File name: Pandora183s1_LondonderryNH_20240605_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240606T045440.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240605_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240605T111919.3Z 8922.471751 124 1 49.57 2 68.59 78.47 57.33 86.83 0.00 1 0.00 1 0 17 7.911e-02 7.874e-03 5.239e-02 2.804e-03 4.259033e-01 1.436754e-03 5.104674e-03 -6.000000e+00 4.558994e-02 232.35 -2.00 3.55 -2.00 319.90 0.00e+00 1.309319e-03 4.445232e-04 1.726669e-03 -6.000000e+00 1.990492e-03 284.09 -2.00 20.00 -2.00 319.18 0.00e+00 2.714 0.000 302.00 328.00 3 3.2089e+00 4.1812e-03 3.6032e-02 -6.0000e+00 1.1450e-01 3.6542e-03 5.0169e-03 2.4565e-02 -6.0000e+00 1.2397e-01 -1.0505e-02 4.1144e-03 1.1931e-02 -6.0000e+00 7.3649e-02 -2.7424e-03 2.1278e-03 3.1680e-03 -6.0000e+00 3.0911e-02 8.5158e-04 -2.3499e-04 8.2158e-05 3.8895e-05 -6.0000e+00 2.0893e-03 -3.4118e-04 4.5720e-05 11 8 0 10 0 0 99.46 22.84 0.30 -0.00034 -0.00211 50 10 1 5 0 991.040 26.51 19.99 22.84 25.78 30.3 1062.08 13037 -27159 -23246 -5412 23699 -44364 -32716 -31303 -22348 -7932 -18443 -6419 -17723 -7201 -14844 -12177 1624 583 -4023 -9939 7239 -6120 -3575 -7528 -7329 -8250 -1431 -7183 -3157 -3636 -9196 -1140 -4732 -2397 -2522 -517 -2676 -4764 -2844 -801 -2564 881 -1046 1097 1315 127 4 1110 -1805 253 139 -519 376 2078 2637 2035 2012 -266 -134 303 1752 2323 2752 4590 1331 456 -661 -346 -139 1157 2021 604 1502 -62 549 -628 -1497 -3263 -1664 -859 -1692 -1166 -2506 -1256 -866 -496 552 697 1100 1024 511 -394 -1273 -814 -951 -352 -63 909 863 -324 -803 -1554 -1209 -450 -883 -1782 -640 -569 482 534 784 543 414 215 -426 -86 -216 222 589 664 315 777 803 84 722 -522 -290 687 29 -375 -600 -770 -459 57 -219 -234 497 983 75 136 -26 -681 -405 134 -489 -434 -84 271 -937 -643 -685 -511 -172 -454 -145 -520 -231 -620 -578 74 29 -222 -613 391 -377 -219 -513 -538 -646 -107 -550 -220 -254 -745 -97 -472 -252 -256 -54 -307 -651 -465 -154 -514 201 -254 267 321 32 1 275 -463 65 38 -159 123 718 952 763 776 -105 -52 115 670 953 1248 2246 698 229 -317 -163 -70 659 1268 404 997 -40 328 -341 -745 -1593 -850 -501 -1143 -880 -2082 -1085 -796 -488 567 740 1166 1050 490 -350 -1060 -665 -838 -347 -70 1128 1157 -437 -1022 -1810 -1303 -490 -1048 -2260 -842 -790 706 773 1222 876 654 322 -654 -125 -313 335 945 1125 541 1297 1298 131 1071 -749 -397 949 45 -627 -1077 -1441 -883 104 -428 -480 1037 2082 160 282 -52 -1290 -823 SS 20240605T112936.6Z 8922.478896 127 1 50.09 2 66.74 80.08 55.49 88.44 0.00 1 0.00 1 0 17 9.335e-02 8.148e-03 6.081e-02 3.837e-03 3.950879e-01 1.975353e-03 4.764749e-03 -6.000000e+00 5.379126e-02 232.35 -2.00 3.55 -2.00 319.80 0.00e+00 1.007790e-03 5.855707e-04 1.548969e-03 -6.000000e+00 2.348663e-03 284.09 -2.00 20.00 -2.00 319.08 0.00e+00 2.512 0.000 302.00 328.00 3 3.8284e+00 5.7273e-03 3.3427e-02 -6.0000e+00 1.3510e-01 9.3591e-03 6.8109e-03 2.2842e-02 -6.0000e+00 1.4628e-01 -1.3538e-03 5.3650e-03 1.0927e-02 -6.0000e+00 8.6901e-02 -7.9142e-03 2.7698e-03 2.8877e-03 -6.0000e+00 3.6468e-02 5.7522e-04 -4.1629e-04 1.1355e-04 3.4002e-05 -6.0000e+00 2.4655e-03 -8.2945e-05 1.5933e-05 11 8 0 10 0 0 99.83 22.85 0.41 -0.00008 -0.00321 51 11 1 5 0 982.040 26.51 20.01 22.85 26.56 30.3 1067.88 -16258 30749 -31465 25553 -46469 -34914 -9797 -47764 13983 -24785 24639 -4498 19164 -20625 -11214 -6162 -8387 45 -8174 9678 -6575 5859 -4636 141 -3459 831 -191 -9869 -2730 -8794 -1282 -2470 5237 5543 -6373 -2022 -2435 -4568 -288 -7005 -99 -2967 -233 -643 140 -284 3936 -2070 -772 229 1524 2553 1733 1751 852 327 987 1617 1298 324 1500 722 2842 3531 748 -325 611 139 210 1815 -60 2112 485 1753 -470 -1237 -1288 -2306 130 -1627 -981 -1090 -2537 -1271 -275 -497 317 626 1045 1316 488 853 -921 -47 -424 -1027 606 120 -39 -328 -969 -1660 -1336 -964 -1781 -1634 -1408 -421 21 937 675 547 339 430 -318 6 -230 132 904 1189 6 221 667 275 480 -93 322 668 426 -252 97 -736 -290 -148 14 -336 89 864 -86 15 -363 -226 -469 -299 412 -844 382 -1290 -806 -183 -1474 266 -757 469 -118 495 -875 -565 -342 -519 3 -573 596 -494 389 -347 11 -294 72 -17 -930 -226 -766 -113 -248 545 618 -770 -224 -289 -646 -48 -1480 -22 -722 -57 -163 35 -72 963 -534 -197 59 414 751 554 597 308 122 377 615 533 132 619 324 1378 1860 418 -174 303 68 110 1068 -40 1445 338 1160 -296 -704 -665 -1153 67 -977 -671 -836 -2138 -1113 -255 -494 331 673 1123 1364 474 757 -769 -39 -371 -1013 663 149 -52 -436 -1213 -1904 -1422 -1044 -2107 -2046 -1842 -574 30 1456 1128 857 571 682 -470 9 -319 192 1389 1928 10 359 1045 416 689 -128 421 886 617 -401 164 -1302 -526 -280 29 -716 194 1900 -192 33 -748 -445 -905 SS 20240605T113520.3Z 8922.482873 131 1 23.73 2 65.70 80.98 54.46 89.35 0.00 1 0.00 1 0 17 3.432e-02 7.866e-03 1.055e-02 1.132e-03 3.798807e-01 5.769732e-04 4.528184e-03 -6.000000e+00 1.978061e-02 232.35 -2.00 3.55 -2.00 318.97 0.00e+00 1.405716e-03 1.322773e-04 1.036696e-03 -6.000000e+00 8.635885e-04 284.09 -2.00 20.00 -2.00 318.21 0.00e+00 2.413 0.000 302.00 328.00 3 1.8377e+00 1.6049e-03 3.1609e-02 -6.0000e+00 4.9681e-02 -5.4401e-03 1.8458e-03 2.0569e-02 -6.0000e+00 5.3785e-02 -1.0355e-02 1.3106e-03 1.0140e-02 -6.0000e+00 3.1953e-02 -1.3925e-03 6.8568e-04 2.8659e-03 -6.0000e+00 1.3414e-02 4.7735e-03 -1.0829e-05 3.2440e-05 3.0406e-05 -6.0000e+00 9.0625e-04 -7.7220e-04 8.1109e-05 12 9 1 12 1 1 98.88 22.85 0.28 -0.00077 -0.00085 86 38 1 5 0 272.690 26.41 20.06 22.85 26.97 30.4 1071.42 -2780 -12393 -2843 -14174 -8894 -11535 -13453 -209 -10884 -3881 -13947 -9944 -7515 -8930 -4172 -2832 -1252 -2838 1644 365 -35 -160 514 277 -2651 1120 -712 -2216 -4199 -3777 -2250 -1301 1955 -2383 -3966 -5508 -4242 -3135 -482 -156 -916 202 -822 -563 41 395 -542 212 -948 -503 987 838 1419 1112 1397 1676 1502 430 352 582 726 2271 2603 3088 1481 356 -284 -1585 1098 1035 1190 1089 811 947 -17 -624 -1724 -2445 -1595 -1602 -1493 -1252 -2045 -1382 -426 -396 392 587 1117 735 255 -391 -1609 -1171 -1192 -474 360 867 208 -386 -521 -1392 -1103 -638 -1333 -1309 -597 -607 276 795 1224 796 546 273 -407 -214 56 -58 640 234 321 575 994 372 754 -300 -380 697 7 24 -379 -590 -642 -319 -163 -96 399 700 276 72 -20 -675 -717 -74 -420 -94 -516 -277 -343 -422 -7 -468 -169 -683 -480 -404 -583 -310 -240 -114 -278 163 38 -4 -18 57 33 -345 148 -98 -297 -540 -478 -304 -196 318 -435 -705 -950 -772 -657 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