File name: Pandora183s1_LondonderryNH_20240224_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240225T050342.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240224_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240224T125946.8Z 8820.541514 282 1 21.02 2 75.43 118.33 102.22 299.24 0.00 1 0.00 1 0 25 4.866e-01 3.407e-02 3.674e-01 2.277e-02 6.482815e-01 1.203738e-02 9.347136e-03 -6.000000e+00 2.749629e-01 225.11 -2.00 3.55 -2.00 321.12 0.00e+00 8.759916e-03 4.751508e-03 7.914925e-03 -6.000000e+00 1.179352e-02 273.70 -2.00 20.00 -2.00 320.64 0.00e+00 3.895 0.001 302.00 328.00 3 4.1966e+00 3.7059e-02 6.0017e-02 -6.0000e+00 6.8264e-01 5.4936e-01 4.5814e-02 5.0265e-02 -6.0000e+00 7.4582e-01 -7.5875e-01 3.8410e-02 2.7586e-02 -6.0000e+00 4.4095e-01 3.3232e-01 1.9270e-02 9.4693e-03 -6.0000e+00 1.8479e-01 7.1822e-05 -2.0154e-03 6.4212e-04 2.0306e-04 -6.0000e+00 1.3078e-02 -1.1318e-03 -1.5113e-04 12 9 9 12 1 1 99.97 22.90 0.59 -0.00113 -0.01628 5 3 1 5 0 3501.080 26.51 20.00 22.90 6.60 27.5 939.76 -85762 -52903 77625 -11452 -71444 -105164 -119807 900000 -67006 -114247 -86554 -141386 -81220 78075 900000 35018 -48648 3512 104069 900000 64259 121859 -50052 -12908 88976 109503 133488 -20028 24328 3956 96176 75864 29954 -30182 43013 200255 11367 181213 87709 54982 81078 13721 24209 54822 88417 36244 31521 -27519 21856 250 22772 12802 33073 47954 15499 14052 22096 10195 9791 25096 36528 37955 10409 23123 12966 16435 12687 1776 24353 12494 2842 10010 572 2857 -4089 -807 2404 -3062 -8977 6753 -673 -2975 -69 -2181 -4564 -8 -3396 -8112 1951 1597 -2248 -4713 -9268 -1281 -674 -5061 2024 -4571 -547 -2857 -4063 574 -732 -4309 -4950 171 -1315 142 -1619 -576 2 3423 317 323 -1273 -952 -786 69 2875 2610 3919 1970 1561 3764 -1734 4227 -1998 2689 -972 2652 751 985 116 -901 -1555 -617 1136 -15 138 -10 -638 -1198 -1859 -3661 -1897 1723 -274 -2683 -5252 -6648 900000 -2355 -6551 -3682 -10722 -4056 1733 900000 1036 -3689 169 2310 900000 1783 2705 -3981 -716 1975 2430 2963 -1253 933 192 2135 2449 1753 -3471 2256 4445 780 4022 3716 3772 4744 1661 2735 4646 5352 3730 3434 -5497 2734 40 3170 2170 4938 6579 3065 2864 4191 2139 1976 4203 5528 6127 2499 5505 3637 4344 3353 527 6191 4084 1130 3858 239 1095 -1526 -285 752 -1006 -3447 2623 -330 -1703 -42 -1433 -3252 -6 -2668 -6877 1494 1184 -1611 -3211 -6274 -813 -473 -4302 1859 -5154 -650 -3507 -4734 572 -667 -4045 -5020 174 -1433 163 -2066 -816 3 5485 526 515 -1946 -1384 -1143 104 4466 4234 6219 3060 2339 5321 -2482 5479 -2652 3534 -1492 4432 1399 1944 240 -2000 -3699 -1523 2802 -38 346 -23 -1432 -2526 -3797 SS 20240224T131702.5Z 8820.553502 292 1 0.67 2 72.69 121.71 104.90 302.41 0.00 1 0.00 1 0 17 3.251e-01 1.337e-02 2.639e-01 1.129e-02 5.862605e-01 5.740701e-03 6.897066e-03 -6.000000e+00 1.846131e-01 225.11 -2.00 3.55 -2.00 319.88 0.00e+00 5.894669e-03 1.784837e-03 1.352653e-03 -6.000000e+00 7.940253e-03 273.71 -2.00 20.00 -2.00 319.37 0.00e+00 3.313 0.001 302.00 328.00 3 1.3955e+00 1.6242e-02 4.4618e-02 -6.0000e+00 4.5900e-01 5.2167e-02 1.9730e-02 3.0265e-02 -6.0000e+00 5.0114e-01 -7.5956e-02 1.8187e-02 1.7719e-02 -6.0000e+00 2.9509e-01 3.2486e-02 9.5101e-03 8.3160e-03 -6.0000e+00 1.2444e-01 2.3992e-03 -7.0902e-04 3.0104e-04 7.9343e-05 -6.0000e+00 8.8149e-03 -5.3642e-03 -3.1523e-06 12 9 9 12 1 1 999.00 22.91 0.46 -0.00536 -0.01069 1 31 1 5 0 330.540 26.51 20.01 22.91 7.06 27.6 943.31 -26110 900000 -30472 201272 -144174 116352 -75368 900000 900000 -52102 -34243 -120366 89215 -84481 -24362 -18135 -13827 126282 -36236 27732 -42970 -11758 -17409 290 -22341 -9577 22720 -10211 6401 -27412 6840 -13940 15616 6766 -8260 10403 -4486 -8605 -5078 -8216 -7108 3492 4116 478 14063 -1161 5604 4328 1407 2860 4713 3984 4118 2664 1199 3475 -2244 77 1089 766 3417 4385 6830 2679 1269 1587 -3310 -1573 -1548 1336 1000 188 -2822 159 -1139 234 3541 -1988 1560 -5088 -1164 569 461 -326 -505 -1024 1077 -1131 -766 1190 -83 448 1160 -1914 406 -2303 556 776 123 -225 -972 -1138 -970 1897 -2026 -2358 -722 -649 321 -298 1569 -1147 965 86 -26 421 86 1428 178 746 -373 1138 636 1165 1016 -893 -468 653 452 85 -219 -782 -255 -22 -250 -692 -38 1112 438 332 -831 -605 -264 -287 900000 -335 2214 -4182 1280 -1055 900000 900000 -782 -490 -3973 982 -3126 -697 -599 -502 1389 -1993 854 -2789 -556 -881 13 -1352 -537 950 -584 303 -1900 391 -1181 1151 603 -836 835 -444 -1032 -715 -1437 -1272 669 829 94 2707 -243 1233 990 312 658 1164 1108 1252 890 431 1262 -887 30 405 280 1247 1728 2978 1260 646 787 -1663 -783 -832 802 671 124 -1903 107 -714 130 1740 -1021 845 -3471 -824 451 402 -282 -464 -1010 1097 -1134 -767 1210 -80 396 1035 -1648 377 -2356 637 950 166 -305 -1247 -1403 -1085 2061 -2462 -2856 -904 -863 431 -449 2407 -1904 1562 134 -41 618 126 2168 274 1194 -601 1742 997 1752 1463 -1258 -670 953 696 139 -390 -1403 -475 -40 -496 -1382 -77 2256 892 682 -1626 -1170 -492 SS 20240224T132146.3Z 8820.556785 295 1 23.71 2 71.95 122.66 105.62 303.30 0.00 1 0.00 1 0 17 3.027e-01 1.064e-02 2.213e-01 6.219e-03 5.688469e-01 3.210879e-03 6.633254e-03 -6.000000e+00 1.710351e-01 225.11 -2.00 3.55 -2.00 320.51 0.00e+00 5.015742e-03 1.190733e-03 1.693946e-03 -6.000000e+00 7.546893e-03 273.71 -2.00 20.00 -2.00 320.01 0.00e+00 3.186 0.001 302.00 328.00 3 3.4896e+00 9.5559e-03 4.3281e-02 -6.0000e+00 4.2572e-01 9.3107e-02 1.2126e-02 2.9838e-02 -6.0000e+00 4.6459e-01 -6.0719e-02 1.2142e-02 1.8514e-02 -6.0000e+00 2.7386e-01 1.6592e-02 6.1720e-03 8.7380e-03 -6.0000e+00 1.1524e-01 3.3059e-04 1.5750e-04 1.7530e-04 9.1416e-05 -6.0000e+00 8.0555e-03 -6.3970e-03 1.5366e-04 12 9 9 12 1 1 99.99 22.91 0.40 -0.00640 -0.00521 12 6 1 5 0 1822.750 26.51 20.00 22.91 7.16 27.6 944.44 -75369 -87061 93937 -55079 -108010 -70750 60405 -51535 900000 900000 -65656 -113372 213347 -17657 -17430 -21568 -35144 -15842 31416 -19506 -8759 -20877 -9709 -6780 29580 -37702 -46257 -29847 5432 -12593 -1182 16601 -7837 18871 -16228 7701 -10884 -6572 -4215 -12715 5456 2846 2272 -713 3923 3754 3427 -6304 -5488 1833 -3537 9114 13 5798 3120 -2072 6024 15 1530 2537 3145 2400 3384 2922 6664 861 1987 -4870 1649 2379 1455 1735 -247 2802 -2601 -3517 -2193 -3320 -1709 -2686 1606 -2077 -2917 -1377 -1311 543 1379 1170 1607 1713 197 -325 -1332 -1331 -1151 -2498 785 1423 483 -1466 -224 -836 -1036 -5 -536 -1576 -1140 -414 -507 350 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