File name: Pandora183s1_LondonderryNH_20240304_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240426T122709.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240304_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240304T161957.4Z 8829.680526 333 1 49.83 2 49.65 167.85 96.64 236.04 0.00 1 0.00 1 0 17 1.586e-02 7.944e-03 6.182e-03 1.939e-03 2.351919e-01 9.603737e-04 2.846527e-03 -6.000000e+00 8.909490e-03 225.49 -2.00 3.55 -2.00 317.37 0.00e+00 1.013898e-03 1.382085e-04 2.875409e-04 -6.000000e+00 3.832208e-04 274.34 -2.00 20.00 -2.00 316.79 0.00e+00 1.542 0.000 302.00 328.00 3 4.1838e+00 2.5257e-03 1.9387e-02 -6.0000e+00 2.2086e-02 4.8565e-02 2.8448e-03 1.1950e-02 -6.0000e+00 2.4071e-02 -2.5531e-03 1.7323e-03 5.9851e-03 -6.0000e+00 1.4298e-02 -5.0895e-03 8.5904e-04 1.8185e-03 -6.0000e+00 6.0373e-03 1.3068e-03 1.4001e-04 5.5573e-05 1.8331e-05 -6.0000e+00 4.1790e-04 -3.2392e-03 9.3990e-05 11 8 0 10 0 0 99.98 22.87 0.19 -0.00324 -0.00219 33 7 1 5 0 1509.700 26.51 20.01 22.87 18.95 28.9 1035.13 -1332 -4304 518 -3911 -260 -8191 -5359 1749 -3110 -2880 -3371 -5849 -3574 -232 -546 765 -356 418 1879 2088 76 1436 1806 2314 158 703 -352 -876 -348 -519 272 1047 1417 83 -2750 -3948 -2382 -1607 -424 -266 -919 -684 -478 -168 -22 253 -723 -327 -250 11 267 548 746 807 808 773 1013 70 860 353 875 1645 1533 3176 598 -76 -719 -1207 1015 632 746 872 681 822 336 -836 -1328 -1935 -1221 -1587 -1407 -1273 -2400 -1258 -807 -615 -206 244 1287 484 512 3 -982 -680 -965 -319 297 1239 93 -60 -520 -1303 -918 -505 -1365 -1369 -422 -713 396 709 1039 586 653 249 -506 -183 84 -101 540 522 313 845 930 512 655 -309 -196 793 -43 -145 -180 -476 -436 -50 -124 194 366 551 177 -96 -75 -840 -881 -143 -536 64 -488 -28 -860 -556 187 -392 -388 -454 -796 -518 -37 -101 155 -77 92 424 485 19 341 427 568 42 192 -98 -257 -94 -134 72 297 433 27 -872 -1195 -750 -577 -180 -133 -466 -363 -261 -93 -14 152 -432 -189 -140 6 153 336 482 548 566 551 733 51 609 248 625 1245 1261 2751 488 -64 -553 -892 764 540 704 784 616 790 304 -688 -984 -1347 -865 -1262 -1257 -1254 -2559 -1384 -857 -701 -248 301 1580 579 568 3 -1003 -661 -983 -355 365 1517 123 -78 -640 -1629 -1075 -606 -1797 -1736 -554 -979 564 1068 1643 942 1007 358 -669 -248 112 -142 734 760 468 1242 1329 774 938 -425 -255 1020 -59 -214 -280 -759 -706 -76 -200 327 634 973 314 -168 -126 -1367 -1405 SS 20240304T162457.6Z 8829.684000 336 1 5.80 2 49.47 169.47 97.38 236.80 0.00 1 0.00 1 0 17 1.171e-02 7.904e-03 4.778e-03 2.210e-03 2.331641e-01 1.100361e-03 2.834668e-03 -6.000000e+00 6.580402e-03 225.49 -2.00 3.55 -2.00 316.33 0.00e+00 1.059238e-03 1.224972e-04 1.287890e-04 -6.000000e+00 2.830606e-04 274.34 -2.00 20.00 -2.00 315.77 0.00e+00 1.536 0.000 302.00 328.00 3 3.0728e+00 2.8503e-03 1.9264e-02 -6.0000e+00 1.6312e-02 3.9197e-02 3.1953e-03 1.1857e-02 -6.0000e+00 1.7779e-02 -7.6073e-04 1.8628e-03 5.8851e-03 -6.0000e+00 1.0560e-02 -5.9932e-03 8.7458e-04 1.7769e-03 -6.0000e+00 4.4585e-03 4.0191e-03 -1.4447e-04 6.1927e-05 1.8950e-05 -6.0000e+00 3.0869e-04 -2.3784e-03 8.6738e-05 12 9 1 12 1 1 32.54 22.87 0.23 -0.00238 -0.00346 8 16 1 5 0 643.440 26.51 19.99 22.87 19.09 28.8 1035.26 -9 -693 -340 -1361 -3793 -2331 -2740 1713 -1459 -571 -2970 -2752 -1079 -2124 1389 -685 1324 954 -48 1503 1567 1785 1336 2025 436 439 -1390 -151 -186 -458 2129 547 2230 -116 -2841 -2206 -3906 -1745 -750 -39 -443 -492 -725 -267 81 -478 -178 -756 -1109 -671 951 -151 974 1358 535 1157 658 492 -32 535 799 1426 1640 2060 573 -149 -165 -1094 792 955 572 1285 810 732 279 -179 -1394 -1928 -924 -1151 -1235 -1734 -2164 -1583 -640 -368 -202 540 551 926 427 -62 -859 -251 -635 -536 450 711 285 -178 -595 -1677 -988 -398 -981 -1004 -916 -543 254 581 992 718 764 236 -164 -253 -9 244 362 598 7 911 648 396 816 8 123 928 65 -137 -269 -496 -425 -242 192 -196 453 574 76 160 -156 -924 -833 -2 -134 -68 -267 -674 -372 -446 295 -291 -121 -641 -584 -245 -559 404 -206 411 305 -16 513 550 619 464 729 168 176 -573 -58 -66 -173 811 207 899 -50 -1200 -873 -1659 -834 -390 -24 -299 -323 -491 -183 55 -326 -119 -535 -766 -456 661 -105 708 1032 423 924 538 402 -26 423 644 1218 1411 1887 539 -131 -142 -909 673 851 565 1323 843 738 264 -165 -1166 -1515 -736 -1027 -1153 -1798 -2250 -1708 -729 -449 -245 671 688 1115 511 -68 -919 -255 -676 -585 540 882 378 -235 -740 -2061 -1135 -467 -1260 -1282 -1219 -752 344 833 1492 1097 1122 323 -219 -316 -12 313 498 827 10 1275 940 551 1073 11 157 1170 88 -186 -385 -728 -633 -352 294 -317 706 913 122 250 -249 -1439 -1269 SS 20240304T162953.5Z 8829.687425 339 1 49.42 2 49.32 171.07 98.11 237.55 0.00 1 0.00 1 0 17 1.278e-02 7.218e-03 3.245e-03 1.063e-03 2.350333e-01 5.246487e-04 2.835758e-03 -6.000000e+00 7.181308e-03 225.49 -2.00 3.55 -2.00 317.20 0.00e+00 8.802640e-04 7.163832e-05 1.899700e-04 -6.000000e+00 3.088645e-04 274.34 -2.00 20.00 -2.00 316.59 0.00e+00 1.531 0.000 302.00 328.00 3 3.2661e+00 1.3769e-03 1.9291e-02 -6.0000e+00 1.7802e-02 4.4535e-02 1.5494e-03 1.1928e-02 -6.0000e+00 1.9401e-02 -3.0925e-03 9.3404e-04 5.9454e-03 -6.0000e+00 1.1524e-02 -5.8344e-03 4.5945e-04 1.7899e-03 -6.0000e+00 4.8666e-03 3.3148e-03 2.4461e-04 3.0442e-05 1.8877e-05 -6.0000e+00 3.3680e-04 -3.3989e-03 1.2272e-04 11 8 0 10 0 0 99.93 22.86 0.36 -0.00340 -0.00156 86 18 1 5 0 574.490 26.51 20.00 22.86 19.05 28.8 1034.93 -1506 -429 -189 -4486 -4419 -2955 -1349 -367 -575 -2345 -3780 -4268 -1870 -1734 276 452 -199 1009 475 2256 822 769 1461 1063 438 414 -134 -1422 -699 -1050 424 1727 1795 -24 -3371 -3413 -3384 -2225 -556 -617 -530 -566 -324 -491 214 356 -348 -239 -698 -220 437 677 1026 1153 480 766 1033 378 263 277 1074 1654 1995 2303 513 -243 -610 -1133 635 767 670 731 564 940 399 -181 -829 -1892 -872 -1369 -1437 -1281 -2522 -1446 -752 -346 -185 424 915 758 611 -41 -984 -441 -542 -499 218 708 254 -268 -553 -1198 -768 -390 -1218 -1182 -779 -794 179 525 961 507 423 123 -269 -2 -8 57 654 411 303 638 651 379 706 -171 32 736 312 -12 -198 -447 -350 154 2 -11 243 569 45 -94 -138 -767 -718 -167 -53 -24 -579 -504 -303 -138 -41 -73 -324 -527 -649 -302 -320 57 95 -44 250 123 592 225 208 393 299 131 129 -42 -432 -195 -281 116 501 563 -8 -1107 -1058 -1108 -828 -244 -319 -303 -341 -182 -308 133 220 -214 -142 -405 -126 258 426 681 803 348 562 770 283 193 201 790 1289 1530 1884 431 -191 -483 -861 494 675 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