File name: Pandora183s1_LondonderryNH_20240613_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240619T010849.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240613_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240613T095246.0Z 8930.411644 70 1 49.48 2 83.44 64.20 128.92 350.83 0.00 1 0.00 1 0 17 5.526e-01 3.336e-02 4.419e-01 2.390e-02 1.032380e+00 1.419555e-02 1.163943e-02 -6.000000e+00 3.270478e-01 232.84 -2.00 3.55 -2.00 322.54 0.00e+00 -1.778271e-02 8.213669e-03 1.778148e-03 -6.000000e+00 1.485590e-02 284.90 -2.00 20.00 -2.00 322.08 0.00e+00 7.940 0.009 302.00 328.00 3 5.5239e-02 5.9597e-02 1.0094e-01 -6.0000e+00 8.2451e-01 1.6276e+00 7.5948e-02 7.1766e-02 -6.0000e+00 8.9552e-01 -2.1498e+00 5.2834e-02 2.9672e-02 -6.0000e+00 5.2856e-01 8.3983e-01 2.5569e-02 1.6152e-02 -6.0000e+00 2.2103e-01 6.6351e-05 -1.4898e-03 6.3296e-04 2.1688e-04 -6.0000e+00 1.4904e-02 2.0985e-03 -1.5846e-06 12 8 8 10 0 0 7.43 23.05 0.51 0.00210 -0.00910 55 11 1 5 0 899.470 26.73 20.00 23.05 19.16 30.3 1009.44 59411 900000 900000 240456 124705 900000 -119817 900000 -51151 -5627 114098 -62027 162979 7110 57594 -39204 84140 900000 900000 41819 87419 100039 6278 32410 26823 40763 -12047 90296 28704 900000 -4199 -12466 112106 -12395 121297 6205 -10558 90064 -23826 163742 23241 900000 49442 35096 46580 49139 869 -9078 28754 -3043 252624 18196 87945 50286 83611 69002 65344 69933 -27344 74796 44459 2670 128337 38656 51405 7629 14921 -7404 12364 5708 38219 29945 14072 55588 -3641 49026 -20668 1288 451 -13215 22813 18615 22689 -4268 12218 2556 18659 -6513 1228 11460 -11748 -2188 -10396 6586 -17409 -2367 -6034 -5772 4943 -179 -405 -7659 2203 -11564 -1695 -1854 -819 -4792 -955 580 1938 2579 -166 -14 -2542 -2279 -225 293 1369 -1787 1949 3080 3610 292 782 2023 -3041 3062 2418 1525 962 -332 87 -3768 -87 -944 2658 2031 828 -228 -222 -2371 -1672 1595 900000 900000 5596 2902 900000 -10510 900000 -2747 -201 2655 -3886 3793 267 1564 -3041 1958 900000 900000 1379 2035 2328 244 1069 1040 1423 -678 2101 779 900000 -163 -604 2609 -697 2823 241 -491 2096 -1756 3811 1573 900000 2615 2005 2168 2079 57 -653 1460 -225 5879 1347 3535 3192 4069 4088 4148 4143 -3934 3481 2634 249 3801 3190 4024 920 1673 -1096 1674 954 5094 4498 2412 5763 -601 4149 -3236 166 67 -2712 3909 3899 5136 -1355 3490 849 5487 -2508 431 3814 -4593 -739 -3799 2192 -8590 -1201 -3764 -4205 3612 -140 -299 -5419 1256 -7428 -1057 -1230 -570 -3781 -822 578 2214 3247 -224 -20 -3443 -3002 -294 401 1953 -2695 2739 4029 4487 366 949 2358 -3659 3741 3522 2644 1908 -733 208 -10112 -245 -2804 7739 5993 2437 -639 -567 -5666 -3794 SS 20240613T100400.7Z 8930.419452 73 1 49.76 2 81.57 66.00 129.22 354.26 0.00 1 0.00 1 0 25 6.084e-01 1.616e-02 2.936e-01 6.134e-03 8.701888e-01 3.521570e-03 1.008522e-02 -6.000000e+00 3.512077e-01 232.84 -2.00 3.55 -2.00 322.27 0.00e+00 6.110896e-03 2.235271e-03 7.613493e-03 -6.000000e+00 1.611422e-02 284.90 -2.00 20.00 -2.00 321.80 0.00e+00 6.416 0.005 302.00 328.00 3 1.0100e-02 1.4872e-02 8.7774e-02 -6.0000e+00 8.8340e-01 6.1011e-01 2.2327e-02 6.6303e-02 -6.0000e+00 9.5636e-01 -8.6305e-01 2.2157e-02 3.5092e-02 -6.0000e+00 5.6771e-01 3.4205e-01 9.7683e-03 1.0562e-02 -6.0000e+00 2.3870e-01 3.7902e-04 -5.3983e-04 1.6790e-04 2.1946e-04 -6.0000e+00 1.6205e-02 1.1057e-03 1.0445e-05 12 8 8 10 0 0 1.96 23.05 0.35 0.00111 -0.00295 151 31 1 5 0 329.450 26.62 19.99 23.05 20.38 30.2 1017.91 -234882 -178887 -152928 -35145 -215385 -149410 -142117 -184955 -112096 -241421 900000 -234858 -123287 -138475 92394 -61456 -83540 -90094 -82484 30674 -95523 -11067 -60588 -64257 29896 -92441 -32630 -47001 -46478 -66346 23429 18240 48116 40829 -13452 -28002 -33063 5218 15068 58083 47509 25255 29855 40877 61646 -17762 38299 3457 16905 31204 30154 35974 756 33987 15856 43177 13410 22384 22221 12595 14560 11131 18933 15514 27576 11570 14172 12818 9017 10493 14023 14352 5377 11674 8177 2157 5810 -6269 4823 -1968 4061 -1505 -554 501 2671 -345 1285 1955 309 3559 -526 -890 -2978 -2655 -3664 -4524 -475 -198 -165 -1993 -2241 -3207 -2731 -1293 -4196 -2827 -2585 481 -790 -345 627 95 510 -1226 -953 -1012 -241 543 694 741 1120 1854 1347 2008 743 242 929 722 296 -273 432 -662 -69 60 1 -88 485 574 402 -150 -690 -355 -1288 -3782 -1975 -1407 -210 -3171 -1117 -992 -2120 -670 -5535 900000 -5619 -1229 -2139 553 -704 -1374 -1751 -1603 199 -2190 -105 -936 -1089 209 -2258 -479 -767 -733 -1371 242 248 576 577 -315 -716 -935 116 369 1105 1137 810 958 1200 1475 -956 1208 162 735 1272 1394 1780 59 2070 1233 2653 1137 1716 1631 979 1124 974 1771 1738 2984 1472 1757 1855 1505 2002 2868 3056 1232 2339 1526 379 921 -1159 917 -489 1137 -518 -211 201 1117 -158 608 945 152 1626 -234 -375 -1254 -1180 -1898 -2817 -337 -163 -151 -1890 -1998 -2571 -1954 -903 -3240 -2285 -2209 432 -807 -405 831 138 752 -1810 -1347 -1388 -333 783 1060 1165 1711 2671 1869 2684 973 309 1148 957 459 -494 868 -1459 -162 151 2 -251 1396 1671 1161 -414 -1769 -841 -2977 SS 20240613T101957.8Z 8930.430530 78 1 49.64 2 78.88 68.51 129.44 359.17 0.00 1 0.00 1 0 17 5.924e-01 9.188e-03 1.379e-01 2.096e-03 7.151211e-01 1.140915e-03 8.332038e-03 -6.000000e+00 3.419691e-01 232.84 -2.00 3.55 -2.00 321.57 0.00e+00 2.989724e-03 6.188335e-04 5.115979e-03 -6.000000e+00 1.495566e-02 284.90 -2.00 20.00 -2.00 321.02 0.00e+00 5.000 0.002 302.00 328.00 3 4.0358e-03 4.2088e-03 6.7792e-02 -6.0000e+00 8.5972e-01 1.0812e-01 6.1688e-03 5.1034e-02 -6.0000e+00 9.3043e-01 -1.5556e-01 6.4499e-03 2.5613e-02 -6.0000e+00 5.5278e-01 5.0066e-02 2.9615e-03 6.8081e-03 -6.0000e+00 2.3185e-01 1.7728e-03 -3.9732e-04 5.7696e-05 1.3105e-04 -6.0000e+00 1.5651e-02 1.0701e-03 -6.7909e-07 11 8 0 10 0 0 5.77 23.02 0.28 0.00107 -0.00192 334 69 1 5 0 148.520 26.62 19.99 23.02 22.42 30.3 1032.00 -190595 -214192 -183973 -184704 -216907 -98939 -248027 -141638 -210168 -67157 -188973 -166354 -122228 -136284 -60985 -95410 -5095 -83631 -43022 -48284 -26848 -43578 -61904 -17025 -38307 -6981 -49545 -35390 -38435 -45674 -1789 -38733 1690 -23769 -5029 -19538 -4600 -10262 -8191 2702 -9895 11549 -3317 5287 3110 5214 6302 -2406 6431 -642 11625 3744 6408 6237 2657 5753 2936 5304 672 4143 3340 4938 3323 4987 5328 1785 2407 -565 3595 1553 4081 2843 1754 1664 -941 -1286 -3551 -2267 -3669 -1384 -949 -837 -1669 -1224 469 -193 1135 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