File name: Pandora183s1_LondonderryNH_20240531_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240601T050245.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240531_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240531T095549.0Z 8917.413762 161 1 49.26 2 83.39 65.97 54.48 149.46 0.00 1 0.00 1 0 33 6.740e-01 3.458e-02 4.882e-01 2.692e-02 1.103688e+00 1.598730e-02 1.193808e-02 -6.000000e+00 3.932550e-01 232.03 -2.00 3.55 -2.00 322.63 0.00e+00 -7.508132e-03 8.764870e-03 5.782422e-03 -6.000000e+00 1.899703e-02 283.57 -2.00 20.00 -2.00 322.20 0.00e+00 7.892 0.009 302.00 328.00 3 3.7364e-02 6.5501e-02 1.0581e-01 -6.0000e+00 9.9377e-01 1.9235e+00 8.0116e-02 7.6660e-02 -6.0000e+00 1.0806e+00 -2.2993e+00 5.5011e-02 3.2649e-02 -6.0000e+00 6.3426e-01 8.3590e-01 2.8568e-02 1.0039e-02 -6.0000e+00 2.6678e-01 5.6830e-05 -7.6177e-04 6.8614e-04 1.2282e-04 -6.0000e+00 1.8451e-02 2.2375e-03 -5.1933e-06 12 8 8 10 0 0 12.88 22.94 0.50 0.00224 -0.00349 50 10 1 5 0 985.170 26.51 20.00 22.94 14.30 29.6 983.82 900000 71488 1077 104624 -71821 -14254 -65182 900000 -57460 900000 900000 -61869 900000 41779 16251 7647 900000 103733 22593 67851 -10175 56343 152946 77283 -23479 12880 -9105 -58247 -8898 -50702 -6986 -59030 -60128 10784 16768 -38370 185307 29276 93511 50686 66056 213659 -2004 125416 73708 102010 24986 30933 126764 -17085 282128 6900 370582 68766 78786 39852 -20091 40353 16096 225555 64806 80883 136816 64571 80559 -11105 43558 49339 57193 13408 69266 59986 14668 29460 -19214 39617 1438 26096 5624 24006 14035 -6718 16073 -1034 4164 -2521 12124 9451 11447 3178 561 2201 -12022 -9802 1332 4208 -5592 9045 -5837 131 151 -7419 -8758 -7734 -3090 -1765 -6173 -2214 -6745 -3485 -344 -1067 263 -392 -1423 -6127 2303 310 5693 2036 3065 3741 192 2590 -1099 4382 -1361 4143 1466 3049 -106 -939 -1650 -1780 537 -1213 2265 940 1004 -110 -665 -1465 -1655 900000 1875 50 2744 -4637 -431 -3156 900000 -2782 900000 900000 -3120 900000 1096 590 368 900000 2721 988 1780 -534 1478 4011 2027 -1334 507 -418 -3819 -311 -2660 -275 -4645 -5388 495 660 -2348 4860 1024 2453 2175 2677 5604 -162 3289 2460 2675 1251 1475 3325 -1466 7399 576 9719 3607 3945 3041 -2826 2983 1382 5916 2936 3278 3588 4003 4610 -1589 3635 4117 4909 2046 6606 6436 2378 3723 -3436 3401 168 2489 764 3320 2577 -1778 3794 -308 1241 -842 3613 2929 3412 1075 181 664 -4194 -3651 524 1943 -3403 5599 -4685 101 108 -5059 -5329 -4544 -1847 -1102 -4275 -1614 -5891 -3491 -390 -1357 346 -522 -1870 -8260 2905 420 7690 2899 4141 4690 238 3050 -1309 4815 -1563 4933 2153 5247 -216 -2128 -4094 -4817 1535 -3711 6789 2874 3018 -315 -1738 -3518 -3820 SS 20240531T100714.9Z 8917.421700 164 1 49.71 2 81.46 67.81 53.44 152.65 0.00 1 0.00 1 0 25 5.768e-01 1.726e-02 3.368e-01 7.284e-03 9.590563e-01 4.227296e-03 1.060450e-02 -6.000000e+00 3.320852e-01 232.03 -2.00 3.55 -2.00 322.38 0.00e+00 3.143731e-03 2.694006e-03 5.467367e-03 -6.000000e+00 1.453098e-02 283.57 -2.00 20.00 -2.00 321.94 0.00e+00 6.345 0.005 302.00 328.00 3 2.4646e-01 1.8012e-02 8.6734e-02 -6.0000e+00 8.3354e-01 8.2069e-01 2.7334e-02 6.3037e-02 -6.0000e+00 9.0330e-01 -1.0944e+00 2.7055e-02 3.4945e-02 -6.0000e+00 5.3619e-01 4.2230e-01 1.1874e-02 1.1427e-02 -6.0000e+00 2.2638e-01 2.7598e-04 -4.6991e-04 1.9274e-04 1.9977e-04 -6.0000e+00 1.5370e-02 9.4174e-04 3.7335e-05 12 8 8 10 0 0 97.30 22.91 0.38 0.00094 -0.00259 106 22 1 5 0 468.870 26.51 20.00 22.91 15.34 29.6 990.73 900000 -222002 -128230 -150644 -197792 -126343 -142632 -149866 -119656 -179547 -94036 -228717 -114772 -190877 -149835 11729 -44116 -71787 23117 -25910 -21918 -9731 -58984 -3985 -94234 -73050 -70718 -45191 -4916 -61287 -18202 -46714 -19122 -25418 39437 -28821 8692 78947 19996 43989 14835 57277 29432 30340 19377 36312 55241 6140 12786 5535 34621 34381 43169 50821 58750 38877 20367 37736 31189 11502 14145 22621 25862 32329 24889 9833 29780 5335 16682 21742 18739 14189 8472 12253 1120 79 -6517 -5423 -321 4091 7135 -845 7338 727 2810 2356 1135 1921 1022 2313 1121 -3707 -4873 -2851 -3834 -2209 -325 -922 -585 -2893 -2971 -3730 -1542 -2290 -1541 -3332 -1322 -1481 -1636 -760 286 -15 -402 -580 -1015 -981 219 29 464 899 1621 1297 2197 1002 1243 1327 352 994 588 259 448 -113 -324 -171 71 -465 36 1075 559 111 -179 -1140 -1573 900000 -4367 -1051 -1481 -2702 -897 -1097 -1331 -850 -2444 -668 -5686 -1155 -5423 -3636 83 -522 -1232 164 -307 -246 -92 -908 -38 -2343 -1513 -1553 -730 -51 -1187 -282 -1207 -444 -689 535 -726 157 816 452 937 479 1294 912 940 663 1055 1355 258 537 272 1431 1621 2063 2461 2807 2360 1526 2339 1953 832 996 1592 2037 2776 2523 1168 2923 706 2417 3159 3421 2822 1745 2245 204 13 -1060 -909 -59 886 1804 -271 2424 274 1100 981 500 860 458 982 450 -1477 -1942 -1193 -1887 -1283 -220 -739 -521 -2677 -2579 -2888 -1038 -1527 -1091 -2544 -1048 -1281 -1601 -859 368 -22 -588 -843 -1430 -1343 301 42 707 1394 2414 1826 2928 1310 1571 1625 427 1291 904 467 910 -252 -775 -442 198 -1360 108 3174 1637 308 -459 -2714 -3621 SS 20240531T105333.1Z 8917.453856 184 1 14.09 2 73.42 75.09 50.32 166.43 0.00 1 0.00 1 0 17 1.908e-01 7.794e-03 1.725e-01 3.643e-03 5.769978e-01 1.911680e-03 6.735125e-03 -6.000000e+00 1.098191e-01 232.03 -2.00 3.55 -2.00 320.44 0.00e+00 2.607305e-03 7.241423e-04 1.966625e-03 -6.000000e+00 4.790492e-03 283.57 -2.00 20.00 -2.00 319.80 0.00e+00 3.449 0.001 302.00 328.00 3 2.1449e+00 5.8343e-03 4.6903e-02 -6.0000e+00 2.7565e-01 5.6108e-02 7.3999e-03 3.2441e-02 -6.0000e+00 2.9859e-01 -2.9581e-02 6.9852e-03 1.6929e-02 -6.0000e+00 1.7738e-01 -3.7984e-04 3.5103e-03 5.2363e-03 -6.0000e+00 7.4420e-02 9.8904e-04 -4.8397e-04 1.0067e-04 6.6083e-05 -6.0000e+00 5.0406e-03 1.3319e-03 -1.7660e-05 12 9 1 12 9 1 99.93 22.95 0.26 0.00133 -0.00230 21 16 1 5 0 639.820 26.62 19.99 22.95 16.23 29.5 996.81 18141 8688 -46211 -36218 -80414 -67286 -113527 -44627 -86683 -36346 -45257 14458 -23790 -49218 -34636 -17036 -4154 -34852 -21545 -15237 -15356 2569 11943 -3003 -2750 -12085 -6450 -18715 -8426 -12646 -15271 -12260 -9308 -7702 -2568 -13365 -6869 -884 -10927 -651 -3495 4997 -1918 1646 -1400 -5950 2860 929 5519 -52 880 309 3408 2021 306 3039 985 927 472 1098 336 2531 3353 4428 1993 -16 216 -194 820 1123 1716 1420 696 842 -622 -841 -3479 -1562 -1678 -2348 -675 -1279 -1605 -822 -177 -324 186 -328 1188 1729 824 409 -1244 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