File name: Pandora183s1_LondonderryNH_20240426_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240429T114626.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240426_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240426T102916.1Z 8882.436992 211 1 49.47 2 83.22 77.52 87.76 231.04 0.00 1 0.00 1 0 25 4.470e-01 2.248e-02 4.751e-01 2.138e-02 1.213931e+00 1.286229e-02 1.277747e-02 -6.000000e+00 2.552177e-01 229.36 -2.00 3.55 -2.00 322.80 0.00e+00 -2.054524e-02 7.345159e-03 4.509140e-03 -6.000000e+00 1.229531e-02 279.79 -2.00 20.00 -2.00 322.42 0.00e+00 7.731 0.009 302.00 328.00 3 -8.9699e-02 5.4010e-02 1.0834e-01 -6.0000e+00 6.3833e-01 1.9484e+00 6.6459e-02 8.5368e-02 -6.0000e+00 6.9384e-01 -2.5659e+00 4.5797e-02 3.5861e-02 -6.0000e+00 4.1086e-01 9.7213e-01 2.3687e-02 1.4367e-02 -6.0000e+00 1.7316e-01 7.5507e-05 8.2513e-04 5.1975e-04 1.7088e-04 -6.0000e+00 1.2000e-02 -1.2345e-03 1.3750e-05 12 8 8 10 0 0 -5.08 22.80 0.56 -0.00123 0.00497 73 15 1 5 0 677.570 26.41 19.99 22.80 4.87 28.2 933.58 34533 50259 -25621 -21056 -51432 -15690 -59069 -4581 -7573 900000 -95239 900000 -32605 67432 28284 -7933 71206 56137 28868 -31070 166572 -28213 72903 -154 66793 28557 115536 900000 -34500 91054 52993 -5637 45641 63881 45645 27637 22064 17322 -26285 11325 125132 74796 124120 19735 45704 107025 38922 28407 38583 2141 69517 59047 41803 17783 74070 94023 196540 26207 87395 -7926 6494 23427 26027 20405 100479 14947 5014 37073 81579 11986 30165 39322 15692 -2190 18168 5218 39497 -22385 -17627 4285 20555 5008 7135 14715 4790 2662 10630 -7985 7328 220 -4070 -12107 -10185 -3075 -5939 1229 11914 -1734 -4848 -2510 -1070 -4171 -526 -5559 -665 -443 -6703 3615 -3521 -1406 1275 -413 -2787 1069 -1558 -683 -171 -652 -624 2822 552 -754 3737 2516 660 521 3797 2006 182 1031 -1029 341 -357 -214 -866 -513 954 1393 869 117 -619 -2067 -1010 1107 1369 -1355 -877 -2226 -402 -2367 -117 -218 900000 -6869 900000 -1411 1405 884 -386 1607 1462 952 -1726 3471 -1225 1519 -6 1392 893 2407 900000 -1318 1897 1104 -206 1109 1331 1030 672 575 591 -1693 601 2607 2409 2586 972 1558 2230 1253 1022 1316 114 2107 2237 2059 1213 3087 3384 4095 1837 2980 -616 406 1287 1578 1507 3616 1274 484 2809 4481 1521 3486 4246 2051 -307 1790 504 2544 -2841 -2504 601 2959 996 1568 3206 1216 721 2739 -2496 2107 64 -1153 -3582 -3035 -955 -2277 533 5561 -1095 -3526 -1809 -709 -2494 -266 -2896 -352 -247 -4246 2283 -2774 -1304 1362 -505 -3694 1383 -2036 -869 -221 -889 -891 3915 741 -952 4299 2862 748 577 4050 2429 273 1845 -2168 789 -911 -597 -2633 -1626 3010 4385 2682 338 -1626 -4984 -2313 SS 20240426T105338.2Z 8882.453915 219 1 49.64 2 78.82 81.54 91.24 235.08 0.00 1 0.00 1 0 25 8.859e-01 1.072e-02 1.221e-01 2.011e-03 8.827230e-01 1.112617e-03 1.014829e-02 -6.000000e+00 5.049071e-01 229.36 -2.00 3.55 -2.00 321.92 0.00e+00 7.671822e-03 6.366680e-04 5.457987e-03 -6.000000e+00 2.189391e-02 279.80 -2.00 20.00 -2.00 321.46 0.00e+00 4.980 0.002 302.00 328.00 3 -2.9737e-01 4.2205e-03 7.2502e-02 -6.0000e+00 1.2607e+00 2.7359e-01 6.8346e-03 5.5724e-02 -6.0000e+00 1.3691e+00 -3.4619e-01 7.7303e-03 3.4569e-02 -6.0000e+00 8.1329e-01 1.2518e-01 3.4563e-03 1.3854e-02 -6.0000e+00 3.4212e-01 1.9118e-03 -5.5821e-04 5.1660e-05 2.3122e-04 -6.0000e+00 2.3378e-02 -1.5056e-03 1.0728e-05 12 8 8 10 0 0 -3.18 22.77 0.26 -0.00151 -0.00570 431 90 1 5 0 115.150 26.41 20.00 22.77 7.61 28.4 953.56 -310947 -288901 -271203 -242687 -278675 -236914 -304102 -250774 -275316 -221998 -254461 -245274 -247370 -155986 -92620 -156329 -64239 -113302 -59808 -102765 -63076 -86355 -115560 -43051 -86827 -72586 -79500 -48054 -82264 -57458 -39588 -47036 -8714 -15711 -15014 -23894 -27725 -13477 -11942 716 -6378 8351 -1055 8282 4467 2339 6919 10185 6764 4811 7434 6457 13392 9251 8839 12174 5994 7615 1426 3265 3160 7646 9302 10364 10610 6811 5665 4819 7262 5647 5144 3992 3342 1990 880 -499 -3940 -3556 -2004 -1561 329 -879 -725 -817 149 -329 919 599 1863 1478 202 -398 -2704 -2262 -2684 -1392 -42 672 342 -439 -1187 -2411 -1464 -1484 -1860 -1896 -1343 -648 -225 855 640 592 146 -297 -862 -331 177 218 637 326 662 1158 1223 679 404 -563 -427 816 128 -115 -178 -382 -373 -283 -291 -144 396 773 303 -17 -57 -625 -569 -2287 -2172 -1950 -1349 -2050 -1084 -2833 -1517 -2385 -1234 -2080 -2085 -2871 -1113 -479 -1979 -389 -1293 -448 -1264 -540 -924 -1690 -330 -1115 -854 -1035 -454 -1100 -666 -487 -805 -124 -272 -254 -426 -549 -272 -292 19 -207 256 -38 312 179 99 293 445 332 264 452 456 988 786 811 1132 613 763 147 320 316 808 1129 1458 1642 1109 940 849 1389 1278 1305 1074 893 503 203 -103 -792 -739 -473 -449 112 -352 -324 -389 75 -176 509 342 1046 802 104 -194 -1315 -1158 -1591 -971 -34 636 360 -473 -1206 -2197 -1175 -1170 -1572 -1694 -1261 -654 -253 1096 937 939 238 -478 -1335 -493 264 341 1048 551 1083 1779 1793 967 557 -756 -558 1124 206 -217 -375 -793 -826 -672 -741 -385 1065 2092 814 -44 -135 -1375 -1325 SS 20240426T105926.0Z 8882.457940 222 1 49.68 2 77.77 82.49 92.10 236.01 0.00 1 0.00 1 0 25 7.653e-01 9.224e-03 9.328e-02 1.455e-03 8.238117e-01 7.958297e-04 9.505359e-03 -6.000000e+00 4.362185e-01 229.36 -2.00 3.55 -2.00 321.71 0.00e+00 5.845295e-03 4.318026e-04 4.985265e-03 -6.000000e+00 1.891470e-02 279.80 -2.00 20.00 -2.00 321.23 0.00e+00 4.583 0.002 302.00 328.00 3 -3.4426e-01 2.8678e-03 6.6859e-02 -6.0000e+00 1.0892e+00 1.7822e-01 4.4983e-03 5.2132e-02 -6.0000e+00 1.1828e+00 -2.1736e-01 5.0652e-03 3.2022e-02 -6.0000e+00 7.0262e-01 7.3699e-02 2.3072e-03 1.2117e-02 -6.0000e+00 2.9560e-01 3.1195e-03 -3.6242e-04 3.8034e-05 1.6905e-04 -6.0000e+00 2.0195e-02 -1.8894e-03 2.6756e-05 11 8 0 10 0 0 -3.28 22.77 0.24 -0.00189 -0.00461 555 115 1 5 0 89.500 26.41 20.00 22.77 8.20 28.3 957.62 -286750 -259564 -218744 -271734 -218560 -284035 -177717 -272226 -172517 -231816 -200343 -179995 -176084 -124312 -146734 -78970 -100565 -47488 -68029 -58354 -60768 -71617 -50371 -69659 -38052 -80414 -35467 -56512 -61428 -48512 -46473 -20694 -25970 -8751 -26360 -15328 -15674 -15184 117 -9899 3139 -8855 5102 -654 5424 498 2515 3942 -737 6484 4284 8629 7030 8092 7763 5038 7765 1842 5012 659 5007 4016 7017 7471 5460 5734 1520 3018 2499 3638 3334 2923 1744 49 1176 -2452 -857 -4354 -1804 -1169 -653 -283 -2028 -766 -975 169 545 1025 1184 1115 646 -813 -1680 -2325 -1633 -1358 16 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