File name: Pandora183s1_LondonderryNH_20240417_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240426T144919.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240417_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240417T104243.9Z 8873.446342 159 1 49.89 2 83.14 81.71 113.68 334.60 0.00 1 0.00 1 0 17 5.388e-01 2.268e-02 4.495e-01 1.567e-02 1.181636e+00 9.512787e-03 1.240515e-02 -6.000000e+00 3.079885e-01 228.56 -2.00 3.55 -2.00 322.76 0.00e+00 1.898174e-03 5.782731e-03 5.083410e-03 -6.000000e+00 1.379943e-02 278.78 -2.00 20.00 -2.00 322.37 0.00e+00 7.659 0.008 302.00 328.00 3 -4.6105e-01 4.0180e-02 1.0711e-01 -6.0000e+00 7.6911e-01 1.8419e+00 5.2970e-02 8.3465e-02 -6.0000e+00 8.3722e-01 -2.2872e+00 4.4877e-02 3.7914e-02 -6.0000e+00 4.9471e-01 8.6564e-01 2.1460e-02 1.2553e-02 -6.0000e+00 2.0964e-01 1.0792e-04 -9.2899e-04 3.8943e-04 1.6324e-04 -6.0000e+00 1.4849e-02 3.6779e-04 -5.9935e-06 12 8 8 10 0 0 30.19 23.07 0.49 0.00037 -0.00661 91 19 1 5 0 548.090 26.73 20.00 23.07 10.01 28.7 972.16 900000 33877 -41689 -47314 11173 -98113 4028 -90913 900000 -19419 -3034 -42642 241458 900000 47049 46497 -13970 206294 12209 11916 94716 26364 900000 -107354 -55885 -36861 -90271 900000 -5449 152689 -34544 48522 -6228 30668 27338 -63864 900000 25245 46726 50530 45291 138215 44364 77328 23393 236165 -4020 65832 33529 63818 37767 3362 138437 49811 85645 415 60539 5015 20471 40601 127013 68150 82485 56385 25775 42582 11924 1040 25071 34777 45019 39429 42938 6931 27808 1715 -6178 4119 -13640 12240 7446 17056 6286 11927 5097 6829 14719 1054 10471 5484 6899 -3380 426 -11264 -8392 -3190 -5461 -921 -1388 3270 -5461 -4093 -6544 -233 -4260 -5224 -870 -1978 2175 -591 -453 131 -2768 788 -2574 -123 -822 -1348 -337 161 684 2120 4491 1444 2294 2069 2087 -982 713 -272 -795 940 124 157 -388 -78 1671 572 268 -585 -576 -1264 -1434 900000 517 -1322 -1389 171 -3111 62 -2456 900000 -297 -46 -760 3687 900000 718 769 -462 3150 326 303 1446 470 900000 -6967 -2204 -1173 -4594 900000 -97 2331 -1055 803 -206 741 626 -3546 900000 631 1103 1333 1383 2110 1416 1717 844 3606 -184 1553 1164 1772 1520 215 2498 2351 2972 35 2773 383 1222 1803 2292 2365 2862 2974 2039 2896 1125 117 2471 3572 4562 4324 4351 904 2548 176 -643 412 -1931 1665 1292 3172 1466 3078 1479 2033 4180 348 3086 1616 1865 -965 118 -3887 -3370 -1490 -3161 -606 -1034 2377 -4053 -2618 -3727 -120 -2420 -3167 -536 -1359 1657 -555 -502 161 -3724 1035 -3428 -156 -1075 -1865 -484 232 935 2644 5184 1674 2571 2268 2262 -1210 1049 -487 -1648 2130 308 426 -1142 -239 5101 1770 815 -1675 -1492 -2977 -3221 SS 20240417T105344.8Z 8873.453991 162 1 49.67 2 81.13 83.55 114.50 337.17 0.00 1 0.00 1 0 25 7.033e-01 1.639e-02 2.723e-01 4.489e-03 9.908164e-01 2.581547e-03 1.082165e-02 -6.000000e+00 3.996373e-01 228.56 -2.00 3.55 -2.00 322.36 0.00e+00 4.729008e-03 1.575691e-03 3.727662e-03 -6.000000e+00 1.730807e-02 278.78 -2.00 20.00 -2.00 321.92 0.00e+00 6.140 0.004 302.00 328.00 3 -3.5734e-01 1.0400e-02 8.3668e-02 -6.0000e+00 9.9629e-01 7.4376e-01 1.6734e-02 5.9763e-02 -6.0000e+00 1.0828e+00 -1.0066e+00 1.8059e-02 3.4977e-02 -6.0000e+00 6.4325e-01 3.9451e-01 7.9453e-03 1.3397e-02 -6.0000e+00 2.7078e-01 5.9509e-04 -4.2687e-04 1.1483e-04 2.1094e-04 -6.0000e+00 1.8555e-02 -7.5365e-04 3.5335e-05 12 8 8 10 0 0 91.06 23.08 0.29 -0.00075 -0.00396 235 49 1 5 0 211.250 26.73 20.00 23.08 10.94 28.8 980.42 -182154 -198506 -138409 -158439 -56453 -176425 -278092 -226520 -289401 -199558 -262113 -152367 -131308 -100947 -39672 -143455 -35717 -111610 -7152 -97128 -36522 -41216 -4932 -8865 -109000 -52366 -96698 -40583 -67895 191561 -19206 11787 -24360 -23814 29747 -35488 38224 9648 41471 71009 30487 36154 5269 40541 17824 21799 33291 27603 25090 15630 32222 20899 55279 25860 50266 33452 24535 24822 17523 23108 10658 19602 21063 24887 22453 17039 16324 11169 12217 9004 15248 13259 13454 13708 7616 5286 -3601 -1046 -4308 2448 3942 1525 758 663 1719 91 3260 1288 3449 1768 -769 -2529 -5175 -2462 -4427 -2542 -1475 -486 69 -1737 -1400 -4738 -1453 -2994 -1007 -2573 -1907 -1023 -822 70 -570 372 -525 -268 -1239 -708 -17 -283 708 138 1543 1565 2035 1637 1270 647 -484 1304 -185 596 166 38 -280 -293 125 -263 861 584 407 -280 -226 -828 -1287 -1165 -1805 -746 -1098 -247 -1158 -5072 -2644 -6862 -2038 -5163 -1112 -1006 -773 -217 -2774 -274 -2036 -50 -1701 -346 -391 -32 -71 -2516 -709 -2040 -468 -1000 839 -237 136 -485 -521 367 -791 426 165 627 961 704 849 176 968 532 633 888 824 829 622 1231 1023 2134 1472 2400 1970 1621 1610 1158 1507 788 1450 1789 2386 2438 1984 1944 1486 1797 1588 2803 2589 2562 2400 1260 789 -552 -164 -815 534 1023 476 267 250 679 39 1400 577 1501 751 -313 -992 -2068 -1031 -2215 -1505 -1032 -397 62 -1630 -1226 -3785 -993 -2029 -714 -1960 -1529 -887 -806 79 -754 536 -789 -400 -1801 -995 -23 -421 1100 220 2336 2221 2740 2146 1620 806 -597 1709 -291 1093 346 87 -688 -779 355 -715 2349 1609 1217 -795 -588 -1987 -2977 SS 20240417T110626.5Z 8873.462806 167 1 49.73 2 78.82 85.66 115.35 340.19 0.00 1 0.00 1 0 25 7.819e-01 1.100e-02 1.752e-01 2.204e-03 8.351082e-01 1.210210e-03 9.624374e-03 -6.000000e+00 4.442785e-01 228.56 -2.00 3.55 -2.00 321.84 0.00e+00 6.853987e-03 6.688361e-04 4.844619e-03 -6.000000e+00 1.924197e-02 278.78 -2.00 20.00 -2.00 321.37 0.00e+00 4.977 0.002 302.00 328.00 3 -1.4949e-01 4.4484e-03 6.9788e-02 -6.0000e+00 1.1076e+00 2.2761e-01 7.0426e-03 5.1723e-02 -6.0000e+00 1.2038e+00 -2.8482e-01 7.9644e-03 3.1921e-02 -6.0000e+00 7.1511e-01 1.0220e-01 3.6001e-03 1.2752e-02 -6.0000e+00 3.0100e-01 1.7593e-03 -4.8021e-04 5.7982e-05 2.0420e-04 -6.0000e+00 2.0630e-02 -5.5616e-04 2.2295e-05 12 8 8 10 0 0 88.98 23.10 0.25 -0.00056 -0.00416 443 92 1 5 0 112.220 26.73 20.00 23.10 12.73 29.1 992.98 -186787 -275233 -183927 -297398 -193973 -279515 -226150 -174914 -292483 145741 -280016 -172529 -212242 -179520 -152850 -98567 -35641 -103094 -66877 -95840 -17057 -95770 -68382 -67159 -77361 -44638 -64059 -17492 -89055 -42834 -56986 -23010 -24888 -26196 -14490 -33942 5172 -20773 -4494 -10348 4979 9367 4328 16775 2529 11148 -2296 15191 5873 10921 15447 7589 12183 5282 12933 7654 8607 5915 1487 4871 2183 8886 4686 11407 8750 7221 5834 857 5651 3795 5659 3590 4086 1368 -353 1608 -3330 -883 -2963 224 -2277 2 -2352 -1503 -426 -313 1122 639 2336 754 104 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