File name: Pandora183s1_LondonderryNH_20240429_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240430T045138.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240429_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240429 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240429T103519.6Z 8885.441199 196 1 49.80 2 81.42 77.89 74.02 198.18 0.00 1 0.00 1 0 25 5.693e-01 1.518e-02 2.994e-01 7.467e-03 7.917497e-01 4.211916e-03 9.185835e-03 -6.000000e+00 3.269760e-01 229.62 -2.00 3.55 -2.00 322.08 0.00e+00 6.424202e-03 2.448369e-03 5.390546e-03 -6.000000e+00 1.429243e-02 280.13 -2.00 20.00 -2.00 321.61 0.00e+00 6.319 0.005 302.00 328.00 3 5.3721e-01 1.6318e-02 7.9169e-02 -6.0000e+00 8.1781e-01 4.7219e-01 2.4024e-02 5.0596e-02 -6.0000e+00 8.8821e-01 -6.4417e-01 2.4771e-02 2.9276e-02 -6.0000e+00 5.2589e-01 2.4978e-01 1.1192e-02 1.1057e-02 -6.0000e+00 2.2097e-01 2.6960e-04 -1.7529e-04 2.1098e-04 2.0371e-04 -6.0000e+00 1.5398e-02 -2.4448e-03 3.2214e-05 12 8 8 10 0 0 56.07 22.77 0.39 -0.00244 -0.00376 97 20 1 5 0 513.310 26.41 19.99 22.77 21.60 29.6 1056.11 -273827 -169880 -171623 900000 -173937 -72975 -214590 900000 -180676 -159345 -189712 -148313 -43581 -132899 -102812 32368 -49904 -39497 -95735 -44577 -39242 -28857 -57728 -79867 -26551 42111 -91207 -63989 22277 -50552 -74965 -9707 -10453 7771 -34204 -14569 35316 -47063 -1993 42915 9106 40030 29980 56408 42826 15195 5798 31063 13177 13257 18602 7763 27542 18753 19511 24745 19205 6406 4375 13420 986 10783 21134 15879 12185 15923 10084 7393 11559 3275 12330 10646 6819 4014 6417 879 -4128 -5028 -3024 2943 2965 2796 -3391 1030 982 21 549 814 1644 1651 1214 -982 -2838 -4644 -5088 -2631 -709 370 -1842 230 -1302 -3138 -2318 -2542 -2175 -897 -1050 -1684 445 328 1 -119 -313 -631 -465 -944 330 -273 302 1005 1501 1505 1068 764 1196 100 -433 1496 207 962 -175 65 -610 -293 53 -160 581 864 -1 -10 -218 -536 -1427 -6440 -1712 -1922 900000 -1753 -531 -3254 900000 -2302 -1740 -2877 -1619 -317 -2096 -1559 236 -636 -503 -2323 -676 -571 -368 -981 -1793 -370 307 -2545 -1440 206 -1037 -2381 -199 -256 175 -1132 -376 584 -2056 -67 1108 374 1298 1131 1680 1474 704 303 1316 706 763 1133 596 1914 1551 1704 2129 1792 674 452 1226 104 1127 2294 2091 1806 2266 1508 1179 1951 696 2660 2445 1607 911 1415 182 -838 -1054 -707 784 941 1030 -1476 456 464 11 292 444 889 862 595 -462 -1320 -2302 -2893 -1725 -537 322 -1819 225 -1214 -2661 -1756 -1919 -1759 -760 -943 -1645 474 399 2 -177 -476 -941 -661 -1301 454 -398 465 1589 2317 2216 1518 1055 1589 130 -551 1982 320 1702 -348 140 -1394 -716 140 -441 1621 2435 -2 -28 -547 -1258 -3274 SS 20240429T104841.5Z 8885.450480 201 1 49.63 2 79.01 80.08 74.80 201.02 0.00 1 0.00 1 0 25 4.961e-01 8.327e-03 1.408e-01 2.593e-03 6.611865e-01 1.392050e-03 7.770881e-03 -6.000000e+00 2.830781e-01 229.62 -2.00 3.55 -2.00 321.44 0.00e+00 5.266152e-03 6.978942e-04 3.620269e-03 -6.000000e+00 1.227933e-02 280.13 -2.00 20.00 -2.00 320.91 0.00e+00 5.059 0.002 302.00 328.00 3 4.2270e-01 4.8162e-03 6.2992e-02 -6.0000e+00 7.0719e-01 1.0429e-01 6.8298e-03 3.9970e-02 -6.0000e+00 7.6774e-01 -1.2993e-01 7.2590e-03 2.3653e-02 -6.0000e+00 4.5606e-01 4.0510e-02 3.4134e-03 9.0747e-03 -6.0000e+00 1.9184e-01 1.1630e-03 -3.9113e-04 7.3232e-05 1.3804e-04 -6.0000e+00 1.3092e-02 -2.3051e-03 2.2333e-05 11 8 0 10 0 0 87.73 22.82 0.38 -0.00231 -0.00524 202 42 1 5 0 245.660 26.41 20.00 22.82 22.45 29.7 1062.22 -183586 -142721 -196856 -59908 -172989 -162289 -212851 -172011 -98660 -147696 -92588 -148838 -90117 -67613 -77352 -72885 -56255 -12730 -60295 -38862 -38894 -36064 -27943 -41965 -25051 -48815 -14418 -27154 -11784 -32035 -18884 -16768 -10638 -9666 -12312 -2236 -23897 518 -7972 565 1261 -1109 188 3462 1876 420 5234 2904 2934 3437 -1279 3710 -1416 3318 4755 4583 3134 3127 51 1641 898 2068 5482 4545 4298 2120 2336 407 972 2746 2209 3000 2016 1664 -1560 -253 -1486 -3513 -1185 -1596 433 -737 -1879 -1038 -576 2 424 934 1257 1128 613 371 -2366 -1949 -1141 -1378 490 534 682 -303 -824 -1533 -1598 -223 -1715 -1155 -1086 -590 187 270 688 135 74 -295 -588 -420 118 95 771 428 301 1126 982 622 522 -499 -471 447 198 -246 -139 -532 -292 -111 -165 -52 74 875 242 137 -103 -472 -513 -1315 -842 -2240 -177 -1458 -1163 -2646 -1595 -499 -1338 -507 -1711 -725 -575 -942 -1056 -802 -132 -1109 -616 -644 -580 -424 -791 -432 -1133 -245 -518 -190 -670 -412 -439 -311 -311 -399 -63 -901 18 -370 29 74 -73 13 264 148 35 424 250 265 329 -143 445 -197 482 726 731 525 525 9 267 151 378 1106 1055 1075 534 575 104 272 874 789 1120 757 595 -527 -76 -416 -1007 -369 -596 187 -369 -1052 -612 -361 1 297 672 903 785 400 226 -1419 -1192 -774 -1090 443 554 776 -351 -899 -1514 -1437 -198 -1665 -1183 -1172 -678 233 378 1068 224 123 -476 -898 -614 173 145 1249 725 506 1806 1519 933 753 -701 -639 627 315 -446 -276 -1131 -649 -238 -380 -127 182 2181 606 328 -234 -1108 -1172 SS 20240429T105434.2Z 8885.454563 204 1 49.67 2 77.95 81.04 75.18 202.26 0.00 1 0.00 1 0 25 3.610e-01 7.872e-03 9.604e-02 1.912e-03 6.139326e-01 1.009851e-03 7.193018e-03 -6.000000e+00 2.059823e-01 229.62 -2.00 3.55 -2.00 321.14 0.00e+00 3.754147e-03 4.661372e-04 3.284878e-03 -6.000000e+00 8.935137e-03 280.13 -2.00 20.00 -2.00 320.60 0.00e+00 4.646 0.002 302.00 328.00 3 4.0066e-01 3.3316e-03 5.7984e-02 -6.0000e+00 5.1459e-01 7.0032e-02 4.5811e-03 3.7331e-02 -6.0000e+00 5.5865e-01 -7.5766e-02 4.7544e-03 2.1172e-02 -6.0000e+00 3.3186e-01 1.6917e-02 2.2822e-03 7.2938e-03 -6.0000e+00 1.3959e-01 1.8423e-03 -3.1193e-04 5.3881e-05 1.0052e-04 -6.0000e+00 9.5271e-03 -2.2517e-03 1.7198e-05 11 8 0 10 0 0 32.71 22.82 0.26 -0.00225 -0.00460 263 55 1 5 0 188.820 26.41 20.00 22.82 22.74 29.7 1064.22 -87620 -143870 -76981 -113851 -141349 -123044 -143278 -61607 -143123 -62747 -125959 -67046 -69797 -84142 -29125 -54380 -9537 -54025 -10563 -19609 -15259 -19680 -42886 -14451 -23489 -3065 -28739 -1428 -24393 -20417 -9977 -9305 -6351 -14595 310 -22600 -4822 -10232 -5592 -1605 -2522 3483 -4930 3371 -2914 521 -279 3223 909 -1334 4686 482 5105 2191 4637 1878 1310 1169 -810 1098 -366 4361 3404 4795 4014 753 1125 -1207 3235 527 2950 1736 1237 1059 -481 -796 -2902 -2404 -2469 -1177 -1085 -599 -2068 -1224 -327 -541 909 870 1872 995 623 86 -2028 -1060 -1672 -592 215 976 51 -280 -264 -2036 -786 -936 -1318 -1485 -761 -653 -131 761 1009 561 119 257 -662 -220 1 159 689 5 494 581 1093 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