File name: Pandora183s1_LondonderryNH_20240526_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240527T045425.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240526_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240526 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240526T103121.8Z 8912.438446 215 1 49.50 2 77.71 72.31 84.99 222.00 0.00 1 0.00 1 0 17 4.218e-01 2.375e-02 3.562e-01 1.471e-02 6.830515e-01 8.308644e-03 7.733808e-03 -6.000000e+00 2.466206e-01 231.72 -2.00 3.55 -2.00 321.65 0.00e+00 -1.436887e-03 4.271622e-03 4.019209e-03 -6.000000e+00 1.251513e-02 283.06 -2.00 20.00 -2.00 321.11 0.00e+00 4.561 0.002 302.00 328.00 3 3.0635e+00 2.9811e-02 6.2770e-02 -6.0000e+00 6.1980e-01 2.6244e-01 4.0823e-02 4.8345e-02 -6.0000e+00 6.7372e-01 -4.4741e-01 3.9019e-02 2.1479e-02 -6.0000e+00 3.9872e-01 1.8256e-01 1.8326e-02 5.8509e-03 -6.0000e+00 1.6786e-01 1.2892e-04 -7.1195e-04 4.3347e-04 7.7566e-05 -6.0000e+00 1.1641e-02 8.0085e-07 -1.1270e-05 12 8 8 10 0 0 99.98 22.75 0.61 0.00000 -0.00535 73 15 1 5 0 677.970 26.32 20.01 22.75 23.05 30.1 1050.28 -165419 900000 -155009 900000 -147469 101815 900000 -75409 22646 -106801 900000 -191436 900000 -27532 103451 11243 -71072 900000 -103064 900000 -49065 900000 -12156 -3270 63659 -14974 900000 -89314 900000 -85971 40338 -74850 -17456 20296 -14916 12330 -18974 19311 84310 46167 29829 -18516 36725 -10189 65705 3024 53419 -5834 -12638 44176 -5413 46801 -225 18622 2003 8288 9267 7608 30834 3869 22748 4127 30164 11155 16304 5511 8672 9841 1594 2313 1751 7986 3693 10061 8472 -1486 -2953 -11134 5104 -5004 10086 -2418 -5650 3147 -2776 1487 -976 2700 3045 771 -697 -768 411 -8185 3765 -3056 1726 -552 1324 -1894 -3214 -2760 -4393 1022 -5334 -1401 -803 221 -1171 -1768 1033 -1323 2282 -1633 254 -1269 -560 884 -937 4850 -1349 2373 -429 2297 1602 323 1822 838 376 -916 2623 -638 627 -598 -818 -364 -590 2547 -593 1145 -732 -1102 -1665 -2550 900000 -2731 900000 -2111 1458 900000 -1080 324 -1529 900000 -7080 900000 -394 1481 161 -1950 900000 -4550 900000 -1346 900000 -232 -62 911 -375 900000 -4582 900000 -4103 626 -4376 -666 634 -641 385 -864 704 1975 1923 1669 -1807 2151 -968 2908 252 2711 -547 -1316 2760 -613 3533 -30 2230 302 1230 1411 1178 3652 579 2842 671 4279 2163 3204 1183 1761 2024 390 650 551 2484 1192 2881 2249 -389 -723 -2956 1276 -1641 3347 -1045 -2787 1511 -1510 828 -587 1613 1811 452 -388 -439 222 -4957 2264 -2284 1426 -536 1384 -2058 -3322 -2553 -3761 831 -4987 -1336 -802 234 -1380 -2360 1492 -2082 3486 -2511 363 -1762 -778 1267 -1454 7388 -2165 3527 -631 3180 2147 422 2266 1101 563 -1571 4770 -1277 1303 -1339 -1969 -916 -1522 6455 -1542 2801 -1707 -2419 -3565 SS 20240526T103624.2Z 8912.441947 218 1 17.57 2 76.83 73.11 85.59 222.89 0.00 1 0.00 1 0 17 4.299e-01 1.040e-02 2.758e-01 5.574e-03 6.496726e-01 3.026225e-03 7.605906e-03 -6.000000e+00 2.500628e-01 231.72 -2.00 3.55 -2.00 321.21 0.00e+00 3.333042e-03 1.454896e-03 3.500046e-03 -6.000000e+00 1.098235e-02 283.06 -2.00 20.00 -2.00 320.61 0.00e+00 4.277 0.001 302.00 328.00 3 2.0282e+00 1.0277e-02 5.7112e-02 -6.0000e+00 6.2853e-01 4.2955e-02 1.4124e-02 4.0265e-02 -6.0000e+00 6.8175e-01 -1.0731e-01 1.4320e-02 2.1830e-02 -6.0000e+00 4.0200e-01 3.2760e-02 6.8076e-03 6.9088e-03 -6.0000e+00 1.6857e-01 4.9887e-04 -1.8745e-04 1.5775e-04 1.0397e-04 -6.0000e+00 1.1547e-02 -1.0049e-03 1.6964e-05 12 9 9 12 1 1 95.72 22.77 0.38 -0.00100 -0.00241 25 15 1 5 0 675.570 26.41 20.02 22.77 23.32 30.1 1052.00 -145181 900000 -87340 75112 -127671 -218403 900000 -106859 900000 -190424 109138 -126095 -123727 -34680 -72084 11180 -79814 112737 -41346 -31920 28348 39173 53837 -92107 -12599 -45721 -26701 -47735 -28687 -48364 -48888 -27924 -11492 19715 -24167 -10873 -22243 10569 -1441 7120 16511 1130 11643 5299 1433 -5593 7689 8078 -2425 7974 2937 6500 474 6212 1298 5726 3705 4971 895 -4494 7159 864 2711 5087 3615 3017 824 -100 764 4990 1560 3894 1952 3383 -215 -2563 1021 -4528 -1393 -4050 -198 -2259 -1812 -1694 -739 139 70 -122 1198 1724 675 -1413 18 -2668 -1597 -1205 270 1579 183 127 -1172 -1749 -818 -68 -1978 -680 -506 -582 73 571 741 773 181 -59 -771 -453 -11 13 -65 983 501 668 749 303 549 58 -395 467 270 -105 -483 -461 -528 -51 -48 4 339 940 137 -132 -32 -570 -437 -855 900000 -475 408 -809 -3263 900000 -686 900000 -3574 593 -1432 -1711 -257 -997 83 -1695 613 -735 -552 280 348 425 -3412 -230 -1242 -620 -1344 -652 -1409 -1690 -952 -392 600 -1116 -425 -1051 425 -81 445 1076 93 917 461 132 -565 698 755 -263 832 357 862 74 996 233 1030 705 937 171 -889 1291 182 638 1327 1023 844 230 -29 239 1738 627 1610 820 1329 -80 -877 312 -1464 -484 -1718 -95 -1270 -1119 -1109 -512 102 54 -98 949 1312 484 -965 12 -1802 -1191 -1038 265 1599 206 143 -1258 -1867 -790 -66 -2092 -753 -589 -659 90 784 1125 1243 293 -92 -1145 -642 -16 19 -103 1606 816 1045 1128 443 767 78 -570 698 415 -183 -924 -937 -1127 -114 -107 8 804 2254 330 -306 -76 -1279 -954 SS 20240526T105643.8Z 8912.456062 224 1 1.53 2 73.23 76.30 88.09 226.40 0.00 1 0.00 1 0 17 2.590e-01 1.299e-02 3.028e-01 1.349e-02 5.283125e-01 7.021946e-03 6.080068e-03 -6.000000e+00 1.501798e-01 231.72 -2.00 3.55 -2.00 320.00 0.00e+00 -2.135960e-03 2.292690e-03 7.580114e-04 -6.000000e+00 6.767898e-03 283.06 -2.00 20.00 -2.00 319.34 0.00e+00 3.413 0.001 302.00 328.00 3 2.3906e+00 2.0687e-02 4.4439e-02 -6.0000e+00 3.7733e-01 -3.2590e-02 2.5267e-02 2.9039e-02 -6.0000e+00 4.0917e-01 1.9932e-03 2.2383e-02 1.3996e-02 -6.0000e+00 2.4156e-01 -1.0908e-02 1.1502e-02 4.6096e-03 -6.0000e+00 1.0106e-01 9.0683e-04 -9.3499e-04 3.7869e-04 4.1263e-05 -6.0000e+00 6.9141e-03 -1.8644e-03 -4.4899e-05 12 9 9 12 1 1 999.00 22.90 0.40 -0.00186 -0.00889 1 14 1 5 0 758.440 26.51 19.99 22.90 24.69 30.1 1061.37 -67284 -49510 -40399 649 -150678 900000 -83005 -67660 900000 147483 -8245 -35872 900000 -34310 21622 38910 119655 9248 17444 -12557 15920 13160 -32085 30420 -15921 -20389 11840 -5509 8624 6538 12576 3667 -15468 -344 301 1504 -13886 22738 3722 656 -1588 -4462 2291 -2194 20343 -4235 -2872 1779 2334 -2988 -1037 6003 -1021 4376 7274 186 2807 -4143 648 -7235 3047 3281 2740 1153 -2414 -1469 1221 -1826 1871 1011 -2537 3489 930 3634 -2491 156 -3272 -1626 697 -3002 220 241 -2523 771 1256 416 -944 1766 1388 533 -107 462 -925 -1029 -2886 287 953 568 306 650 -1780 -154 -1725 -597 -1814 -270 -116 -927 162 1902 370 404 -942 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