File name: Pandora183s1_LondonderryNH_20240612_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240613T045927.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240612_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240612T105825.2Z 8929.457236 102 1 50.32 2 72.20 74.56 121.83 21.27 0.00 1 0.00 1 0 17 2.623e-01 1.113e-02 2.269e-01 7.206e-03 5.068231e-01 3.814209e-03 6.020217e-03 -6.000000e+00 1.523529e-01 232.78 -2.00 3.55 -2.00 320.56 0.00e+00 9.558892e-04 1.458298e-03 2.503820e-03 -6.000000e+00 6.618919e-03 284.80 -2.00 20.00 -2.00 319.89 0.00e+00 3.225 0.001 302.00 328.00 3 3.8647e+00 1.1854e-02 4.3694e-02 -6.0000e+00 3.8343e-01 7.5841e-02 1.4960e-02 3.1374e-02 -6.0000e+00 4.1518e-01 -4.1926e-02 1.3391e-02 1.4771e-02 -6.0000e+00 2.4570e-01 9.1047e-03 6.6927e-03 3.8026e-03 -6.0000e+00 1.0267e-01 2.3716e-04 -3.1531e-04 2.1066e-04 5.2990e-05 -6.0000e+00 7.0363e-03 3.2378e-04 1.5954e-05 12 8 8 10 0 0 97.10 23.05 0.36 0.00032 -0.00205 16 3 1 5 0 3144.400 26.73 20.00 23.05 22.83 30.1 1034.22 -67595 -90865 9309 62908 -101619 -124206 137559 900000 -97015 19931 10055 -1734 -40138 -76917 -4264 35030 -10029 -9774 -196 -15390 64305 232 11777 43395 -11168 34247 12964 -8208 21313 53769 -11162 13458 -2217 -2701 -1636 -3764 5249 -3902 -645 -7863 -7974 1200 -6780 3764 11874 617 -8474 -4430 3728 4134 -2979 4269 8188 576 512 -1563 3848 -2506 1152 -359 3128 -195 6889 4376 299 -1399 76 1177 1766 411 2767 3544 3779 3001 330 -3788 348 293 1140 -4105 -1224 -546 -1567 -3040 -518 -1305 1157 905 17 2028 -670 25 -2052 178 -2821 -603 1165 514 255 -505 -139 -1458 -354 -1040 -357 -2267 -1106 -961 530 1190 857 222 672 -297 -248 -286 -224 219 114 935 -11 1183 596 328 672 -593 -181 1186 -349 -223 -215 -537 -1486 125 -251 6 1147 753 -252 -249 133 -613 -305 -731 -1596 65 442 -1964 -2836 967 900000 -2329 163 94 -19 -776 -2657 -87 574 -288 -303 -6 -577 1130 8 359 1137 -549 1138 547 -414 762 1408 -627 688 -152 -202 -117 -264 362 -346 -68 -1075 -1238 182 -1169 599 1752 103 -1564 -792 626 718 -603 892 1789 147 138 -445 1072 -746 322 -100 859 -60 2205 1593 119 -542 28 424 683 185 1352 1806 1919 1466 168 -1802 145 119 496 -2186 -733 -367 -1160 -2411 -428 -1163 1061 859 17 1837 -580 20 -1555 131 -2345 -557 1205 605 325 -649 -167 -1601 -354 -1062 -392 -2682 -1357 -1247 729 1785 1402 380 1129 -478 -373 -408 -319 325 180 1540 -18 1889 925 491 956 -817 -238 1581 -522 -369 -382 -1005 -2906 254 -545 13 2636 1768 -597 -568 285 -1259 -609 SS 20240612T112613.9Z 8929.476550 114 1 49.97 2 67.24 78.86 119.86 28.50 0.00 1 0.00 1 0 17 6.047e-02 7.227e-03 3.227e-02 2.356e-03 4.105537e-01 1.213498e-03 4.800119e-03 -6.000000e+00 3.489924e-02 232.78 -2.00 3.55 -2.00 319.54 0.00e+00 1.103641e-03 3.331280e-04 9.337800e-04 -6.000000e+00 1.525936e-03 284.80 -2.00 20.00 -2.00 318.78 0.00e+00 2.563 0.000 302.00 328.00 3 3.1823e+00 3.4713e-03 3.3867e-02 -6.0000e+00 8.7728e-02 3.7748e-02 4.0817e-03 2.2261e-02 -6.0000e+00 9.4942e-02 3.0451e-04 3.1674e-03 1.0987e-02 -6.0000e+00 5.6406e-02 -8.4170e-03 1.6500e-03 3.0912e-03 -6.0000e+00 2.3665e-02 1.0026e-03 -2.2461e-04 6.8037e-05 3.2447e-05 -6.0000e+00 1.5972e-03 3.4591e-04 3.2167e-05 11 8 0 10 0 0 95.60 23.02 0.27 0.00035 -0.00134 38 8 1 5 0 1314.620 26.62 20.01 23.02 22.77 30.1 1034.24 -27111 -8557 -16811 -2448 -12620 -9978 -19796 -24856 -16151 -24171 -23911 -18733 3464 -19139 -10084 -4641 -5685 463 734 -1684 -2910 -3272 2758 -2232 -890 -3449 -196 -3879 -3947 -3684 -398 2669 1967 -2681 -6009 -5045 -4693 -990 -2742 149 153 -1019 746 -1626 119 -716 -216 -1631 500 -349 -502 1032 1492 2208 789 2314 526 -380 998 51 1896 2291 2818 2840 971 583 -594 -790 572 1057 1292 1405 681 725 -6 -955 -381 -3124 -1208 -1110 -1137 -982 -2525 -1184 -660 -749 -372 497 1267 1261 265 180 -432 -862 -922 -462 710 965 147 -50 -667 -1491 -1206 22 -890 -1407 -1068 -336 -11 667 670 446 628 131 -510 -170 155 60 254 130 59 625 781 414 422 -35 -81 572 229 -136 -287 -483 -480 -112 -99 -237 521 651 292 156 -325 -685 -540 -540 -180 -414 -52 -266 -192 -438 -654 -445 -787 -794 -610 104 -871 -503 -255 -346 28 48 -118 -214 -241 195 -177 -75 -315 -18 -351 -337 -344 -39 289 241 -371 -825 -657 -652 -155 -532 34 39 -279 209 -477 34 -211 -63 -483 146 -105 -162 358 556 874 332 989 235 -172 435 22 824 1069 1449 1599 576 329 -318 -418 319 671 907 1035 506 516 -4 -576 -207 -1680 -676 -712 -835 -808 -2284 -1112 -658 -729 -381 521 1320 1397 275 172 -384 -756 -870 -488 836 1157 191 -65 -814 -1833 -1375 26 -1118 -1710 -1354 -446 -16 1014 1094 752 1031 204 -737 -231 209 85 384 208 96 981 1186 606 646 -51 -114 811 356 -210 -475 -832 -850 -208 -195 -492 1097 1396 630 325 -650 -1310 -1006 SS 20240612T113146.3Z 8929.480397 118 1 12.93 2 66.24 79.72 119.40 29.90 0.00 1 0.00 1 0 17 4.881e-02 7.626e-03 2.331e-02 2.553e-03 3.919890e-01 1.296975e-03 4.653488e-03 -6.000000e+00 2.817177e-02 232.78 -2.00 3.55 -2.00 318.90 0.00e+00 1.365478e-03 2.948818e-04 8.346168e-04 -6.000000e+00 1.231763e-03 284.80 -2.00 20.00 -2.00 318.13 0.00e+00 2.464 0.000 302.00 328.00 3 2.7520e+00 3.6019e-03 3.2412e-02 -6.0000e+00 7.0817e-02 3.1102e-02 4.1472e-03 2.1093e-02 -6.0000e+00 7.6639e-02 -7.7049e-03 2.9330e-03 1.0363e-02 -6.0000e+00 4.5532e-02 -2.2324e-03 1.5343e-03 2.9292e-03 -6.0000e+00 1.9104e-02 1.7486e-03 -2.1486e-04 7.2180e-05 2.9466e-05 -6.0000e+00 1.2892e-03 7.9011e-06 3.5132e-05 12 9 1 12 1 1 95.95 23.01 0.30 0.00001 -0.00161 15 13 1 5 0 807.320 26.62 20.00 23.01 22.98 30.3 1036.35 -3665 -14343 -6714 -10194 -33663 -12732 -9609 -9343 -14921 -17811 -19055 -4361 -3175 -9317 -8972 -2088 1372 -2951 572 1034 -1791 2745 2520 -567 -1305 -3840 -830 -1518 -329 -4861 -909 -4909 2050 -1402 -4896 -4985 -5987 -805 -2793 800 -1221 1790 -1411 -692 1507 205 1317 -1784 542 -948 1585 998 1320 1461 1712 1667 1451 245 339 618 722 1535 2357 2348 1534 502 59 -781 604 1570 673 1508 166 605 42 -381 -1942 -922 -1084 -1251 -1208 -1477 -2182 -1867 -301 -955 335 373 710 585 299 218 -772 -459 -904 -585 547 989 -89 -561 -354 -1819 -713 -387 -1600 -1342 -637 -478 117 729 999 542 559 191 -321 116 113 -79 462 217 485 660 536 665 316 -257 94 830 345 106 -198 -436 -333 -311 -182 -86 458 587 35 8 -110 -645 -654 -95 -484 -225 -348 -1311 -375 -313 -342 -658 -878 -968 -197 -162 -608 -697 -175 121 -290 58 109 -201 294 274 -68 -169 -536 -115 -203 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