File name: Pandora183s1_LondonderryNH_20240707_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240708T045848.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240707_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240707T102804.5Z 8954.436163 78 1 49.53 2 78.82 69.59 91.68 55.69 0.00 1 0.00 1 0 17 3.809e-01 1.515e-02 3.473e-01 1.155e-02 6.154001e-01 6.375573e-03 7.259567e-03 -6.000000e+00 2.229268e-01 232.99 -2.00 3.55 -2.00 321.48 0.00e+00 1.745727e-03 3.285748e-03 4.284763e-03 -6.000000e+00 1.031063e-02 287.12 -2.00 20.00 -2.00 320.88 0.00e+00 4.975 0.002 302.00 328.00 3 2.5354e+00 2.3130e-02 6.3461e-02 -6.0000e+00 5.6287e-01 1.6110e-01 3.1441e-02 4.4485e-02 -6.0000e+00 6.1042e-01 -2.2381e-01 2.9291e-02 2.0061e-02 -6.0000e+00 3.5888e-01 8.4380e-02 1.3781e-02 4.8440e-03 -6.0000e+00 1.5118e-01 1.5962e-04 -8.1016e-04 3.4276e-04 8.3313e-05 -6.0000e+00 1.0242e-02 3.5164e-03 -1.1193e-04 12 8 8 10 0 0 99.94 22.95 0.38 0.00352 -0.00257 50 10 1 5 0 990.390 26.51 20.00 22.95 29.61 31.1 1060.28 -247005 900000 900000 -69085 -78901 -167254 900000 -128543 900000 900000 -65843 -17820 1910 -108628 -72215 51241 -91631 -54561 35746 -13372 44630 -71573 -39292 75062 -43300 -79956 22490 19374 56042 -50192 -38242 14648 18650 17705 -19664 10872 -8762 28876 -16719 -19443 18194 7159 5812 15997 -6551 3913 5454 -927 18436 -750 6191 6274 12263 13644 8519 12054 9624 2575 18192 4140 -4183 7915 943 8105 1830 10277 3787 6165 1463 7638 1559 8295 9 6640 -3866 6 6597 -3120 -4489 -8287 2408 -2058 21 -2555 2537 -2166 2552 2999 -1085 -776 391 -1891 -2739 -151 -1385 -2887 -1245 -761 21 -703 -145 -2724 -1597 -1055 -1307 -1605 -1578 -540 590 61 1286 398 -100 871 -833 -35 -1165 -1032 1133 1775 727 1566 204 -357 670 -545 274 1296 1111 -92 830 -339 -106 187 -1096 -536 415 1098 -40 -131 274 -823 -856 -6844 900000 900000 -778 -888 -2317 900000 -1567 900000 900000 -741 -201 22 -2343 -1355 577 -2836 -1279 402 -238 502 -2350 -958 845 -1300 -3675 380 327 631 -1849 -1448 390 553 580 -905 356 -377 1005 -1129 -1631 1191 564 488 1244 -644 352 491 -91 1547 -81 684 777 1569 1871 1307 1862 1576 453 2662 682 -766 1401 203 1825 464 2335 891 1444 394 2235 539 2818 3 2167 -1286 2 1633 -849 -1369 -3104 949 -969 10 -1409 1423 -1363 1617 1952 -810 -557 259 -1192 -1659 -91 -940 -2298 -1125 -783 24 -790 -152 -2637 -1404 -933 -1254 -1637 -1696 -614 724 84 1931 635 -160 1326 -1215 -49 -1646 -1529 1749 2845 1171 2415 307 -523 933 -738 356 1739 1680 -158 1542 -675 -221 412 -2621 -1340 1052 2810 -104 -324 636 -1826 -1853 SS 20240707T110054.1Z 8954.458959 93 1 49.55 2 73.10 74.72 86.79 61.05 0.00 1 0.00 1 0 17 1.013e-01 6.864e-03 5.180e-02 2.272e-03 4.412318e-01 1.171887e-03 5.240986e-03 -6.000000e+00 5.851456e-02 232.99 -2.00 3.55 -2.00 320.19 0.00e+00 1.371109e-03 4.035693e-04 1.693968e-03 -6.000000e+00 2.581497e-03 287.12 -2.00 20.00 -2.00 319.44 0.00e+00 3.386 0.001 302.00 328.00 3 2.0610e+00 3.5372e-03 4.1742e-02 -6.0000e+00 1.4705e-01 1.0310e-02 4.3375e-03 2.5640e-02 -6.0000e+00 1.5905e-01 4.2019e-03 3.6653e-03 1.2393e-02 -6.0000e+00 9.4609e-02 -1.2473e-02 1.8691e-03 3.2738e-03 -6.0000e+00 3.9768e-02 1.4011e-03 -1.5838e-04 6.6732e-05 4.1667e-05 -6.0000e+00 2.6759e-03 3.4121e-04 4.4253e-05 11 8 0 10 0 0 99.97 23.00 0.30 0.00034 -0.00085 157 33 1 5 0 315.550 26.62 20.00 23.00 29.91 31.0 1062.88 -42427 -35471 -17676 -45848 12813 -44791 -28896 -42774 -15986 -5553 -38882 -909 -27590 -16808 -8013 -5739 858 -1437 -1076 -5978 3436 -9487 -4515 -8108 -5176 -6983 -3163 -3012 -5354 -7268 -3798 4706 1077 -5750 -7254 -6335 -4198 -2911 2051 259 -1138 -1076 -305 -1725 300 442 -517 2644 -1272 -1372 -149 1322 992 983 1655 677 1011 560 -382 630 97 2657 1809 3810 1053 691 228 -729 1038 680 1454 1378 1093 903 441 -527 -2136 -2223 -1284 -792 -1246 -1158 -2399 -1432 -638 -787 484 378 1461 775 1186 -214 -1013 -87 -780 -520 576 1090 94 -306 -732 -1602 -845 -404 -1308 -1675 -832 -681 286 477 983 531 301 307 -341 -106 180 186 372 142 31 435 810 185 549 -163 -308 606 107 -51 -406 -618 -514 -84 -169 -149 500 596 214 95 -99 -567 -173 -540 -498 -225 -770 109 -637 -402 -775 -254 -87 -877 -15 -678 -454 -240 -198 31 -56 -45 -279 152 -480 -222 -444 -298 -435 -194 -179 -309 -430 -240 314 84 -522 -646 -537 -412 -331 271 42 -192 -214 -63 -371 64 95 -113 560 -283 -315 -36 351 286 305 537 230 352 197 -133 214 34 979 748 1702 503 316 99 -317 476 359 848 846 675 535 244 -264 -992 -1000 -612 -433 -789 -824 -1880 -1173 -554 -735 472 382 1465 756 1072 -180 -802 -67 -660 -496 616 1308 123 -400 -903 -1811 -881 -428 -1515 -2063 -1067 -921 410 746 1650 843 469 498 -517 -152 258 278 594 241 53 723 1300 288 811 -231 -420 838 163 -85 -732 -1167 -1002 -171 -336 -311 1062 1289 465 201 -200 -1202 -357 SS 20240707T110603.8Z 8954.462544 97 1 49.68 2 72.18 75.52 85.99 61.87 0.00 1 0.00 1 0 17 7.463e-02 6.554e-03 2.525e-02 1.302e-03 4.237528e-01 6.686094e-04 5.045937e-03 -6.000000e+00 4.311140e-02 232.99 -2.00 3.55 -2.00 320.03 0.00e+00 1.351463e-03 2.184485e-04 1.587399e-03 -6.000000e+00 1.901984e-03 287.12 -2.00 20.00 -2.00 319.28 0.00e+00 3.223 0.001 302.00 328.00 3 1.1826e+00 1.9876e-03 3.9804e-02 -6.0000e+00 1.0834e-01 4.2104e-03 2.4116e-03 2.4454e-02 -6.0000e+00 1.1719e-01 7.5999e-03 1.9916e-03 1.1790e-02 -6.0000e+00 6.9705e-02 -1.4546e-02 1.0235e-03 3.1055e-03 -6.0000e+00 2.9299e-02 4.0320e-03 -2.1675e-04 3.8137e-05 3.9156e-05 -6.0000e+00 1.9716e-03 5.6241e-04 3.8222e-05 11 9 0 11 8 0 99.52 23.00 0.26 0.00056 -0.00107 519 108 1 5 0 95.700 26.62 20.00 23.00 30.21 31.2 1066.20 -16877 -25053 -17898 -27252 -25525 -33210 -27052 -24689 -22048 -14205 -27928 -11637 -16063 -13807 -6673 -5479 -5290 -6891 -3194 570 -1690 267 -1216 -185 -1844 -182 -2585 -2655 -7254 -3565 -4010 360 1614 -2060 -4526 -5623 -3823 -4221 -2567 -460 -1487 -766 139 -764 -50 152 -1312 -653 -1207 -258 900 303 1849 1406 1203 874 874 193 -9 377 961 1709 2383 3243 1277 668 8 -722 1053 998 1334 982 1022 942 -23 -625 -1501 -2294 -1418 -1046 -1214 -944 -2255 -1487 -497 -71 323 876 1256 907 583 64 -1271 -703 -725 -600 234 934 202 -397 -753 -1505 -979 -468 -1367 -1292 -807 -689 290 717 1049 502 551 107 -374 5 138 131 417 119 47 364 772 349 512 -335 -237 608 36 -159 -389 -504 -421 -115 -149 -133 376 570 341 -23 6 -570 -322 -200 -379 -273 -453 -378 -544 -437 -442 -440 -287 -664 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