File name: Pandora183s1_LondonderryNH_20240718_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20240719T050040.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20240718_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20240718 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240718T104723.3Z 8965.449575 120 1 50.81 2 76.75 73.67 138.25 274.62 0.00 1 0.00 1 0 25 5.212e-01 4.158e-02 3.956e-01 3.481e-02 5.427952e-01 1.930984e-02 6.139868e-03 -6.000000e+00 3.074291e-01 232.89 -2.00 3.55 -2.00 321.01 0.00e+00 1.016416e-02 8.416913e-03 1.688963e-03 -6.000000e+00 1.682719e-02 287.89 -2.00 20.00 -2.00 320.29 0.00e+00 4.253 0.001 302.00 328.00 3 4.4754e+00 6.4422e-02 5.4330e-02 -6.0000e+00 7.8065e-01 3.2873e-01 7.9189e-02 3.9798e-02 -6.0000e+00 8.5117e-01 -3.5008e-01 6.2983e-02 1.4804e-02 -6.0000e+00 4.9288e-01 1.3443e-01 3.1242e-02 1.2730e-02 -6.0000e+00 2.1058e-01 4.3735e-05 -2.5078e-03 1.0629e-03 1.0906e-04 -6.0000e+00 1.4778e-02 5.4383e-03 -3.9486e-04 12 8 8 10 0 0 99.97 22.96 0.79 0.00544 -0.01341 16 3 1 5 0 3174.670 26.62 19.99 22.96 29.46 31.0 1045.27 900000 900000 -120840 -140212 900000 132958 900000 900000 -149078 900000 900000 900000 900000 -49972 111434 -90464 -75632 -46265 265010 130461 900000 198656 -10627 -14225 52035 33961 66304 7375 900000 -10127 218394 96390 900000 -21407 2440 10520 -57881 -31987 -26482 78874 11977 62441 55841 9355 27406 55908 31194 35391 61219 -12378 46597 27562 43185 39830 -19613 -3814 16484 7487 -7490 8514 -10020 12917 -433 331 2459 -9509 24939 -9956 7002 -6167 -7374 14400 2375 6684 -3386 -1582 9514 -11470 11538 -10742 -5466 6905 -2076 -3912 -4620 2822 16949 686 57 2026 10389 1045 3080 -5491 -4631 724 -1325 -2067 1825 1774 2250 -6024 2508 -4281 1138 -219 -7485 -5890 1609 1493 -122 -2056 1811 -3373 -7604 3128 1564 -3000 4545 636 2204 1067 54 4617 2462 1105 299 17 1428 1978 2508 -1553 -2697 701 1452 -1608 1256 1854 1004 1562 -3684 1104 -3495 900000 900000 -4677 -6444 900000 4503 900000 900000 -7379 900000 900000 900000 900000 -1692 3774 -6363 -5123 -2531 8975 4418 900000 6727 -443 -630 1762 1150 2245 291 900000 -486 7396 3264 900000 -1933 165 623 -7187 -3521 -3288 4007 1318 4405 4412 1214 3016 4733 3433 3795 5183 -2271 5129 4045 5850 5957 -5535 -936 3349 1648 -1860 1778 -2602 2916 -126 107 812 -3408 6603 -3739 2393 -2753 -3678 6029 1112 2840 -1459 -599 2958 -4343 3801 -5192 -2911 3678 -1317 -2661 -3371 2042 11218 551 46 1553 6812 695 1887 -3685 -3394 577 -1240 -2221 2050 1993 2355 -6176 2169 -4007 1090 -225 -8711 -7180 1971 2027 -184 -3304 2772 -5182 -11400 4015 2052 -4323 6478 989 3372 1599 79 6211 3236 1411 369 22 2014 3088 4216 -2859 -5223 1386 3040 -3643 2827 4640 2528 3767 -8846 2390 -7706 SS 20240718T114536.8Z 8965.490009 149 1 49.57 2 66.32 82.88 148.23 286.55 0.00 1 0.00 1 0 17 3.641e-02 7.077e-03 2.447e-02 2.549e-03 3.334738e-01 1.301210e-03 3.969141e-03 -6.000000e+00 2.102567e-02 232.89 -2.00 3.55 -2.00 319.41 0.00e+00 9.693048e-04 3.378399e-04 8.817383e-04 -6.000000e+00 9.309052e-04 287.89 -2.00 20.00 -2.00 318.58 0.00e+00 2.471 0.000 302.00 328.00 3 3.0909e+00 3.6900e-03 3.0529e-02 -6.0000e+00 5.2812e-02 7.5067e-03 4.3098e-03 1.8329e-02 -6.0000e+00 5.7117e-02 1.0469e-02 3.0896e-03 8.8332e-03 -6.0000e+00 3.3994e-02 -1.3654e-02 1.6055e-03 2.3767e-03 -6.0000e+00 1.4304e-02 1.3731e-03 -1.5782e-04 7.5344e-05 2.5909e-05 -6.0000e+00 9.6179e-04 -5.4465e-04 2.6660e-05 11 8 0 10 0 0 99.99 22.86 0.40 -0.00054 -0.00173 185 38 1 5 0 267.900 26.51 20.00 22.86 29.95 31.2 1049.76 -7000 -8742 1105 -5297 -10539 -2717 -23440 -14051 -7219 -20386 -2759 -6251 -918 -1000 -1353 -6242 -1714 -2282 -836 2720 1379 3892 -1223 219 -645 -1055 -964 -1247 1391 -3197 1245 -1372 709 -1228 -6653 -4013 -3426 -1135 -1256 44 -1729 -791 -1567 -465 43 710 -445 -501 -237 -1034 813 1110 784 1047 739 1340 537 869 305 305 1224 2287 2781 2909 2045 -95 -554 -1376 1025 1419 832 1308 599 913 -192 -427 -1109 -2560 -499 -1417 -1279 -1160 -2110 -1226 -543 -387 195 825 1119 957 704 658 -1492 -186 -833 -464 423 662 310 -381 -1081 -1401 -1303 -571 -1131 -1061 -791 -564 12 848 809 409 448 90 -425 3 204 -164 466 112 53 589 745 332 756 -101 -408 550 -58 -145 -110 -342 -195 -264 -60 -196 545 718 139 -89 183 -629 -838 -203 -297 36 -181 -341 -75 -830 -509 -278 -971 -111 -265 -42 -54 -86 -475 -146 -206 -79 259 138 378 -127 24 -75 -130 -121 -151 153 -361 144 -181 101 -191 -1042 -584 -530 -200 -268 11 -494 -237 -492 -147 14 224 -141 -157 -73 -326 266 394 299 423 312 578 239 387 134 132 538 1070 1423 1613 1170 -58 -312 -762 587 923 603 902 418 673 -134 -268 -632 -1407 -281 -916 -940 -949 -1879 -1136 -534 -409 197 857 1280 1060 726 621 -1322 -158 -758 -468 475 829 418 -513 -1373 -1631 -1420 -634 -1371 -1363 -1060 -793 18 1339 1239 643 751 142 -621 3 278 -235 709 183 88 955 1170 503 1084 -140 -537 726 -83 -226 -182 -584 -341 -482 -116 -401 1137 1527 298 -186 366 -1218 -1591 SS 20240718T121023.0Z 8965.507210 166 1 21.92 2 61.80 86.90 152.30 293.11 0.00 1 0.00 1 0 17 1.877e-02 7.303e-03 1.191e-02 2.351e-03 2.851459e-01 1.191251e-03 3.404124e-03 -6.000000e+00 1.084301e-02 232.89 -2.00 3.55 -2.00 318.18 0.00e+00 1.147955e-03 2.165282e-04 4.557271e-04 -6.000000e+00 4.800420e-04 287.89 -2.00 20.00 -2.00 317.31 0.00e+00 2.106 0.000 302.00 328.00 3 3.4275e+00 3.2430e-03 2.5897e-02 -6.0000e+00 2.7235e-02 -7.8967e-04 3.6780e-03 1.5191e-02 -6.0000e+00 2.9453e-02 6.2528e-03 2.3221e-03 7.3924e-03 -6.0000e+00 1.7530e-02 -8.5315e-03 1.1824e-03 2.0857e-03 -6.0000e+00 7.3780e-03 1.5032e-03 -9.7079e-05 6.8005e-05 2.0976e-05 -6.0000e+00 4.9587e-04 -9.7130e-04 6.3812e-05 12 9 1 12 1 1 98.97 22.92 0.23 -0.00097 -0.00170 19 9 1 5 0 1095.390 26.51 20.00 22.92 30.91 31.0 1056.28 -1452 -503 6687 -2254 -77 -2173 -7891 -10849 -2250 -2952 -6762 431 -3510 -1764 300 -625 -1049 -1448 1864 894 2714 -850 -990 -870 648 206 -1391 -1351 -612 -1300 2040 488 187 -275 -5142 -3848 -3911 -2362 -765 -371 -530 -538 -517 -563 183 -279 -279 440 -1417 -537 817 736 1423 1324 803 1137 1560 294 641 869 1134 1899 1774 2730 996 -147 -633 -694 559 993 167 969 849 1053 209 -484 -1134 -2198 -718 -1937 -1472 -998 -2017 -1558 -466 -390 12 110 962 743 458 -71 -711 -258 -525 -812 704 851 64 -232 -228 -1594 -1011 -488 -1342 -1060 -681 -819 81 664 1203 398 595 43 -210 27 50 -394 597 512 118 429 607 219 629 -166 186 781 436 64 -314 -293 -493 5 -55 -97 209 635 0 -51 -22 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