File name: Pandora183s1_LondonderryNH_20240514_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240515T045357.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240514_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240514T125156.0Z 8900.536065 187 1 0.77 2 53.68 97.81 108.44 36.02 0.00 1 0.00 1 0 17 1.435e-02 8.338e-03 5.834e-03 2.325e-03 2.787868e-01 1.179888e-03 3.353090e-03 -6.000000e+00 8.230913e-03 230.96 -2.00 3.55 -2.00 316.71 0.00e+00 9.219582e-04 1.454512e-04 2.267168e-04 -6.000000e+00 3.577864e-04 281.84 -2.00 20.00 -2.00 316.00 0.00e+00 1.684 0.000 302.00 328.00 3 1.0243e+00 3.1055e-03 2.2306e-02 -6.0000e+00 2.0618e-02 -9.1292e-05 3.4728e-03 1.4516e-02 -6.0000e+00 2.2352e-02 -3.0295e-03 2.0293e-03 7.0720e-03 -6.0000e+00 1.3277e-02 -2.8535e-03 9.6446e-04 1.9864e-03 -6.0000e+00 5.5789e-03 2.5045e-02 -4.9615e-06 6.5083e-05 2.1804e-05 -6.0000e+00 3.7883e-04 -1.8322e-03 8.5007e-05 12 9 1 12 1 1 -1.84 22.91 0.29 -0.00183 -0.00187 8 121 1 5 0 85.080 26.51 19.99 22.91 23.95 29.9 1067.79 -2196 -60 1234 -3409 -3991 -7964 -1957 -3678 -858 -1580 -2091 -1927 -2235 785 -1587 504 -969 957 2152 1938 1623 -370 1624 715 1402 1068 -57 -220 -2775 215 1050 732 1387 -254 -3041 -3293 -3368 -2350 -410 -346 -487 -357 -202 -254 363 254 -104 152 -1499 4 377 568 1369 1625 980 488 1060 348 233 153 833 2025 1908 2737 497 415 -629 -1029 642 556 859 1124 554 327 331 -306 -959 -2262 -1344 -1526 -1731 -1360 -2573 -1670 -1028 -468 55 647 711 307 268 -238 -895 -691 -342 -585 457 1118 147 -130 -520 -1062 -930 -171 -1151 -963 -801 -1045 298 1064 1211 769 583 509 -318 66 -140 -30 660 457 111 494 994 490 807 -119 -36 730 199 10 -429 -758 -359 -58 127 -171 133 504 122 34 -52 -929 -633 -299 -9 194 -544 -570 -1087 -258 -549 -141 -281 -374 -343 -441 158 -380 133 -276 277 645 604 523 -121 523 244 462 369 -20 -74 -976 71 360 252 518 -102 -1195 -1229 -1334 -1065 -203 -188 -295 -227 -133 -170 241 169 -69 98 -961 2 248 375 954 1193 751 384 793 262 184 120 660 1590 1638 2360 445 369 -519 -822 530 491 835 1083 539 308 309 -275 -779 -1868 -1066 -1365 -1652 -1355 -2786 -1778 -1161 -536 66 804 886 372 317 -258 -940 -697 -362 -651 533 1440 195 -171 -644 -1272 -1099 -206 -1446 -1219 -1058 -1450 409 1552 1785 1158 850 722 -437 85 -179 -41 939 664 166 723 1409 701 1093 -155 -46 942 264 15 -619 -1129 -542 -87 202 -276 219 844 205 56 -82 -1489 -990 SS 20240514T125655.2Z 8900.539527 190 1 28.13 2 52.77 98.76 107.93 37.07 0.00 1 0.00 1 0 17 1.443e-02 7.136e-03 3.664e-03 9.027e-04 2.746404e-01 4.559140e-04 3.268542e-03 -6.000000e+00 8.273607e-03 230.96 -2.00 3.55 -2.00 317.83 0.00e+00 9.112862e-04 7.378467e-05 3.495736e-04 -6.000000e+00 3.596200e-04 281.84 -2.00 20.00 -2.00 317.09 0.00e+00 1.649 0.000 302.00 328.00 3 2.2878e+00 1.2223e-03 2.1912e-02 -6.0000e+00 2.0725e-02 1.5582e-02 1.3783e-03 1.4314e-02 -6.0000e+00 2.2467e-02 -9.5060e-04 8.5233e-04 7.0283e-03 -6.0000e+00 1.3345e-02 -6.6192e-03 4.2702e-04 2.0192e-03 -6.0000e+00 5.6084e-03 7.3191e-03 1.9606e-04 2.5965e-05 2.0395e-05 -6.0000e+00 3.8074e-04 -2.1865e-03 1.1049e-04 12 9 1 12 1 1 99.99 22.90 0.24 -0.00219 -0.00071 197 73 1 5 0 142.010 26.51 19.99 22.90 24.25 29.9 1070.12 -2488 -2535 -3722 -2274 -5834 -3509 -3842 -2074 -3312 -3009 -3026 -4466 -1620 -2125 1173 -114 -662 687 233 1317 709 809 763 1242 277 360 -530 -1588 -1387 -1131 147 531 1684 -665 -3783 -3565 -3530 -1930 -783 79 -745 -389 -279 -548 283 195 -240 -81 -670 -590 345 579 1070 1373 740 1294 881 528 281 489 1018 1953 2138 2690 1114 144 -499 -887 664 782 655 946 579 795 278 -384 -1167 -1964 -1071 -1180 -1310 -1372 -2313 -1480 -745 -564 -48 356 827 807 492 36 -993 -574 -570 -557 348 851 245 -304 -526 -1261 -995 -274 -1089 -1150 -723 -618 97 600 926 586 520 131 -296 86 160 -46 486 247 146 576 694 379 586 -152 -38 855 237 132 -185 -502 -144 -108 -71 -150 325 635 47 -120 -205 -684 -671 -187 -216 -337 -197 -466 -252 -283 -184 -305 -327 -330 -492 -191 -292 180 -20 -124 131 47 272 152 172 163 277 66 90 -135 -390 -315 -247 33 130 446 -191 -1063 -947 -994 -618 -298 35 -374 -186 -138 -275 155 107 -130 -43 -350 -307 186 336 656 805 453 804 561 338 176 333 640 1301 1551 2087 891 109 -347 -656 461 615 571 864 533 706 232 -290 -877 -1400 -781 -970 -1108 -1287 -2350 -1561 -832 -675 -56 424 985 930 575 39 -979 -542 -566 -611 422 1044 323 -399 -650 -1566 -1158 -326 -1416 -1453 -951 -850 139 915 1488 961 823 194 -403 119 221 -61 685 373 225 875 1023 537 858 -214 -50 1133 339 186 -276 -770 -223 -175 -121 -272 601 1194 82 -223 -367 -1181 -1134 SS 20240514T131545.1Z 8900.552605 202 1 51.16 2 49.38 102.47 105.88 40.94 0.00 1 0.00 1 0 17 1.233e-02 7.040e-03 7.886e-04 2.295e-04 2.556176e-01 1.151765e-04 3.071016e-03 -6.000000e+00 7.071009e-03 230.96 -2.00 3.55 -2.00 317.55 0.00e+00 8.406126e-04 1.733734e-05 2.978355e-04 -6.000000e+00 3.073696e-04 281.84 -2.00 20.00 -2.00 316.81 0.00e+00 1.533 0.000 302.00 328.00 3 3.2038e-01 3.0694e-04 2.0406e-02 -6.0000e+00 1.7712e-02 1.2510e-03 3.4545e-04 1.3365e-02 -6.0000e+00 1.9203e-02 3.2958e-04 2.0928e-04 6.5382e-03 -6.0000e+00 1.1406e-02 -5.9919e-03 1.0333e-04 1.8466e-03 -6.0000e+00 4.7926e-03 6.0873e-02 1.0206e-07 6.4133e-06 1.9818e-05 -6.0000e+00 3.2546e-04 -2.0787e-03 6.7533e-05 11 8 0 10 0 0 99.31 22.83 0.24 -0.00208 -0.00208 1872 389 1 5 0 26.530 26.41 20.01 22.83 25.07 30.1 1076.15 -986 -1039 -1292 -2963 -4488 -3464 -2304 -1215 -951 -2401 -3904 -3675 -2035 -1539 -8 38 -286 581 361 1507 958 517 1227 1061 469 288 -110 -942 -1242 -668 495 651 1285 -601 -3411 -3205 -3518 -1844 -650 -280 -813 -404 -380 -437 216 122 -103 -331 -713 -485 554 763 1006 1161 756 1105 863 431 267 438 1138 1739 2074 2452 839 25 -499 -875 736 701 565 892 557 765 316 -432 -966 -1845 -943 -1153 -1253 -1319 -2226 -1460 -807 -545 -136 379 800 689 421 -14 -803 -343 -456 -512 356 840 106 -312 -561 -1309 -981 -269 -1206 -1096 -745 -736 111 609 948 521 515 121 -224 104 164 107 505 279 149 488 714 442 680 -127 -13 892 284 76 -199 -439 -281 -21 -23 -57 259 574 95 -81 -135 -728 -709 -88 -105 -137 -310 -423 -326 -219 -127 -112 -308 -508 -473 -282 -245 -1 8 -61 127 83 353 233 125 296 269 126 81 -31 -259 -317 -163 124 177 377 -190 -1050 -932 -1088 -647 -271 -138 -405 -211 -205 -239 117 66 -55 -190 -403 -271 320 430 600 728 493 732 584 293 179 289 761 1235 1599 2021 711 20 -365 -617 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