File name: Pandora183s1_LondonderryNH_20240528_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240529T045251.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240528_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240528T104420.4Z 8914.447458 220 1 48.35 2 75.26 74.06 70.28 204.02 0.00 1 0.00 1 0 17 3.413e-01 2.126e-02 3.205e-01 1.579e-02 5.625862e-01 8.480442e-03 7.557661e-03 -6.000000e+00 1.970479e-01 231.84 -2.00 3.55 -2.00 321.05 0.00e+00 9.792989e-03 3.614545e-03 5.439657e-03 -6.000000e+00 9.231209e-03 283.26 -2.00 20.00 -2.00 320.44 0.00e+00 3.851 0.001 302.00 328.00 3 4.0745e+00 2.7855e-02 5.3079e-02 -6.0000e+00 4.9700e-01 2.6182e-01 3.5151e-02 3.9272e-02 -6.0000e+00 5.3964e-01 -2.8448e-01 3.1132e-02 2.3375e-02 -6.0000e+00 3.1825e-01 1.1355e-01 1.5379e-02 9.0532e-03 -6.0000e+00 1.3346e-01 9.4898e-05 -2.2344e-03 4.6557e-04 1.6328e-04 -6.0000e+00 9.2447e-03 3.9185e-03 -3.3297e-04 12 8 8 10 0 0 99.96 22.84 -0.00 0.00392 -0.01287 14 3 1 5 0 3452.640 26.51 19.99 22.84 26.08 30.3 1069.71 -76813 -87532 19040 900000 116513 -152504 -175457 -138203 900000 900000 -74386 -54125 900000 29353 900000 8251 9074 55772 -13468 -33990 49270 -36851 74901 -20083 46474 -77085 76875 8998 -42648 -51300 39805 -54157 -4496 19637 -10952 -10043 8748 5792 23754 -4810 20902 734 3573 11432 12044 21527 7821 -8012 10523 8802 435 5823 25196 16177 13470 3987 3178 -2307 12141 3567 -9496 2238 8558 3635 13788 326 2165 7073 6668 1615 4111 3035 8295 -695 -2755 5707 -6898 -9544 -1054 364 1455 883 -1387 -4943 3403 -4631 4163 -868 2846 1751 -2039 147 -3675 -7280 1463 -6125 -3336 1594 -3011 -3334 631 -2634 -563 -2687 1012 -706 -601 -570 721 -583 1769 206 991 329 -1617 -592 2253 330 1684 792 906 -20 135 2699 1782 -992 278 344 -1396 226 1007 -100 -434 -720 -712 540 541 642 30 -184 -13 -1588 -361 -1182 -1657 293 900000 1792 -4872 -7059 -4088 900000 900000 -1430 -902 900000 452 900000 180 221 929 -483 -1569 1011 -1748 1152 -824 1013 -5929 1281 288 -2242 -3091 1123 -4651 -271 1007 -730 -688 526 413 1694 -538 2017 92 460 1407 1499 2499 1061 -1300 1457 1292 75 1059 4087 3077 2750 914 747 -568 2513 793 -2483 570 2310 1154 4165 109 681 2127 2173 634 1742 1358 3491 -303 -1125 1915 -2412 -3390 -377 151 696 481 -844 -3283 2213 -3485 3022 -684 2161 1298 -1460 95 -2328 -4815 978 -5079 -3098 1607 -3461 -3846 655 -2795 -536 -2633 1031 -774 -692 -698 946 -859 2789 346 1635 522 -2445 -844 3137 491 2632 1308 1490 -33 209 3911 2492 -1367 364 465 -2144 381 1824 -194 -875 -1534 -1618 1273 1300 1566 74 -434 -30 -3377 -737 SS 20240528T105334.2Z 8914.453869 223 1 8.48 2 73.63 75.51 70.95 206.09 0.00 1 0.00 1 0 17 1.373e-01 7.236e-03 8.017e-02 2.737e-03 5.239046e-01 1.413122e-03 6.098922e-03 -6.000000e+00 7.898304e-02 231.85 -2.00 3.55 -2.00 320.17 0.00e+00 1.686523e-03 4.837509e-04 1.680609e-03 -6.000000e+00 3.442903e-03 283.26 -2.00 20.00 -2.00 319.50 0.00e+00 3.490 0.001 302.00 328.00 3 1.2889e+00 4.1985e-03 4.5011e-02 -6.0000e+00 1.9818e-01 1.9721e-02 5.1675e-03 2.9159e-02 -6.0000e+00 2.1468e-01 -1.3962e-02 4.6335e-03 1.4727e-02 -6.0000e+00 1.2753e-01 -5.6525e-03 2.3701e-03 4.2693e-03 -6.0000e+00 5.3542e-02 2.4628e-03 -2.7077e-04 7.6965e-05 4.9448e-05 -6.0000e+00 3.6257e-03 -7.7260e-04 4.2257e-05 12 9 1 12 1 1 99.99 22.85 0.31 -0.00077 -0.00281 44 55 1 5 0 187.400 26.41 19.99 22.85 26.23 30.4 1071.35 -53159 -49413 -32878 -52157 -60959 -46661 -13294 -35261 -27706 -13492 -47758 -40078 -32379 -30963 -26838 -6900 -648 -6124 7049 -15462 -6039 -16145 -6899 -3785 -3752 -8741 844 -8308 -13932 -10862 -10387 -7706 -5348 -4029 -4291 -7054 -5723 -4955 -2845 1758 -1784 164 117 -1024 282 2046 -2456 -510 -1273 -503 692 105 2315 1828 1832 1378 2053 -200 380 -1039 494 3449 2815 4729 2135 303 184 -1091 1175 1336 1404 1055 442 522 373 -1389 -1197 -1968 -1637 -936 -1400 -1018 -2485 -1151 -471 -225 444 680 1483 1056 623 -446 -1352 -906 -731 -490 -9 1088 429 -30 -595 -1811 -1126 -386 -1319 -840 -513 -1007 212 550 955 488 303 177 -514 271 14 250 484 167 -55 362 877 424 676 -371 -157 737 -304 118 -504 -565 -426 -135 -191 -85 323 411 410 208 -104 -618 -333 -490 -528 -327 -633 -740 -464 -100 -376 -316 -147 -765 -632 -566 -669 -690 -192 -19 -208 228 -664 -247 -733 -293 -169 -182 -476 43 -452 -770 -594 -640 -543 -424 -345 -358 -584 -503 -508 -351 251 -300 29 22 -200 55 398 -505 -104 -269 -110 163 28 653 560 595 468 715 -72 132 -360 172 1268 1169 2149 1047 146 85 -513 583 694 811 644 272 306 202 -756 -595 -965 -866 -522 -910 -748 -2025 -979 -425 -217 412 649 1408 1061 585 -391 -1126 -752 -662 -505 -9 1312 565 -39 -743 -2068 -1176 -405 -1510 -1015 -649 -1356 304 801 1510 809 497 277 -757 408 21 364 749 273 -90 573 1334 676 1027 -545 -221 1060 -489 193 -901 -1062 -830 -257 -389 -181 703 911 907 444 -211 -1196 -675 SS 20240528T105839.1Z 8914.457397 227 1 8.24 2 72.73 76.30 71.34 207.21 0.00 1 0.00 1 0 17 1.474e-01 8.186e-03 9.854e-02 3.530e-03 4.988089e-01 1.809837e-03 5.919524e-03 -6.000000e+00 8.479683e-02 231.85 -2.00 3.55 -2.00 319.99 0.00e+00 3.256025e-03 5.902144e-04 1.764095e-03 -6.000000e+00 3.696599e-03 283.27 -2.00 20.00 -2.00 319.32 0.00e+00 3.318 0.001 302.00 328.00 3 1.8974e+00 5.3295e-03 4.2830e-02 -6.0000e+00 2.1277e-01 2.8081e-02 6.4552e-03 2.7611e-02 -6.0000e+00 2.3051e-01 -2.0399e-02 5.5647e-03 1.4520e-02 -6.0000e+00 1.3693e-01 -6.9366e-04 2.8695e-03 4.7907e-03 -6.0000e+00 5.7466e-02 1.6074e-03 -6.2286e-04 9.9418e-05 5.5380e-05 -6.0000e+00 3.8942e-03 -4.5431e-05 -3.3139e-05 12 9 1 12 1 1 99.99 22.84 0.30 -0.00005 -0.00473 26 34 1 5 0 304.900 26.41 19.99 22.84 26.61 30.7 1075.16 42149 -67850 -33547 -72279 -55870 -24510 -25986 -39260 -42589 -15148 -51034 -28692 -36400 -40737 -4169 -21838 -4012 -15689 8912 -7767 -7926 -11915 -8676 -3744 -21676 2421 -8671 -2864 -2626 -11298 -6416 -4008 6672 -6541 -2560 -10866 -9684 -6441 -2975 1735 -381 -1674 1981 1496 753 2649 49 -580 -624 -922 3586 1101 2455 2094 992 470 59 1154 43 -76 366 2794 2236 3240 1598 -510 475 200 1945 1593 2117 950 1331 807 -195 -333 -2589 -2333 -2231 -1134 -1404 -997 -1942 -1264 39 -599 869 822 1295 894 313 206 -1939 -219 -926 -446 52 826 488 -485 -951 -1711 -783 -712 -1809 -1513 -975 -1228 368 659 627 632 435 114 -520 62 131 -20 445 515 204 799 1097 451 427 -132 254 887 -16 -92 -316 -427 -431 -92 -193 -284 587 439 158 -18 16 -663 -447 198 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