229 -982 -992 -1086 -667 -164 -181 -345 19 -71 -133 466 128 150 229 -339 -83 287 368 686 1079 609 931 425 222 53 337 590 1010 1546 2529 801 134 -375 -665 486 522 696 692 202 428 293 -403 -1075 -1360 -634 -1241 -1110 -1176 -2145 -1967 -1218 -825 -106 352 1340 714 330 25 -797 -273 -556 -451 216 1234 555 -293 -812 -1672 -898 -408 -1499 -1380 -1082 -1073 370 749 1515 746 1043 294 -268 158 453 126 652 645 315 715 1270 764 855 -87 -84 1075 403 105 -273 -930 -498 19 -324 -205 406 1037 256 -205 -461 -967 -1195 SS 20231226T163556.1Z 8760.691622 424 1 50.46 2 66.26 177.46 109.88 1.59 0.00 1 0.00 1 0 17 5.773e-02 9.035e-03 3.818e-02 4.515e-03 3.361639e-01 2.219158e-03 4.079674e-03 -6.000000e+00 3.210628e-02 222.78 -2.00 3.55 -2.00 319.18 0.00e+00 1.018847e-03 5.286971e-04 7.652833e-04 -6.000000e+00 1.394728e-03 274.27 -2.00 20.00 -2.00 318.60 0.00e+00 2.466 0.000 302.00 328.00 3 4.3454e+00 6.0708e-03 2.9746e-02 -6.0000e+00 7.9114e-02 5.2967e-02 7.0157e-03 1.7417e-02 -6.0000e+00 8.6393e-02 2.0850e-03 5.1876e-03 8.8387e-03 -6.0000e+00 5.1416e-02 -8.1528e-03 2.7510e-03 2.6437e-03 -6.0000e+00 2.1831e-02 3.9115e-04 -4.7325e-04 1.3200e-04 2.8777e-05 -6.0000e+00 1.5207e-03 -3.8959e-03 2.5353e-05 11 8 0 10 0 0 99.77 22.64 0.23 -0.00390 -0.00745 18 4 1 5 0 2803.120 26.21 20.00 22.64 17.01 27.9 991.03 -9442 -6347 4721 -20535 -33109 -38028 -1689 -11976 -1970 14533 -19147 4192 6889 -8735 4958 -1827 7212 -1417 -7292 7318 4813 2828 664 -1231 -4908 3718 -1079 514 -213 -533 3177 -933 -3321 -1900 -5757 -3244 -4978 -6419 -439 1192 -2040 325 -1054 29 -1092 1415 -975 2621 -1420 -294 1615 -1449 3171 760 533 2015 -858 -851 -1876 1518 1102 2820 1887 3572 1185 843 1494 -1486 3312 65 1124 532 1232 562 889 -851 -1128 -2272 -804 -2043 216 -1283 -2742 -2231 -808 -555 975 1098 1165 709 -286 389 -633 -27 -1401 -145 246 1095 242 -836 -141 -2015 -21 -1513 -1577 -1232 -683 -640 -194 764 568 822 622 292 -578 -259 291 -120 697 302 4 618 1138 176 317 -36 -219 827 203 440 142 -512 -570 -300 -6 -338 545 554 -209 372 509 -1026 -904 -322 -242 171 -942 -1543 -1716 -55 -479 -81 549 -1026 180 324 -567 331 -150 635 -143 -823 744 518 309 75 -149 -660 482 -149 67 -26 -64 394 -134 -541 -326 -984 -513 -849 -1285 -100 318 -630 104 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