File name: Pandora183s1_LondonderryNH_20240322_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240426T132437.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240322_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240322 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240322T112525.8Z 8847.475993 230 1 49.54 2 83.30 94.98 104.93 305.29 0.00 1 0.00 1 0 25 5.387e-01 2.408e-02 4.217e-01 1.617e-02 1.096376e+00 9.601243e-03 1.172049e-02 -6.000000e+00 3.075992e-01 226.50 -2.00 3.55 -2.00 322.67 0.00e+00 6.256391e-03 5.396534e-03 1.813005e-03 -6.000000e+00 1.345749e-02 275.89 -2.00 20.00 -2.00 322.28 0.00e+00 7.816 0.009 302.00 328.00 3 -4.3574e-01 3.7875e-02 9.8445e-02 -6.0000e+00 7.6537e-01 1.7486e+00 4.8884e-02 6.2619e-02 -6.0000e+00 8.3401e-01 -2.2074e+00 4.0011e-02 3.2636e-02 -6.0000e+00 4.9207e-01 8.4159e-01 1.9814e-02 1.2292e-02 -6.0000e+00 2.0822e-01 1.0471e-04 -1.4271e-03 4.2305e-04 1.7790e-04 -6.0000e+00 1.4600e-02 -1.5839e-03 9.6521e-06 12 8 8 10 0 0 -7.19 23.03 0.45 -0.00158 -0.01231 87 18 1 5 0 569.250 26.62 19.99 23.03 -0.46 27.1 891.03 -9943 900000 -28586 173052 -69990 -26949 900000 -30086 900000 -142355 62092 -33297 -61991 -10747 -14925 119517 -203 110598 32413 175746 10369 1996 -39384 -33491 1461 -61589 134782 -40173 900000 3892 900000 73693 -3445 102732 4509 4403 -1307 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1167 1586 848 3559 1960 1814 1983 863 -1224 21 -1743 276 -710 -1902 -992 -3899 -4207 -1597 -6331 -378 -6016 -1242 -950 -2777 -1956 -806 1373 -792 1783 -3497 -1068 -2657 -2186 273 -558 3206 2407 6271 3231 2423 1076 904 893 -1191 2882 -1541 557 1722 -118 26 -1660 1899 1640 2308 -11 -1586 936 -2276 -4972 SS 20240322T113629.2Z 8847.483671 233 1 49.59 2 81.28 96.88 106.54 307.40 0.00 1 0.00 1 0 25 6.185e-01 1.757e-02 2.312e-01 4.403e-03 9.443398e-01 2.542807e-03 1.041676e-02 -6.000000e+00 3.533943e-01 226.50 -2.00 3.55 -2.00 322.31 0.00e+00 8.799020e-03 1.487041e-03 2.468141e-03 -6.000000e+00 1.611952e-02 275.89 -2.00 20.00 -2.00 321.88 0.00e+00 6.235 0.005 302.00 328.00 3 -3.5523e-01 9.7836e-03 8.1346e-02 -6.0000e+00 8.8050e-01 7.3479e-01 1.5129e-02 5.5686e-02 -6.0000e+00 9.6072e-01 -1.0155e+00 1.6420e-02 3.0839e-02 -6.0000e+00 5.6600e-01 4.0710e-01 7.3730e-03 1.3419e-02 -6.0000e+00 2.3874e-01 5.8126e-04 -1.1403e-03 1.1734e-04 2.0937e-04 -6.0000e+00 1.6689e-02 -1.8768e-03 9.8982e-06 12 8 8 10 0 0 3.21 23.03 0.41 -0.00188 -0.01045 225 47 1 5 0 220.350 26.62 20.02 23.03 0.48 27.2 898.20 -230576 900000 -160369 -178318 -125397 -241357 900000 -267220 900000 -137509 900000 -194170 -188976 -10210 -149707 900000 -108110 50417 -59305 -89045 -45041 -98770 -17514 -111179 45221 -88362 122729 -55225 -35133 -29825 -38446 77490 -46979 65363 -14869 20527 -25139 11349 31433 8173 63000 2908 45480 11065 43464 22297 19654 81559 17396 50089 29910 41837 25267 35425 40223 19123 34867 19755 30417 3064 34304 17867 28837 27651 19885 24229 8826 19401 10700 21008 13243 12575 12175 3274 11039 -3808 7573 -7779 5357 -1653 354 2942 -454 1597 -82 3984 -577 2288 2068 366 615 -3050 -217 -7270 -1856 -4328 89 148 -1443 -212 -2877 -1020 -3396 -1769 -3037 -3833 -1317 -2850 38 -614 433 -471 -257 -665 -1903 -312 -896 813 357 1416 797 1858 2679 1438 1750 -337 934 483 445 172 497 429 -711 192 -495 172 160 830 379 -223 -30 -1226 -1209 -3500 900000 -1588 -2231 -807 -4400 900000 -6400 900000 -983 900000 -2707 -3243 -44 -3157 900000 -2203 234 -890 -1846 -596 -2118 -163 -2742 265 -1999 526 -861 -438 -384 -675 544 -1374 688 -336 304 -608 217 588 229 1155 104 1117 393 1119 722 674 1590 692 1563 1283 1811 1429 1976 2274 1380 2189 1418 1862 235 2134 1433 2412 2740 2354 2785 1193 2480 1652 3388 2562 2552 2429 660 1837 -648 1075 -1342 940 -383 97 920 -164 604 -33 1649 -261 1033 932 161 253 -1227 -84 -3206 -902 -2594 61 120 -1322 -196 -2563 -789 -2377 -1187 -2201 -2968 -1053 -2517 36 -698 561 -675 -379 -978 -2732 -428 -1250 1172 545 2192 1202 2612 3559 1877 2205 -421 1125 627 680 308 1004 947 -1701 491 -1366 450 425 2427 1101 -617 -77 -2886 -2726 SS 20240322T115001.8Z 8847.493077 238 1 49.64 2 78.82 99.25 108.45 310.07 0.00 1 0.00 1 0 17 7.164e-01 9.103e-03 9.634e-02 1.689e-03 7.872939e-01 9.113599e-04 9.016216e-03 -6.000000e+00 4.039830e-01 226.50 -2.00 3.55 -2.00 321.67 0.00e+00 6.018892e-03 4.745745e-04 4.076343e-03 -6.000000e+00 1.742231e-02 275.89 -2.00 20.00 -2.00 321.23 0.00e+00 4.981 0.002 302.00 328.00 3 -4.0248e-01 3.2002e-03 6.6654e-02 -6.0000e+00 1.0033e+00 1.7326e-01 4.9745e-03 4.7273e-02 -6.0000e+00 1.0925e+00 -2.1521e-01 5.7052e-03 2.9900e-02 -6.0000e+00 6.4896e-01 7.4230e-02 2.6289e-03 1.2243e-02 -6.0000e+00 2.7372e-01 2.4571e-03 -4.7377e-04 4.5020e-05 1.7468e-04 -6.0000e+00 1.8888e-02 -2.2064e-03 3.4443e-05 11 8 0 10 0 0 15.73 23.06 0.28 -0.00221 -0.00577 482 100 1 5 0 102.960 26.73 20.00 23.06 1.45 27.3 904.87 -287666 -224520 -233615 -215502 -231255 -188101 -200739 -231827 -204486 -244358 -184824 -198803 -150715 -80567 -116129 -88684 -77610 -67355 -77297 -23284 -75637 -57137 -43813 -70615 -54827 -62040 -53633 -65829 -44210 -48438 -24390 -18653 -19777 -10656 -19875 -11473 -31277 -5445 -4574 4096 2927 2217 4713 -533 1567 -108 6994 3656 3198 4905 3205 6594 4572 8626 6937 8036 6925 3723 2367 -974 3249 1542 6458 7488 5453 4496 3733 2971 2211 4061 3267 3934 2264 639 402 -2003 -2069 -4050 -1971 -2047 -672 -931 -1537 -1061 -982 48 195 756 1121 1188 631 -741 -2042 -2505 -1281 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