File name: Pandora183s1_LondonderryNH_20240302_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240303T050344.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240302_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240302 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240302T140240.7Z 8827.585194 319 1 2.26 2 63.60 130.01 89.22 234.82 0.00 1 0.00 1 0 17 2.418e-02 7.772e-03 1.658e-02 3.813e-03 3.346786e-01 1.888010e-03 4.003274e-03 -6.000000e+00 1.358227e-02 225.40 -2.00 3.55 -2.00 317.71 0.00e+00 5.475218e-04 3.006586e-04 3.078797e-04 -6.000000e+00 5.840507e-04 274.20 -2.00 20.00 -2.00 317.14 0.00e+00 2.237 0.000 302.00 328.00 3 2.3174e+00 5.0000e-03 2.7909e-02 -6.0000e+00 3.3665e-02 2.0997e-02 5.6448e-03 1.7033e-02 -6.0000e+00 3.6693e-02 -1.5869e-03 3.5718e-03 8.4722e-03 -6.0000e+00 2.1794e-02 -3.7660e-03 1.8291e-03 2.4412e-03 -6.0000e+00 9.2036e-03 3.7394e-03 -5.1374e-05 1.0677e-04 2.5198e-05 -6.0000e+00 6.3726e-04 -3.3605e-03 9.3589e-05 12 9 1 12 1 1 -144.06 22.93 0.21 -0.00336 -0.00375 4 23 1 5 0 451.420 26.51 20.00 22.93 12.26 28.2 985.46 -6668 -5651 -143 -5885 -14650 -7787 9653 -5854 -6981 -4317 -1917 -4283 -2629 -14 1148 488 1664 1361 2176 2576 3298 375 1771 1461 356 383 -589 -2352 -2523 71 -114 916 3311 -1225 -2444 -3485 -4708 -1962 -1082 -1610 -1041 -570 229 113 26 338 -396 -1109 -968 -35 529 601 1384 1208 536 874 1440 -154 -234 810 662 1387 2028 2432 1079 -370 92 -1660 1213 823 1074 786 1107 1074 -576 -299 -210 -2389 -1742 -1753 -1477 -275 -2465 -1716 -856 -649 156 123 1546 1000 608 120 -880 -316 -690 -366 359 836 372 -286 -668 -1260 -1102 -266 -715 -1133 -253 -645 -55 737 775 505 442 265 -100 -169 153 607 474 41 294 231 466 545 455 274 -492 1012 102 -300 -555 -655 -89 -139 362 -39 159 382 193 -32 -189 -447 -644 -464 -448 -11 -486 -1182 -541 582 -461 -633 -414 -182 -421 -284 -2 166 81 294 253 423 520 683 80 374 328 79 89 -141 -549 -605 16 -28 244 866 -358 -692 -947 -1375 -646 -427 -698 -503 -291 120 61 14 181 -213 -590 -509 -18 292 360 812 754 351 586 983 -107 -159 536 448 998 1480 1920 886 -290 72 -1280 959 690 929 718 1011 946 -514 -240 -163 -1801 -1361 -1443 -1380 -264 -2613 -1776 -936 -760 181 147 1831 1152 694 126 -913 -316 -736 -407 444 1080 489 -376 -876 -1516 -1312 -320 -884 -1493 -346 -877 -79 1067 1196 800 682 383 -141 -237 213 829 694 60 441 340 703 788 626 381 -656 1342 147 -446 -830 -1014 -141 -228 598 -68 283 694 335 -57 -322 -730 -1086 SS 20240302T140720.8Z 8827.588435 322 1 19.16 2 62.95 131.08 89.91 235.59 0.00 1 0.00 1 0 25 2.038e-02 7.201e-03 5.880e-03 1.118e-03 3.282430e-01 5.553575e-04 3.960539e-03 -6.000000e+00 1.144385e-02 225.40 -2.00 3.55 -2.00 318.13 0.00e+00 1.336600e-03 9.810505e-05 4.262197e-04 -6.000000e+00 4.921214e-04 274.20 -2.00 20.00 -2.00 317.54 0.00e+00 2.187 0.000 302.00 328.00 3 2.0506e+00 1.4812e-03 2.7380e-02 -6.0000e+00 2.8364e-02 2.4781e-02 1.6758e-03 1.6804e-02 -6.0000e+00 3.0917e-02 -8.6920e-04 1.1012e-03 8.4685e-03 -6.0000e+00 1.8364e-02 -6.0467e-03 5.7296e-04 2.6185e-03 -6.0000e+00 7.7541e-03 5.1462e-03 -1.5279e-04 3.1875e-05 2.7378e-05 -6.0000e+00 5.3698e-04 -3.4098e-03 6.2494e-05 12 9 1 12 1 1 99.63 22.93 0.28 -0.00341 -0.00456 57 31 1 5 0 330.260 26.51 19.99 22.93 12.61 28.3 988.11 -6127 -2100 -5404 -5436 -8229 -4270 -6695 -5176 -5233 -6091 -5843 -5882 -4123 -3797 485 -1277 -1520 1359 -104 1395 163 1118 247 1493 -276 -1003 -439 -2721 -1145 -1802 1156 -278 819 -571 -4089 -2469 -4273 -1187 -807 -53 -789 -731 -466 -512 695 337 388 -19 -279 6 747 983 916 1503 724 1317 838 327 361 161 1380 1676 2228 2506 1159 110 -428 -987 911 773 652 1090 387 643 62 -344 -1291 -1995 -898 -1278 -1349 -1167 -2310 -1646 -945 -611 -347 360 861 853 376 86 -606 -809 -366 -456 435 689 319 -506 -404 -1455 -967 -444 -1328 -1131 -774 -568 69 664 994 505 544 182 -136 79 238 138 491 392 126 615 884 535 622 -253 -31 653 281 -57 -184 -497 -249 -150 -122 -48 304 576 111 -204 -180 -591 -698 -321 -122 -343 -372 -519 -238 -393 -334 -383 -486 -470 -478 -370 -401 58 -177 -227 207 -17 234 29 193 43 273 -55 -210 -93 -565 -219 -339 225 -61 196 -148 -1049 -591 -1106 -345 -282 -20 -333 -327 -216 -242 325 159 182 -9 -128 3 360 513 512 885 448 829 542 213 230 101 875 1136 1513 1842 885 80 -315 -710 678 601 562 983 353 563 51 -255 -951 -1403 -652 -967 -1163 -1119 -2230 -1655 -1006 -695 -417 444 1061 1017 418 88 -619 -802 -383 -490 520 851 424 -675 -505 -1803 -1113 -519 -1701 -1423 -1015 -780 100 1026 1522 795 830 280 -193 105 314 190 722 613 202 962 1338 780 862 -364 -42 891 385 -85 -291 -814 -417 -243 -210 -87 564 1088 199 -378 -319 -1010 -1168 SS 20240302T141212.8Z 8827.591815 325 1 3.03 2 62.29 132.21 90.63 236.39 0.00 1 0.00 1 0 17 2.131e-02 8.266e-03 1.344e-02 3.352e-03 3.186286e-01 1.664298e-03 3.835208e-03 -6.000000e+00 1.196509e-02 225.40 -2.00 3.55 -2.00 317.59 0.00e+00 7.144889e-04 2.560644e-04 3.135648e-04 -6.000000e+00 5.145611e-04 274.20 -2.00 20.00 -2.00 317.01 0.00e+00 2.139 0.000 302.00 328.00 3 2.4984e+00 4.3951e-03 2.6654e-02 -6.0000e+00 2.9656e-02 1.8596e-02 4.9556e-03 1.6229e-02 -6.0000e+00 3.2327e-02 2.9528e-03 3.0876e-03 8.0901e-03 -6.0000e+00 1.9201e-02 -5.4228e-03 1.5706e-03 2.3451e-03 -6.0000e+00 8.1064e-03 3.5053e-03 -3.4965e-04 9.4016e-05 2.4507e-05 -6.0000e+00 5.6154e-04 -3.2370e-03 2.8529e-05 12 9 1 12 1 1 85.53 22.92 0.26 -0.00324 -0.00586 5 21 1 5 0 503.540 26.51 20.00 22.92 13.11 28.4 992.26 -5500 -2662 5378 -10071 -2493 -2904 -4788 3054 -5294 399 -10046 -2341 -8171 766 -503 2037 -738 -801 62 24 3527 -2614 1260 -160 12 -383 -538 2906 -3205 -3424 -510 991 860 -796 -4067 -5550 -2775 -1644 712 -234 74 216 -152 -518 733 478 -221 1037 -706 293 1100 1701 1598 -90 1154 1239 830 75 -671 571 56 1805 1871 2826 699 112 -1037 -481 725 570 1088 1089 1103 389 -29 -919 -1699 -1987 -1010 -1089 -1565 -1642 -2948 -1484 -476 -924 -194 341 976 303 1155 106 -865 193 -1019 -339 24 1028 497 -112 -375 -1237 -787 -365 -819 -1405 -956 -470 82 852 766 731 272 133 -120 -10 20 169 570 141 747 375 749 912 396 -68 -303 1194 -18 -316 -214 -546 -413 -104 15 -239 529 418 280 17 -201 -883 -674 -422 -228 450 -961 -197 -213 -368 243 -519 40 -1130 -246 -1015 102 -80 358 -143 -163 13 5 776 -608 284 -39 3 -95 -135 745 -814 -848 -130 275 239 -240 -1211 -1591 -821 -557 285 -103 37 112 -82 -286 399 262 -121 551 -377 156 611 1018 1023 -57 756 831 572 52 -460 381 39 1300 1477 2223 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