File name: Pandora183s1_LondonderryNH_20240617_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240618T213348.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240617_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240617T101920.2Z 8934.430095 123 1 50.09 2 79.03 68.17 135.87 298.60 0.00 1 0.00 1 0 17 4.998e-01 2.654e-02 4.049e-01 1.978e-02 6.193426e-01 1.093612e-02 8.300696e-03 -6.000000e+00 2.942674e-01 232.92 -2.00 3.55 -2.00 321.54 0.00e+00 1.731343e-02 5.404368e-03 4.709472e-03 -6.000000e+00 1.352563e-02 285.28 -2.00 20.00 -2.00 320.95 0.00e+00 5.063 0.002 302.00 328.00 3 3.0627e+00 3.8644e-02 6.1301e-02 -6.0000e+00 7.4056e-01 4.7022e-01 5.0595e-02 3.5268e-02 -6.0000e+00 8.0265e-01 -5.9241e-01 4.3337e-02 2.7395e-02 -6.0000e+00 4.7223e-01 2.3009e-01 2.0544e-02 1.6717e-02 -6.0000e+00 1.9730e-01 7.7685e-05 -1.5825e-03 5.8140e-04 2.3584e-04 -6.0000e+00 1.3553e-02 1.8990e-03 2.1486e-05 12 8 8 10 0 0 99.20 23.01 0.75 0.00190 -0.00999 21 4 1 5 0 2384.630 26.62 19.99 23.01 22.37 30.2 1027.86 163399 182926 900000 -57956 -78327 900000 -200934 900000 900000 -192614 -139316 95241 48276 55346 104223 23778 -12255 -50808 -36364 26059 49179 85410 -32820 -55634 30014 900000 -23880 -60238 172626 25536 900000 78040 -34451 189264 9030 82333 58840 49443 646 -10890 -32128 66813 41501 26674 7790 32501 31126 54772 41571 35515 39689 12307 6751 30498 22756 3074 17104 24905 2661 -1632 -7536 8508 24500 -1347 16649 941 4005 -1121 6651 16 2741 5037 6555 13419 -2885 11071 -94 -4452 4445 4157 -10203 -3969 -551 -1684 3030 -1812 -3250 4847 1119 1096 7715 -2759 -1232 -1020 967 -2736 -4373 -2533 -1887 -2433 -1016 -180 -4909 -2025 -6110 365 -1512 3161 -144 1728 -1365 -853 943 -1001 -2439 2097 61 -667 2212 427 889 2043 2731 -194 252 964 417 -214 1114 -85 1668 -771 555 -1091 695 525 -437 1723 -362 609 -732 -1454 -1763 3148 3524 900000 -1117 -1509 900000 -11018 900000 900000 -9991 -4129 1835 930 1066 2008 458 -354 -2366 -1576 628 947 1645 -1317 -2769 626 900000 -843 -2998 3326 574 900000 1503 -2378 3646 420 1875 1752 1819 45 -992 -3995 3277 2762 2149 778 2619 2617 3741 3349 3172 3684 1660 1040 3953 3308 549 2666 3533 457 -289 -1465 1550 4334 -349 3849 249 989 -293 1724 5 936 1755 2227 4019 -930 2773 -24 -1193 1207 1347 -4485 -1870 -275 -897 1635 -1095 -2100 2988 719 684 4202 -1546 -643 -591 611 -2088 -3951 -2356 -1921 -2766 -1071 -169 -4398 -1760 -5956 355 -1579 3374 -174 2291 -2067 -1360 1479 -1541 -3590 2823 85 -980 3366 694 1433 3145 4025 -285 353 1291 541 -290 1683 -147 3094 -1556 1158 -2453 1641 1307 -1123 4407 -946 1514 -1737 -3272 -3855 SS 20240617T103409.3Z 8934.440385 132 1 49.33 2 76.49 70.48 138.16 302.40 0.00 1 0.00 1 0 17 3.060e-01 1.141e-02 2.660e-01 6.426e-03 5.458947e-01 3.469483e-03 6.494237e-03 -6.000000e+00 1.780186e-01 232.92 -2.00 3.55 -2.00 321.08 0.00e+00 4.253267e-03 1.573380e-03 2.848271e-03 -6.000000e+00 7.945877e-03 285.28 -2.00 20.00 -2.00 320.45 0.00e+00 4.177 0.001 302.00 328.00 3 2.7971e+00 1.1619e-02 5.2092e-02 -6.0000e+00 4.4919e-01 5.6698e-02 1.5386e-02 3.3079e-02 -6.0000e+00 4.8674e-01 -9.1123e-02 1.4618e-02 1.7957e-02 -6.0000e+00 2.8708e-01 2.8012e-02 7.0468e-03 5.9089e-03 -6.0000e+00 1.1982e-01 2.8293e-04 -5.0252e-04 1.9107e-04 8.7478e-05 -6.0000e+00 8.2112e-03 2.4988e-03 -4.6081e-05 12 8 8 10 0 0 99.91 23.00 0.24 0.00250 -0.00128 31 6 1 5 0 1590.940 26.62 20.06 23.00 22.81 30.1 1030.66 185904 -35364 -34627 -147099 -59163 -137872 -67503 900000 -21196 900000 -156254 -10814 -5538 -47289 17689 31138 33800 -23933 27386 -22634 -3342 3896 -22885 -1489 -668 -1279 -6297 -28400 -44133 16513 -16762 32382 -7345 -17527 -11697 -36150 -8971 -10966 16365 5105 -1930 5422 -7528 1606 10440 12715 -4372 6060 -5609 6545 286 4324 1357 5979 10940 1346 5709 3435 517 -1983 136 5315 3328 8519 537 3289 929 -555 -933 3856 1715 -171 2400 2370 -1710 849 -1039 -1893 -1816 -2207 -3914 -1053 -3573 -1991 -1143 589 181 84 2465 848 1550 -395 -927 -471 -2604 -626 -10 1994 -93 -329 50 -1600 -1972 -595 -1233 -1662 -507 -1842 3 1161 1175 593 350 1410 -1973 -861 -302 1256 537 100 95 608 722 -338 1016 -764 603 1303 -629 -68 -165 -258 -751 -140 -439 -4 383 751 408 -273 98 -804 -180 1165 -222 -217 -2841 -432 -2087 -529 900000 -133 900000 -4242 -73 -43 -716 175 325 388 -537 400 -579 -73 87 -678 -38 -18 -37 -197 -1084 -1910 404 -659 922 -360 -1038 -633 -2409 -490 -718 997 419 -192 540 -900 181 1094 1332 -553 704 -754 816 41 672 237 1079 1988 279 1167 720 109 -422 29 1184 853 2319 167 961 267 -180 -330 1498 756 -73 1102 1038 -719 312 -358 -650 -682 -976 -2050 -609 -2317 -1344 -818 444 145 69 1996 675 1141 -275 -612 -312 -1942 -525 -10 2128 -110 -391 55 -1628 -1858 -561 -1266 -1816 -577 -2260 4 1659 1837 974 572 2173 -2947 -1213 -426 1830 841 166 157 967 1109 -507 1437 -1056 791 1759 -966 -115 -305 -502 -1527 -299 -1008 -9 939 1868 1017 -660 223 -1753 -381 SS 20240617T104500.8Z 8934.447926 135 1 9.59 2 74.61 72.16 139.77 305.37 0.00 1 0.00 1 0 17 2.799e-01 2.357e-02 2.164e-01 1.586e-02 4.638176e-01 8.315667e-03 5.831591e-03 -6.000000e+00 1.626693e-01 232.92 -2.00 3.55 -2.00 320.26 0.00e+00 7.173378e-03 2.775966e-03 2.733800e-03 -6.000000e+00 7.178968e-03 285.28 -2.00 20.00 -2.00 319.53 0.00e+00 3.697 0.001 302.00 328.00 3 3.7833e+00 2.5002e-02 4.4962e-02 -6.0000e+00 4.0947e-01 1.5455e-01 3.0042e-02 2.6381e-02 -6.0000e+00 4.4326e-01 -2.2405e-01 2.3539e-02 1.5433e-02 -6.0000e+00 2.6252e-01 9.0895e-02 1.1931e-02 6.5957e-03 -6.0000e+00 1.1002e-01 1.7779e-04 -2.3215e-04 4.6803e-04 8.6015e-05 -6.0000e+00 7.5797e-03 2.7297e-04 4.5775e-05 12 9 9 12 1 1 999.00 23.05 0.19 0.00027 -0.00147 2 3 1 5 0 3192.160 26.73 19.99 23.05 23.05 30.1 1032.32 -73539 -114943 -25286 900000 -132138 -22183 -118869 900000 2377 -94238 -61699 -75911 7016 35621 1300 -45578 76380 -32491 -6530 72003 2737 19697 42107 53290 -3681 29599 -27785 13771 -39738 9289 31363 28182 38369 8271 6986 162 -6081 65465 -797 15820 -442 18765 7751 13133 2052 7578 29299 2526 886 16748 16305 -936 11620 4437 5157 9838 7735 -4994 597 -3785 1048 -5874 -3412 14930 3783 -4008 2516 -3752 4814 1990 34 5320 -4618 8634 -2910 -233 -7463 -1259 -427 230 -2150 -3264 1644 -4176 -781 -1791 -1127 86 657 245 6589 398 -1601 -2702 -3984 -1273 -586 1152 788 -1203 -1446 -4371 -1868 -1217 -1298 -2257 -2526 -242 319 2898 127 690 -93 548 -536 2355 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