File name: Pandora183s1_LondonderryNH_20240119_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240120T050003.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240119_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240119T140411.0Z 8784.586238 155 1 36.10 2 74.57 138.46 111.32 34.80 0.00 1 0.00 1 0 17 3.631e-01 1.328e-02 1.900e-01 7.299e-03 5.996976e-01 3.792978e-03 7.214439e-03 -6.000000e+00 2.027142e-01 223.68 -2.00 3.55 -2.00 320.88 0.00e+00 5.561023e-03 1.539483e-03 2.776418e-03 -6.000000e+00 8.890908e-03 273.02 -2.00 20.00 -2.00 320.40 0.00e+00 3.692 0.001 302.00 328.00 3 3.3339e+00 1.1598e-02 4.8505e-02 -6.0000e+00 5.0072e-01 1.4851e-01 1.5237e-02 3.2744e-02 -6.0000e+00 5.4679e-01 -1.5446e-01 1.5704e-02 2.0943e-02 -6.0000e+00 3.2500e-01 5.6165e-02 7.7998e-03 9.5540e-03 -6.0000e+00 1.3916e-01 2.3586e-04 -2.0640e-04 2.0624e-04 1.2266e-04 -6.0000e+00 9.7301e-03 -5.3128e-03 5.2258e-05 12 9 9 12 1 1 90.56 22.68 0.33 -0.00531 -0.00686 14 4 1 5 0 2406.120 26.32 20.00 22.68 1.07 26.6 883.34 900000 -130954 -120866 900000 -140426 -88285 -79271 -128327 -188138 -119579 -75836 -119035 -88787 -55753 -7165 22515 -14117 -28422 -45031 -37703 -26595 28424 4117 -7581 -23774 -13126 -343 -38480 -9400 32267 14120 26165 -12288 -107 -4012 -32219 -17408 -8619 10795 13706 13063 4331 11599 9389 9580 6597 -7413 5258 -5984 2284 3520 5724 6202 12954 7860 5716 4343 2336 -61 1915 -723 1837 5159 6080 1177 5984 1209 -120 1990 3728 793 -450 3811 87 613 1304 -2416 -5469 -2059 -2372 -4086 -257 -1726 -2440 -2349 -772 -479 2066 1048 1638 3469 -2085 -2135 -2464 -1878 -1775 133 2413 -605 -713 -21 -973 -1521 -727 -1237 -1571 -2217 -1119 759 1379 668 -272 164 -395 -485 -430 594 326 395 672 1090 1665 1380 405 -491 -811 173 528 25 307 -446 80 -868 100 -78 335 259 133 -64 -273 360 -927 -136 900000 -2019 -1863 900000 -2415 -838 -705 -2055 -6136 -2127 -899 -2329 -1579 -926 -102 291 -301 -772 -1573 -1293 -843 515 96 -211 -830 -433 -10 -1643 -292 689 420 829 -668 -6 -215 -2188 -1081 -569 712 1055 1149 448 1178 1008 1041 755 -997 639 -844 312 519 922 1087 2296 1706 1310 1035 567 -15 443 -175 473 1457 1921 416 1971 404 -41 719 1523 371 -223 1803 40 260 491 -866 -2004 -800 -1090 -2236 -154 -1155 -1736 -1775 -612 -399 1729 886 1328 2572 -1515 -1469 -1720 -1441 -1567 133 2692 -760 -901 -24 -1035 -1480 -701 -1289 -1739 -2595 -1380 999 2009 1080 -467 280 -651 -749 -632 864 496 639 1130 1813 2651 2120 605 -710 -1129 229 722 38 529 -844 160 -1819 220 -166 745 589 307 -146 -604 819 -2007 -283 SS 20240119T140951.3Z 8784.590177 158 1 50.05 2 73.89 139.65 110.72 36.02 0.00 1 0.00 1 0 17 2.690e-01 8.603e-03 2.698e-01 5.511e-03 5.902094e-01 2.891260e-03 6.900379e-03 -6.000000e+00 1.501644e-01 223.68 -2.00 3.55 -2.00 320.89 0.00e+00 7.657667e-04 1.185583e-03 2.636653e-03 -6.000000e+00 6.484721e-03 273.02 -2.00 20.00 -2.00 320.42 0.00e+00 3.545 0.001 302.00 328.00 3 3.2799e+00 8.8907e-03 4.7840e-02 -6.0000e+00 3.7090e-01 6.5045e-02 1.1902e-02 3.4522e-02 -6.0000e+00 4.0511e-01 -3.8516e-02 1.2699e-02 1.8481e-02 -6.0000e+00 2.4071e-01 3.3219e-03 6.2888e-03 5.6590e-03 -6.0000e+00 1.0262e-01 2.9581e-04 -3.4883e-04 1.5849e-04 7.8650e-05 -6.0000e+00 7.1738e-03 -5.1020e-03 1.9017e-05 11 8 0 10 0 0 98.21 22.68 0.25 -0.00510 -0.00772 28 6 1 5 0 1786.620 26.32 19.99 22.68 1.38 26.6 886.05 900000 -62409 -174222 -2653 17581 81386 36016 -122727 -38606 -12393 33346 -117743 -21180 -71904 900000 -75265 42805 -21442 19129 10595 -4883 -11054 -21891 54593 -27368 -4873 -12549 -14944 -17491 -13316 46454 -5325 18869 -10312 11876 -4968 -10485 5619 -4000 4535 1022 11039 -7837 1544 -618 4361 3431 -835 4568 3938 2579 1313 -824 1897 1983 4158 -3827 1155 -2566 961 -118 1125 7148 4285 2915 -1174 1796 1681 1431 712 1389 1668 -792 2572 -1954 -57 221 -1489 -715 -4488 -1758 -1729 -1294 -1735 743 -825 937 196 247 601 -385 -141 -847 -322 -1054 -252 1080 1132 521 -278 11 -1876 -1019 -1128 -1519 -317 -1036 -447 30 450 975 504 187 -480 -469 104 372 -256 802 -4 871 916 806 273 -80 -671 76 308 -547 -132 -75 -688 -388 24 -169 -293 -426 944 181 415 -148 -318 -295 900000 -363 -3432 -14 94 437 194 -1539 -242 -67 179 -2056 -171 -1223 900000 -2022 439 -461 299 191 -107 -259 -588 747 -936 -143 -411 -489 -564 -423 930 -213 691 -559 505 -240 -574 307 -297 377 101 1068 -965 178 -73 501 404 -105 562 514 374 216 -152 371 413 883 -912 263 -589 228 -29 294 1986 1379 1012 -414 595 563 521 301 650 819 -397 1186 -865 -22 79 -531 -276 -2115 -942 -1056 -865 -1233 548 -660 775 169 212 496 -298 -101 -579 -221 -804 -219 1064 1270 641 -345 13 -1996 -979 -1086 -1581 -345 -1193 -544 39 654 1553 849 315 -780 -714 150 533 -384 1265 -7 1423 1443 1224 402 -113 -916 98 413 -828 -223 -138 -1341 -787 50 -385 -702 -948 2316 446 978 -329 -670 -602 SS 20240119T141527.2Z 8784.594065 161 1 50.60 2 73.24 140.83 110.12 37.21 0.00 1 0.00 1 0 17 3.053e-01 1.280e-02 2.756e-01 8.776e-03 5.732188e-01 4.552024e-03 6.780567e-03 -6.000000e+00 1.703568e-01 223.68 -2.00 3.55 -2.00 320.81 0.00e+00 2.599702e-03 1.790247e-03 2.320706e-03 -6.000000e+00 7.337801e-03 273.02 -2.00 20.00 -2.00 320.34 0.00e+00 3.414 0.001 302.00 328.00 3 3.9036e+00 1.3853e-02 4.5731e-02 -6.0000e+00 4.2078e-01 1.5161e-01 1.7910e-02 3.1993e-02 -6.0000e+00 4.5928e-01 -1.2435e-01 1.8042e-02 1.7819e-02 -6.0000e+00 2.7296e-01 3.8904e-02 9.0649e-03 6.0471e-03 -6.0000e+00 1.1558e-01 1.7671e-04 -7.6425e-04 2.5216e-04 8.2260e-05 -6.0000e+00 8.0419e-03 -5.0863e-03 3.2922e-05 12 8 8 10 0 0 96.06 22.68 0.36 -0.00509 -0.01083 16 3 1 5 0 3161.660 26.32 19.99 22.68 1.73 26.6 888.85 -130853 40658 -66177 -82852 41245 -138157 -78636 -148426 -102969 24076 -20729 -57837 -44224 -15571 -6906 69074 -35654 38020 -36055 -15654 -7469 45531 15036 -50102 53981 21854 -2915 -11353 -27944 37212 -42631 30956 -20341 16195 -3868 -6163 70246 -21964 17194 -3782 -13029 8569 6552 -3863 7625 15952 -10434 12907 6051 16128 -4227 2315 8297 1501 6964 -297 -451 1416 2831 5151 6013 4863 8840 6424 -2812 -17 2411 3871 -1172 -1198 163 388 3795 1883 -1183 -3896 -1620 -2477 -997 2790 -1326 95 -3156 -1254 526 -55 -671 -1355 916 1514 948 -1881 -524 -1069 -1057 -553 1046 161 -550 670 -571 -491 -1661 -1784 -841 -1544 -1532 -1680 1198 1090 706 207 1039 -57 -1717 829 -519 -100 954 63 242 1607 599 -322 1901 -1129 785 444 -513 453 -80 -383 -615 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