File name: Pandora183s1_LondonderryNH_20240205_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240214T155840.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240205_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240205T123122.3Z 8801.521786 156 1 49.54 2 84.97 117.31 70.92 176.96 0.00 1 0.00 1 0 25 5.366e-01 5.547e-02 4.479e-01 5.375e-02 1.283992e+00 3.182206e-02 1.451686e-02 -6.000000e+00 3.087398e-01 224.34 -2.00 3.55 -2.00 322.28 0.00e+00 -3.083490e-02 1.001444e-02 9.844645e-03 -6.000000e+00 1.322496e-02 273.01 -2.00 20.00 -2.00 321.74 0.00e+00 9.797 0.018 302.00 328.00 3 -1.4023e+00 1.0586e-01 1.4530e-01 -6.0000e+00 7.6585e-01 3.0300e+00 1.2225e-01 1.3928e-01 -6.0000e+00 8.3768e-01 -2.8004e+00 7.0417e-02 3.6755e-02 -6.0000e+00 4.9394e-01 8.3119e-01 4.1356e-02 2.7022e-02 -6.0000e+00 2.0556e-01 2.5332e-05 3.3394e-04 1.2302e-03 2.8105e-04 -6.0000e+00 1.4445e-02 -2.4281e-03 3.5510e-06 12 8 8 10 0 0 28.92 22.76 0.75 -0.00243 0.00008 42 9 1 5 0 1179.370 26.41 20.00 22.76 0.79 26.7 890.00 149314 1512 53442 -14930 73354 -30495 900000 18021 900000 39475 744 37102 36923 900000 -38401 52001 38109 35061 900000 38288 320631 88455 24973 -8960 45585 73627 -3943 51388 -7983 87397 14199 194848 -29657 75627 9660 -51409 -41284 641 216032 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1892 3178 -7400 -6384 -7410 -2788 5528 -1148 4382 11224 -933 8862 1691 4608 3451 3391 1220 -320 -3125 120 -2370 -4611 10365 487 6170 806 5310 744 -7351 3344 -12957 2010 -9095 1958 -3249 7758 6066 2759 2269 -5908 2667 -2754 2277 1127 12519 585 -2421 4617 -10427 9425 994 6272 -8986 -6322 -818 -3141 4575 -4545 6758 -11033 -6077 -1829 -1496 3603 1123 5265 -1567 2087 -2150 5192 SS 20240205T124240.2Z 8801.529631 159 1 49.70 2 83.14 119.33 70.87 179.53 0.00 1 0.00 1 0 25 4.930e-01 2.136e-02 3.657e-01 1.023e-02 1.096243e+00 6.039384e-03 1.150463e-02 -6.000000e+00 2.774103e-01 224.34 -2.00 3.55 -2.00 322.66 0.00e+00 6.051312e-03 3.490071e-03 2.711477e-03 -6.000000e+00 1.242099e-02 273.01 -2.00 20.00 -2.00 322.28 0.00e+00 7.671 0.009 302.00 328.00 3 -8.1244e-01 2.3876e-02 9.8950e-02 -6.0000e+00 6.8506e-01 1.5219e+00 3.3136e-02 6.9121e-02 -6.0000e+00 7.4858e-01 -1.9608e+00 3.1646e-02 3.4775e-02 -6.0000e+00 4.4476e-01 7.5845e-01 1.4954e-02 1.3140e-02 -6.0000e+00 1.8718e-01 1.8895e-04 -9.8716e-04 2.6935e-04 1.8196e-04 -6.0000e+00 1.3041e-02 -3.5759e-03 1.4354e-05 12 8 8 10 0 0 20.75 22.77 0.43 -0.00358 -0.01099 138 29 1 5 0 360.090 26.41 20.00 22.77 1.21 26.8 893.50 6359 25891 -78177 32888 3016 -128226 -93063 -140755 3003 -142868 -76961 43226 -88807 -33013 -54220 900000 -30815 261454 -38293 121833 -3052 -28456 34178 -11677 900000 -90257 900000 -48885 -20127 -36128 -35840 113752 -9106 47195 49457 12538 -20484 25810 68747 -4701 157792 -4523 116748 40039 59600 65716 32893 23584 5702 80878 34713 89233 39391 65213 82079 45335 45703 754 83277 11759 67584 10918 13830 30988 12178 36938 6503 40811 25213 36545 28667 32243 20233 12448 25224 -11005 14510 -20582 13608 5758 12166 11675 -203 11282 8113 11193 297 11824 5402 -1403 559 -5247 -5082 -7830 -3732 -4679 6 344 -3102 -688 -3193 -1879 -5268 -1834 -6845 -5482 -1436 -3166 1559 -2485 -210 -938 -453 -132 -2348 -125 -1142 154 -1668 1671 901 3931 3198 2151 2246 371 2364 -252 936 123 220 445 -606 336 -800 242 168 1809 254 -408 -33 -2398 -907 68 258 -2218 328 30 -3639 -1713 -4102 30 -4164 -1215 431 -2066 -576 -1487 900000 -896 2607 -1304 1215 -66 -709 426 -233 900000 -3900 900000 -1218 -351 -780 -953 1134 -297 941 897 295 -668 585 1184 -196 1573 -217 1693 1234 1459 1489 1043 855 264 1906 1447 2426 1928 2660 2976 2424 2444 61 2717 725 2328 713 1015 2247 1181 2846 690 3255 2605 3875 3612 4033 2751 1659 2842 -1547 1476 -3140 1737 987 2377 2701 -59 3138 2451 3437 105 3808 1831 -487 177 -1674 -1621 -2802 -1522 -2351 3 236 -2484 -551 -2461 -1255 -3172 -1028 -4279 -3580 -956 -2355 1270 -2507 -243 -1222 -617 -181 -3202 -163 -1529 214 -2485 2447 1273 5017 3903 2584 2627 431 2654 -316 1400 221 455 1015 -1516 903 -2342 737 517 5498 772 -1170 -85 -5794 -2054 SS 20240205T125337.1Z 8801.537234 162 1 49.70 2 81.41 121.33 70.92 182.03 0.00 1 0.00 1 0 25 7.443e-01 1.439e-02 2.535e-01 3.678e-03 9.555201e-01 2.078853e-03 1.040478e-02 -6.000000e+00 4.164823e-01 224.34 -2.00 3.55 -2.00 322.26 0.00e+00 7.620553e-03 1.165458e-03 2.249414e-03 -6.000000e+00 1.818781e-02 273.01 -2.00 20.00 -2.00 321.84 0.00e+00 6.319 0.005 302.00 328.00 3 -7.1057e-01 7.7773e-03 8.1816e-02 -6.0000e+00 1.0299e+00 6.0732e-01 1.2963e-02 5.6479e-02 -6.0000e+00 1.1238e+00 -7.8861e-01 1.5038e-02 3.2678e-02 -6.0000e+00 6.6745e-01 3.0596e-01 6.7392e-03 1.3640e-02 -6.0000e+00 2.8255e-01 7.8484e-04 -1.0078e-03 9.7080e-05 1.9826e-04 -6.0000e+00 1.9963e-02 -3.6947e-03 1.4538e-06 12 8 8 10 0 0 -1.46 22.77 0.30 -0.00369 -0.01127 297 62 1 5 0 167.320 26.41 20.01 22.77 1.68 26.7 896.68 -284969 -171664 -209936 -237080 900000 -288127 -182269 -279153 -154354 -214004 -224126 -109449 -240746 12106 -108106 -67426 -86444 -61105 -67849 -115442 -24125 -115116 54791 -126319 26253 -118403 -89488 -47309 -119392 -61413 -95221 13245 -38126 -18387 -6074 -42607 -9510 -28520 73613 -7512 25543 5986 29534 19031 13213 31878 4523 27838 -7222 31776 12421 34048 11759 27456 22455 7827 30053 1770 22947 3256 19180 19173 10099 22126 11965 24389 8090 13107 11580 13244 10589 8529 10540 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